Thermoelectric Properties and Electronic Structure of the Cage Compounds A2BaCu8Te10(A = K, Rb, Cs):  Systems with Low Thermal Conductivity

2001 ◽  
Vol 13 (2) ◽  
pp. 613-621 ◽  
Author(s):  
Rhonda Patschke ◽  
Xiang Zhang ◽  
David Singh ◽  
Jon Schindler ◽  
Carl R. Kannewurf ◽  
...  
ChemInform ◽  
2010 ◽  
Vol 32 (24) ◽  
pp. no-no
Author(s):  
Rhonda Patschke ◽  
Xiang Zhang ◽  
David Singh ◽  
Jon Schindler ◽  
Carl R. Kannewurf ◽  
...  

2000 ◽  
Vol 626 ◽  
Author(s):  
Antje Mrotzek ◽  
Kyoung-Shin Choi ◽  
Duck-Young Chung ◽  
Melissa A. Lane ◽  
John R. Ireland ◽  
...  

ABSTRACTWe present the structure and thermoelectric properties of the new quaternary selenides K1+xM4–2xBi7+xSe15 (M = Sn, Pb) and K1-xSn5-xBi11+xSe22. The compounds K1+xM4-2xBi7+xSe15 (M= Sn, Pb) crystallize isostructural to A1+xPb4-2xSb7+xSe15 with A = K, Rb, while K1-xSn5-xBi11+xSe22 reveals a new structure type. In both structure types fragments of the Bi2Te3-type and the NaCl-type are connected to a three-dimensional anionic framework with K+ ions filled tunnels. The two structures vary by the size of the NaCl-type rods and are closely related to β-K2Bi8Se13 and K2.5Bi8.5Se14. The thermoelectric properties of K1+xM4-2xBi7+xSe15 (M = Sn, Pb) and K1-xSn5-xBi11+xSe22 were explored on single crystal and ingot samples. These compounds are narrow gap semiconductors and show n-type behavior with moderate Seebeck coefficients. They have very low thermal conductivity due to an extensive disorder of the metal atoms and possible “rattling” K+ ions.


Polymer ◽  
2020 ◽  
Vol 206 ◽  
pp. 122912
Author(s):  
Naoya Yanagishima ◽  
Shinji Kanehashi ◽  
Hiromu Saito ◽  
Kenji Ogino ◽  
Takeshi Shimomura

Author(s):  
Chang'an Li ◽  
Xin Guan ◽  
Shizhong Yue ◽  
Xi Zu Wang ◽  
Jianmin Li ◽  
...  

Thermoelectric polymers have attracted great attention because of their unique merits including low thermal conductivity, low cost, non- or low toxicity and high mechanical flexibility. However, their thermoelectric properties particularly...


2017 ◽  
Vol 5 (36) ◽  
pp. 19406-19415 ◽  
Author(s):  
Robin Lefèvre ◽  
David Berthebaud ◽  
Oleg Lebedev ◽  
Olivier Pérez ◽  
Célia Castro ◽  
...  

A new ternary layered compound In2Ge2Te6, belonging to the hexatellurogermanate family has been synthesized from the reaction of appropriate amounts of the pure elements at high temperature in sealed silica tubes.


2021 ◽  
Vol 5 (1) ◽  
pp. 324-332
Author(s):  
J. M. Li ◽  
H. W. Ming ◽  
B. L. Zhang ◽  
C. J. Song ◽  
L. Wang ◽  
...  

Cu3SbSe4-Based materials were fabricated through Sn-doping and AgSb0.98Ge0.02Se2 incorporation and their thermoelectric properties were investigated in the temperature range from 300 K to 675 K.


2017 ◽  
Vol 46 (48) ◽  
pp. 17053-17060 ◽  
Author(s):  
Vijayakumar Sajitha Aswathy ◽  
Cheriyedath Raj Sankar ◽  
Manoj Raama Varma ◽  
Abdeljalil Assoud ◽  
Mario Bieringer ◽  
...  

The layered chalcogenides, TlScQ2 (Q = Se, Te), possess intriguing band structure characteristics and very low thermal conductivity.


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