Cocrystal Controlled Solid-State Synthesis of a Thermally Stable Nicotinate Analogue That Sustains an Isostructural Series of Porous Metal−Organic Materials

2009 ◽  
Vol 9 (12) ◽  
pp. 5021-5023 ◽  
Author(s):  
Jason A. Perman ◽  
Kevin Dubois ◽  
Farid Nouar ◽  
Sandra Zoccali ◽  
Łukasz Wojtas ◽  
...  
Keyword(s):  
Solid State ◽  
Organic Materials ◽  
Porous Metal ◽  
Solid State Synthesis ◽  
Thermally Stable ◽  
Metal Organic

scholarly journals Redox-promoted associative assembly of metal–organic materials

2016 ◽  
Vol 7 (1) ◽  
pp. 707-712 ◽  
Author(s):  
Martin Glavinović ◽  
Feng Qi ◽  
Athanassios D. Katsenis ◽  
Tomislav Friščić ◽  
Jean-Philip Lumb
Keyword(s):  
Solid State ◽  
Self Assembly ◽  
Organic Materials ◽  
Metal Oxidation ◽  
Metal Organic ◽  
One Step

We develop an associative synthesis of metal–organic materials that combines solid-state metal oxidation and coordination-driven self-assembly into a one-step, waste-free transformation.

scholarly journals Flue-gas and direct-air capture of CO 2 by porous metal–organic materials

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160025 ◽  
Author(s):  
David G. Madden ◽  
Hayley S. Scott ◽  
Amrit Kumar ◽  
Kai-Jie Chen ◽  
Rana Sanii ◽  
...  
Keyword(s):  
Flue Gas ◽  
Carbon Capture ◽  
Large Scale ◽  
Organic Materials ◽  
Porous Metal ◽  
Gas Mixtures ◽  
Strong Interactions ◽  
Direct Air Capture ◽  
Air Capture ◽  
Metal Organic

Sequestration of CO 2 , either from gas mixtures or directly from air (direct air capture), is a technological goal important to large-scale industrial processes such as gas purification and the mitigation of carbon emissions. Previously, we investigated five porous materials, three porous metal–organic materials (MOMs), a benchmark inorganic material, Zeolite 13X and a chemisorbent, TEPA-SBA-15 , for their ability to adsorb CO 2 directly from air and from simulated flue-gas. In this contribution, a further 10 physisorbent materials that exhibit strong interactions with CO 2 have been evaluated by temperature-programmed desorption for their potential utility in carbon capture applications: four hybrid ultramicroporous materials, SIFSIX-3-Cu , DICRO-3-Ni-i , SIFSIX-2-Cu-i and MOOFOUR-1-Ni ; five microporous MOMs, DMOF-1 , ZIF-8 , MIL-101 , UiO-66 and UiO-66-NH 2 ; an ultramicroporous MOM, Ni-4-PyC . The performance of these MOMs was found to be negatively impacted by moisture. Overall, we demonstrate that the incorporation of strong electrostatics from inorganic moieties combined with ultramicropores offers improved CO 2 capture performance from even moist gas mixtures but not enough to compete with chemisorbents. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

scholarly journals Thermal Reactivity in Metal Organic Materials (MOMs): From Single-Crystal-to-Single-Crystal Reactions and Beyond

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4088
Author(s):  
Javier Martí-Rujas
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Organic Materials ◽  
Structural Transformations ◽  
Atomic Motion ◽  
X Ray Diffraction ◽  
Thermally Induced ◽  
X Ray ◽  
Thermal Reactivity ◽  
Metal Organic

Thermal treatment is important in the solid-state chemistry of metal organic materials (MOMs) because it can create unexpected new structures with unique properties and applications that otherwise in the solution state are very difficult or impossible to achieve. Additionally, high-temperature solid-state reactivity provide insights to better understand chemical processes taking place in the solid-state. This review article describes relevant thermally induced solid-state reactions in metal organic materials, which include metal organic frameworks (MOFs)/coordination polymers (CPs), and second coordination sphere adducts (SSCs). High temperature solid-state reactivity can occur in a single-crystal-to-single crystal manner (SCSC) usually for cases where there is small atomic motion, allowing full structural characterization by single crystal X-ray diffraction (SC-XRD) analysis. However, for the cases in which the structural transformations are severe, often the crystallinity of the metal-organic material is damaged, and this happens in a crystal-to-polycrystalline manner. For such cases, in the absence of suitable single crystals, structural characterization has to be carried out using ab initio powder X-ray diffraction analysis or pair distribution function (PDF) analysis when the product is amorphous. In this article, relevant thermally induced SCSC reactions and crystal-to-polycrystalline reactions in MOMs that involve significant structural transformations as a result of the molecular/atomic motion are described. Thermal reactivity focusing on cleavage and formation of coordination and covalent bonds, crystalline-to-amorphous-to-crystalline transformations, host–guest behavior and dehydrochlorination reactions in MOFs and SSCs will be discussed.

scholarly journals Recent Advances as Materials of Functional Metal-Organic Frameworks

2013 ◽  
Vol 2013 ◽  
pp. 1-11 ◽  
Author(s):  
Xiao-Lan Tong ◽  
Hai-Lu Lin ◽  
Jian-Hua Xin ◽  
Fen Liu ◽  
Min Li ◽  
...  
Keyword(s):  
Solid State ◽  
Functional Properties ◽  
Critical Review ◽  
Organic Materials ◽  
Metal Organic Frameworks ◽  
Organic Ligand ◽  
Comprehensive Overview ◽  
Recent Advances ◽  
Metal Organic

Metal-organic frameworks (MOFs), also known as hybrid inorganic-organic materials, represent an emerging class of materials that have attracted the imagination of solid-state chemists because MOFs combine unprecedented levels of porosity with a range of other functional properties that occur through the metal moiety and/or the organic ligand. The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the field of functional metal-organic frameworks, including luminescence, magnetism, and porosity through presenting examples. This review will be of interest to researchers and synthetic chemists attempting to design multifunctional MOFs.

scholarly journals Solid state organic amine detection in a photochromic porous metal organic framework

2015 ◽  
Vol 6 (2) ◽  
pp. 1420-1425 ◽  
Author(s):  
Arijit Mallick ◽  
Bikash Garai ◽  
Matthew A. Addicoat ◽  
Petko St. Petkov ◽  
Thomas Heine ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Organic Amine ◽  
Metal Organic ◽  
Amine Detection ◽  
Organic Framework

A new Mg(ii) based porous metal–organic framework (MOF) has been synthesized from naphthalenediimide (NDI) chromophoric unit containing linker. This MOF (Mg–NDI) shows instant and reversible photochromism as well as solvatochromic behavior. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state.

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