Continuous Synthesis of Full-Color Emitting Core/Shell Quantum Dots via Microreaction

2009 ◽  
Vol 9 (11) ◽  
pp. 4807-4813 ◽  
Author(s):  
Hongwei Yang ◽  
Weiling Luan ◽  
Zhen Wan ◽  
Shan-tung Tu ◽  
Wei-Kang Yuan ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Continuous Synthesis ◽  
Full Color

scholarly journals Full-color-emitting (CuInS2)ZnS-alloyed core/shell quantum dots with trimethoxysilyl end-capped ligands soluble in an ionic liquid

RSC Advances ◽  
2019 ◽  
Vol 9 (44) ◽  
pp. 25576-25582 ◽  
Author(s):  
Huiqing Wang ◽  
Jiayuan Hu ◽  
Min Zhu ◽  
Yucheng Li ◽  
Hao Qian ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Ionic Liquid ◽  
Blue Shift ◽  
Core Shell ◽  
Full Color ◽  
Pl Intensity

ZCIS QDs were fabricated by varying ratio stock A to stock B. PL intensity enhanced and blue shift as shell layers increase. Emissions covering 800 nm to 518 nm tuned by compositions or shell layers. Ligand exchanged by MPtMS enable solubility in IL.

scholarly journals Multistage Microfluidic Platform for the Continuous Synthesis of III-V Core/Shell Quantum Dots

2018 ◽  
Vol 130 (34) ◽  
pp. 11081-11084 ◽  
Author(s):  
Jinyoung Baek ◽  
Yi Shen ◽  
Ioannis Lignos ◽  
Moungi G. Bawendi ◽  
Klavs F. Jensen
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Microfluidic Platform ◽  
Continuous Synthesis

scholarly journals Multistage Microfluidic Platform for the Continuous Synthesis of III-V Core/Shell Quantum Dots

2018 ◽  
Vol 57 (34) ◽  
pp. 10915-10918 ◽  
Author(s):  
Jinyoung Baek ◽  
Yi Shen ◽  
Ioannis Lignos ◽  
Moungi G. Bawendi ◽  
Klavs F. Jensen
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Microfluidic Platform ◽  
Continuous Synthesis

High-Temperature Synthesis of CdSe-Based Core/Shell, Core/Shell/Shell, and Core/Graded-Shell Nanoplatelets for Stable and Efficient Narrowband Emitters

2019 ◽  
Author(s):  
Aurelio A. Rossinelli ◽  
Henar Rojo ◽  
Aniket S. Mule ◽  
Marianne Aellen ◽  
Ario Cocina ◽  
...  
Keyword(s):  
Quantum Dots ◽  
High Temperature ◽  
Equilibrium Shape ◽  
Size Variation ◽  
Crystal Defects ◽  
Atomic Scale ◽  
Quantum Yields ◽  
Core Shell ◽  
Compositional Gradient ◽  
High Quality

<div>Colloidal semiconductor nanoplatelets exhibit exceptionally narrow photoluminescence spectra. This occurs because samples can be synthesized in which all nanoplatelets share the same atomic-scale thickness. As this dimension sets the emission wavelength, inhomogeneous linewidth broadening due to size variation, which is always present in samples of quasi-spherical nanocrystals (quantum dots), is essentially eliminated. Nanoplatelets thus offer improved, spectrally pure emitters for various applications. Unfortunately, due to their non-equilibrium shape, nanoplatelets also suffer from low photo-, chemical, and thermal stability, which limits their use. Moreover, their poor stability hampers the development of efficient synthesis protocols for adding high-quality protective inorganic shells, which are well known to improve the performance of quantum dots. <br></div><div>Herein, we report a general synthesis approach to highly emissive and stable core/shell nanoplatelets with various shell compositions, including CdSe/ZnS, CdSe/CdS/ZnS, CdSe/Cd<sub>x</sub>Zn<sub>1–x</sub>S, and CdSe/ZnSe. Motivated by previous work on quantum dots, we find that slow, high-temperature growth of shells containing a compositional gradient reduces strain-induced crystal defects and minimizes the emission linewidth while maintaining good surface passivation and nanocrystal uniformity. Indeed, our best core/shell nanoplatelets (CdSe/Cd<sub>x</sub>Zn<sub>1–x</sub>S) show photoluminescence quantum yields of 90% with linewidths as low as 56 meV (19.5 nm at 655 nm). To confirm the high quality of our different core/shell nanoplatelets for a specific application, we demonstrate their use as gain media in low-threshold ring lasers. More generally, the ability of our synthesis protocol to engineer high-quality shells can help further improve nanoplatelets for optoelectronic devices.</div>

Enhanced Photocurrent Generation in Proton‐Irradiated “Giant” CdSe/CdS Core/Shell Quantum Dots

2019 ◽  
Vol 29 (46) ◽  
pp. 1904501 ◽  
Author(s):  
Chao Wang ◽  
David Barba ◽  
Gurpreet S. Selopal ◽  
Haiguang Zhao ◽  
Jiabin Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Core Shell ◽  
Photocurrent Generation

Surface Organic Ligands-Passivated Quantum Dots: Toward High-Performance Light-Emitting Diodes with Long Lifetime

2021 ◽  
Author(s):  
Lishuang Wang ◽  
Ying Lv ◽  
Jie Lin ◽  
Jialong Zhao ◽  
Xingyuan Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
High Performance ◽  
Light Emitting Diodes ◽  
Organic Ligands ◽  
Colloidal Quantum Dots ◽  
Core Shell ◽  
Light Emitting ◽  
Long Lifetime

For quantum dots light-emitting diodes (QLEDs), typical colloidal quantum dots (QDs) are usually composed of a core/shell heterostructure which is covered with organic ligands as surface passivated materials to confine...

Single-charge transport through hybrid core–shell Au-ZnS quantum dots: a comprehensive analysis from a modified energy structure

Nanoscale ◽  
2021 ◽  
Author(s):  
Tuhin Shuvra Basu ◽  
Simon Diesch ◽  
Ryoma Hayakawa ◽  
Yutaka Wakayama ◽  
Elke Scheer
Keyword(s):  
Quantum Dots ◽  
Electronic Structure ◽  
Carrier Transport ◽  
Comprehensive Analysis ◽  
Energy Structure ◽  
Core Shell ◽  
Single Charge ◽  
Scanning Tunnelling Microscope ◽  
Single Carrier ◽  
Scanning Tunnelling

We examined the modified electronic structure and single-carrier transport of individual hybrid core–shell metal–semiconductor Au-ZnS quantum dots using a scanning tunnelling microscope.

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