Single-Crystal-to-Single-Crystal Structural Transformation in a Flexible Porous Gadolinium-Organic Framework with Selective and Controlled Sorption Properties

2009 ◽  
Vol 9 (9) ◽  
pp. 3844-3847 ◽  
Author(s):  
K. L. Gurunatha ◽  
Sudip Mohapatra ◽  
P. A. Suchetan ◽  
Tapas Kumar Maji
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Sorption Properties ◽  
Crystal Structural ◽  
Organic Framework

Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

CrystEngComm ◽  
2012 ◽  
Vol 14 (12) ◽  
pp. 4153 ◽  
Author(s):  
Sudip Mohapatra ◽  
Hiroshi Sato ◽  
Ryotaro Matsuda ◽  
Susumu Kitagawa ◽  
Tapas Kumar Maji
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Crystal Structural ◽  
Organic Framework

Single-Crystal to Single-Crystal Structural Transformation and Photomagnetic Properties of a Porous Iron(II) Spin-Crossover Framework

2008 ◽  
Vol 130 (9) ◽  
pp. 2869-2876 ◽  
Author(s):  
Suzanne M. Neville ◽  
Gregory J. Halder ◽  
Karena W. Chapman ◽  
Martin B. Duriska ◽  
Peter D. Southon ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Spin Crossover ◽  
Porous Iron ◽  
Crystal Structural

scholarly journals Modification of Structure and Magnetic Properties in Coordination Assemblies Based on [Cu(cyclam)]2+ and [W(CN)8]3−

Crystals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 45 ◽  
Author(s):  
Aleksandra Pacanowska ◽  
Mateusz Reczyński ◽  
Beata Nowicka
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Transformation ◽  
Water Solution ◽  
Building Blocks ◽  
Alcohol Solution ◽  
Slow Diffusion ◽  
Crystal Structural ◽  
Water Alcohol

The 1D {[CuII(cyclam)]3[WV(CN)8]2.5H2O}n (1·5H2O) (cyclam = 1,4,8,11-tetraazacyclotetradecane) coordination polymer of ladder topology can be obtained in water-alcohol solution from [Cu(cyclam)]2+ and [W(CN)8]3− building blocks. Upon dehydration, 1·5H2O undergoes a single-crystal-to-single-crystal structural transformation to the anhydrous {[CuII(cyclam)]3[WV(CN)8]2}n (1) form, which retains the same topology, but is characterized by shorter Cu-W distances and significantly more bent CN-bridges. The deformation of the coordination skeleton is reflected in magnetic properties: the predominant intra-chain interactions change from ferromagnetic in 1·5H2O to antiferromagnetic in 1. The reaction between the same building blocks in water solution under slow diffusion conditions leads to the formation of a 0D {[CuII(cyclam)(H2O)]2[CuII(cyclam)][WV(CN)8]2}.3H2O pentanuclear assembly (2·3H2O).

scholarly journals Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(ii)-framework

2015 ◽  
Vol 51 (15) ◽  
pp. 3173-3176 ◽  
Author(s):  
Susan Sen ◽  
Subhadip Neogi ◽  
Kari Rissanen ◽  
Parimal K. Bharadwaj
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Crystal Structural ◽  
Reversible Structural Transformation

Guest solvent triggered reversible structural transformation and concomitant Zn(ii) to Cu(ii) transmetalation has been realized through single-crystal to single-crystal fashion in an imidazolium functionalized 3D cationic Zn(ii)-framework.

Thermally Triggered Solid-State Single-Crystal-to-Single-Crystal Structural Transformation Accompanies Property Changes

2015 ◽  
Vol 21 (12) ◽  
pp. 4703-4711 ◽  
Author(s):  
Quan-Quan Li ◽  
Chun-Yan Ren ◽  
Yang-Yang Huang ◽  
Jian-Li Li ◽  
Ping Liu ◽  
...  
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Structural Transformation ◽  
Crystal Structural ◽  
Property Changes ◽  
Thermally Triggered

New hybrid organic-zincophosphate frameworks: single-crystal-to-single-crystal structural transformation and remarkable thermal and chemical stabilities

2016 ◽  
Vol 45 (17) ◽  
pp. 7231-7234 ◽  
Author(s):  
Tsung-Yuan Chang ◽  
Zhao-Nan Yan ◽  
Chun-Chi Wang ◽  
Hsing-Chun Li ◽  
Hsiu-Mei Lin ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Structural Transformations ◽  
Metal Phosphates ◽  
Crystal Structural

This research is the first example of hybrid metal phosphates that undergo SCSC structural transformations and exhibit remarkable thermal and chemical stabilities.

Sign in / Sign up

Export Citation Format

Share Document