Six Three-Dimensional Metal−Organic Frameworks with (3,4)-, (4,5)-, and (3,4,5)-Connected Nets Based on Mixed Ligands: Synthesis, Structures, and Adsorption Properties

2009 ◽  
Vol 9 (3) ◽  
pp. 1481-1488 ◽  
Author(s):  
Ming Xue ◽  
Guangshan Zhu ◽  
Hong Ding ◽  
Lei Wu ◽  
Xiaojun Zhao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Adsorption Properties ◽  
Mixed Ligands ◽  
Metal Organic

Two new isomeric zinc(II) metal–organic frameworks based on 1,5-bis(2-methyl-1H-imidazol-1-yl)pentane and 5-methylisophthalate ligands

2017 ◽  
Vol 73 (2) ◽  
pp. 78-83
Author(s):  
Xiong-Wen Tan ◽  
Heng-Feng Li ◽  
Chang-Hong Li
Keyword(s):  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Central Metal Atom ◽  
Central Metal ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Mixed Ligands ◽  
Metal Organic

Many factors, such as temperature, solvent, the central metal atom and the type of coligands, may affect the nature of metal–organic frameworks (MOFs) and the framework formation in the self-assembly process, which results in the complexity of these compounds and the uncertainty of their structures. Two new isomeric ZnIImetal–organic frameworks (MOFs) based on mixed ligands, namely, poly[[μ-1,5-bis(2-methyl-1H-imidazol-1-yl)pentane-κ2N3:N3′](μ-5-methylisophthalato-κ2O1:O3)zinc(II)], [Zn(C9H6O4)(C13H20N4)]n, (I), and poly[[μ-1,5-bis(2-methyl-1H-imidazol-1-yl)pentane-κ2N3:N3′](μ3-5-methylisophthalato-κ3O1:O1′:O3)(μ3-5-methylisophthalato-κ4O1:O1′:O3,O3′)dizinc(II)], [Zn2(C9H6O4)2(C13H20N4)]n, (II), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis and thermogravimetric analysis. Complex (I) displays a two-dimensional layer net, while complex (II) exhibits a twofold interpenetrating three-dimensional framework. Both complexes show high stability and good fluorescence in the solid state at room temperature.

scholarly journals The Structure and Property of Two Different Metal-Organic Frameworks Based on N/O-Donor Mixed Ligands

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1129
Author(s):  
Zhiqiang Lu ◽  
Yanzhi Li ◽  
Yi Ru ◽  
Shujian Yang ◽  
Chu Hao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Chain Structure ◽  
Metal Centers ◽  
Structure And Property ◽  
Trimesic Acid ◽  
Mixed Ligands ◽  
1D Chain ◽  
Metal Organic

Two different metal-organic frameworks (MOFs) [Cd2(AZN)(HAZN)(btc)(Hbtc)·4H2O]·2H2O (1), and [Zn3(AZN)2(btc)2·4H2O] (2) were synthesized by the reactions of different metal salts with mixed ligands of 1-(4-(1H-imidazol-5-yl)phenyl)-1H-1,2,4-triazole (AZN) and trimesic acid (H3btc). The different metal centers in the reaction condition have important impact on the resulting structures of MOFs 1 and 2. Compound 1 is a one-dimensional (1D) chain structure, while 2 features a three-dimensional (3D) framework with 3-fold interpenetration topology of Point (Schläfli) symbol of (6·82)4(62·82·102). Furthermore, the luminescent properties have been studied for MOFs 1 and 2.

Effect of Lithium Doping on the Structures and CO 2 Adsorption Properties of Metal‐Organic Frameworks HKUST‐1

2018 ◽  
Vol 3 (45) ◽  
pp. 12865-12870 ◽  
Author(s):  
Lingling Zhou ◽  
Zhaodong Niu ◽  
Xu Jin ◽  
Lihong Tang ◽  
Liping Zhu
Keyword(s):  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Lithium Doping ◽  
Metal Organic

scholarly journals Four Novel d10 Metal-Organic Frameworks Incorporating Amino-Functionalized Carboxylate Ligands: Synthesis, Structures, and Fluorescence Properties

2021 ◽  
Vol 9 ◽  
Author(s):  
Wang Xie ◽  
Jie Wu ◽  
Xiaochun Hang ◽  
Honghai Zhang ◽  
Kang shen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Fluorescence Properties ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Quenching Effect ◽  
D10 Metal ◽  
Metal Organic ◽  
Point Symbol

By employment of amino-functionalized dicarboxylate ligands to react with d10 metal ions, four novel metal-organic frameworks (MOFs) were obtained with the formula of {[Cd(BCPAB)(μ2-H2O)]}n (1), {[Cd(BDAB)]∙2H2O∙DMF}n (2), {[Zn(BDAB)(BPD)0.5(H2O)]∙2H2O}n (3) and {[Zn(BDAB)(DBPB)0.5(H2O)]∙2H2O}n (4) (H2BCPAB = 2,5-bis(p-carbonylphenyl)-1-aminobenzene; H2BDAB = 1,2-diamino-3,6-bis(4-carboxyphenyl)benzene); BPD = (4,4′-bipyridine); DBPB = (E,E-2,5-dimethoxy-1,4-bis-[2-pyridin-vinyl]-benzene; DMF = N,N-dimethylformamide). Complex 1 is a three-dimensional (3D) framework bearing seh-3,5-Pbca nets with point symbol of {4.62}{4.67.82}. Complex 2 exhibits a 4,4-connected new topology that has never been reported before with point symbol of {42.84}. Complex 3 and 4 are quite similar in structure and both have 3D supramolecular frameworks formed by 6-fold and 8-fold interpenetrated 2D coordination layers. The structures of these complexes were characterized by single crystal X-ray diffraction (SC-XRD), thermal gravimetric analysis (TGA) and powder X-ray diffraction (PXRD) measurements. In addition, the fluorescence properties and the sensing capability of 2–4 were investigated as well and the results indicated that complex 2 could function as sensor for Cu2+ and complex 3 could detect Cu2+ and Ag+via quenching effect.

Construction of Three-Dimensional Cobalt(II)-Based Metal–Organic Frameworks by Synergy between Rigid and Semirigid Ligands

2012 ◽  
Vol 12 (11) ◽  
pp. 5529-5534 ◽  
Author(s):  
Weiting Yang ◽  
Min Guo ◽  
Fei-Yan Yi ◽  
Zhong-Ming Sun
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Metal Organic

New Functionalized Metal–Organic Frameworks MIL-47-X (X = −Cl, −Br, −CH3, −CF3, −OH, −OCH3): Synthesis, Characterization, and CO2 Adsorption Properties

2013 ◽  
Vol 117 (44) ◽  
pp. 22784-22796 ◽  
Author(s):  
Shyam Biswas ◽  
Danny E. P. Vanpoucke ◽  
Toon Verstraelen ◽  
Matthias Vandichel ◽  
Sarah Couck ◽  
...  
Keyword(s):  
Co2 Adsorption ◽  
Metal Organic Frameworks ◽  
Adsorption Properties ◽  
Metal Organic
Sign in / Sign up

Export Citation Format

Share Document