Polymorphism Studied by Lattice Phonon Raman Spectroscopy and Statistical Mixture Analysis Method. Application to Calcium Carbonate Polymorphs during Batch Crystallization

2009 ◽  
Vol 9 (2) ◽  
pp. 807-812 ◽  
Author(s):  
C. Carteret ◽  
A. Dandeu ◽  
S. Moussaoui ◽  
H. Muhr ◽  
B. Humbert ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Calcium Carbonate ◽  
Analysis Method ◽  
Mixture Analysis ◽  
Batch Crystallization ◽  
Statistical Mixture ◽  
Lattice Phonon ◽  
Calcium Carbonate Polymorphs

CALCIUM CARBONATE POLYMORPHS IN FISH OTOLITHS: TOWARDS UNDERSTANDING ONTOGENETIC, ENVIRONMENTAL, AND PHYLOGENETIC CONTROLS

2018 ◽  
Author(s):  
Bryan C. Chakoumakos ◽  
◽  
Brenda M. Pracheil ◽  
R. Seth Wood ◽  
Alison Loeppky ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Fish Otoliths ◽  
Calcium Carbonate Polymorphs

Flotation behavior and mechanism of calcium carbonate polymorphs with sodium oleate as collector

2021 ◽  
pp. 117040
Author(s):  
Jingzhong Kuang ◽  
Xiaoyuan Wang ◽  
Mingming Yu ◽  
Weiquan Yuan ◽  
Zheyu Huang ◽  
...  
Keyword(s):  
Calcium Carbonate ◽  
Sodium Oleate ◽  
Flotation Behavior ◽  
Calcium Carbonate Polymorphs

scholarly journals Luminescence reveals variations in local structural order of calcium carbonate polymorphs formed by different mechanisms

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Michael B. Toffolo ◽  
Giulia Ricci ◽  
Luisa Caneve ◽  
Ifat Kaplan-Ashiri
Keyword(s):  
Infrared Spectroscopy ◽  
Calcium Carbonate ◽  
Construction Materials ◽  
Reference Database ◽  
Formation Processes ◽  
X Ray Diffraction ◽  
Structural Order ◽  
Lime Plaster ◽  
Calcium Carbonate Polymorphs

Abstract In nature, calcium carbonate (CaCO3) in the form of calcite and aragonite nucleates through different pathways including geogenic and biogenic processes. It may also occur as pyrogenic lime plaster and laboratory-precipitated crystals. All of these formation processes are conducive to different degrees of local structural order in CaCO3 crystals, with the pyrogenic and precipitated forms being the least ordered. These variations affect the manner in which crystals interact with electromagnetic radiation, and thus formation processes may be tracked using methods such as X-ray diffraction and infrared spectroscopy. Here we show that defects in the crystal structure of CaCO3 may be detected by looking at the luminescence of crystals. Using cathodoluminescence by scanning electron microscopy (SEM-CL) and laser-induced fluorescence (LIF), it is possible to discern different polymorphs and their mechanism of formation. We were thus able to determine that pyrogenic calcite and aragonite exhibit blue luminescence due to the incorporation of distortions in the crystal lattice caused by heat and rapid precipitation, in agreement with infrared spectroscopy assessments of local structural order. These results provide the first detailed reference database of SEM-CL and LIF spectra of CaCO3 standards, and find application in the characterization of optical, archaeological and construction materials.

Real-time detection of early-stage calcium sulfate and calcium carbonate scaling using Raman spectroscopy

2020 ◽  
Vol 596 ◽  
pp. 117603 ◽  
Author(s):  
Omkar D. Supekar ◽  
Danielle J. Park ◽  
Alan R. Greenberg ◽  
Juliet T. Gopinath ◽  
Victor M. Bright
Keyword(s):  
Raman Spectroscopy ◽  
Calcium Carbonate ◽  
Real Time ◽  
Calcium Sulfate ◽  
Early Stage ◽  
Real Time Detection
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