Structures and Luminescent Properties of a Series of Zinc(II) and Cadmium(II) 4,4′-Oxydiphthalate Coordination Polymers with Various Ligands Based on Bis(pyridyl imidazole) under Hydrothermal Conditions

2008 ◽  
Vol 8 (5) ◽  
pp. 1610-1616 ◽  
Author(s):  
Shun-Li Li ◽  
Ya-Qian Lan ◽  
Jian-Fang Ma ◽  
Yao-Mei Fu ◽  
Jin Yang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Luminescent Properties ◽  
Hydrothermal Conditions

Metal Ion-Driven Assembly of Two New Coordination Polymers Constructed by Asymmetric Tricarboxylate and Imidazole-Containing Ligands: Syntheses, Crystal Structures, and Luminescent Properties

2015 ◽  
Vol 68 (1) ◽  
pp. 121 ◽  
Author(s):  
Wenlong Liu ◽  
Xueying Wang ◽  
Mengqiang Wu ◽  
Bing Wang
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Dimensional Structure ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Dimethyl Benzene

Two new coordination polymers, namely, {[Cd3(bpt)2(bimb)2]·2(H2O)}n (1) and [Zn3(bpt)2(bimb)2]n (2) (bpt = biphenyl-3,4′,5-tricarboxylate, bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene), have been obtained under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterised by elemental analysis and infrared spectroscopy. Complex 1 exhibits a trinodal (4,4,4)-connected topology with Schläfli symbol of (4.62.83)4.(64.82). Complex 2 is also a three-dimensional structure and displays a (3,4,6)-connected topology with Schläfli symbol of (4.62)2.(42.66.85.102).(64.82). It is shown that the asymmetrically tricarboxylate can bear diverse structures regulated by metal ions. The photoluminescence behaviours of compounds 1 and 2 were also discussed.

Five bis(imidazole)-based Coordination Polymers Tuned by Central Metal Ions and S-containing Dicarboxylates: Syntheses, Structures, and Properties

2013 ◽  
Vol 66 (11) ◽  
pp. 1370 ◽  
Author(s):  
Xiu-Li Wang ◽  
Yun Qu ◽  
Guo-Cheng Liu ◽  
Jing-Jing Huang ◽  
Nai-Li Chen ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Dye Degradation ◽  
Luminescent Properties ◽  
Central Metal ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Structures And Properties ◽  
Ring Complex ◽  
3D Architecture

Five new coordination polymers, namely [Zn(2-CMSN)(biim-4)] (1), [Co2(2-CMSN)2(biim-4)(H2O)4] (2), [Ni(2-CMSN)(biim-4)0.5(H2O)2] (3), [Cd(2-CMSN)(biim-4)0.5(H2O)2] (4), and [Cd(ADTZ)(biim-4)1.5]·5H2O (5), (2-H2CMSN = 2-carboxymethylsulfanyl nicotinic acid, H2ADTZ = 2,5-(S-acetic acid) dimercapto-1,3,4-thiadiazole, biim-4 = 1,1′-(1,4-butanediyl)bis(imidazole)) have been synthesised under hydrothermal conditions and structurally characterised by single-crystal X-ray diffraction analysis, infrared spectroscopy, elemental analysis, thermogravimetric analysis, and powder X-ray diffraction. Complex 1 shows a 2D undulated sheet, which is constructed from 1D meso-helical [Zn-(biim-4)]n chains and linear [Zn-(2-CMSN)]n chains. Complexes 2–4 exhibit a similar 2D (4,4) grid network constructed from zigzag [M-(2-CMSN)]n chains and linear [M-(biim-4)]n chains (M = CoII, NiII and CdII), which possesses a ‘4+2’ type six-membered ring. Complex 5 displays a 3D architecture derived from 2D Cd-(biim-4) layers and double ADTZ linkers with diamond-type 66 topology. The effects of the central metals and S-containing dicarboxylates on the structures of the title coordination polymers have been discussed. The luminescent properties of complexes 1, 4, and 5 have been studied. Complex 5 exhibits photocatalytic activity for dye degradation under ultraviolet light and good stability towards photocatalysis.

Syntheses, Structures and Photoluminescent Properties of Two New Pb(II) and Cd(II) Coordination Polymers Constructed from 1,10-Phenanthroline-derived and 1,4-Naphthalenedicarboxylate Ligands

2012 ◽  
Vol 67 (1) ◽  
pp. 23-28
Author(s):  
Zhi-Guo Kong ◽  
Yu He ◽  
Na Xu ◽  
Jia Guo ◽  
Dan Li
Keyword(s):  
Coordination Polymers ◽  
Layer Structure ◽  
Luminescent Properties ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Crystal Data ◽  
Hydrothermal Conditions ◽  
Space Group ◽  
Π Interactions ◽  
A Chain

Two new related coordination polymers, namely, [Pb(L)(1,4-ndc)] · 0.5H2O (1) and [Cd(L)(1,4- ndc)] · 0.5H2O (2), where L = 2-(3-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,4- ndc = 1,4-naphthalenedicarboxylate, were synthesized under hydrothermal conditions. Crystal data for 1: C62H36F2N8O9Pb2, monoclinic space group C2/c, a = 15.874(3), b = 19.982(4), c = 16.045(3) Å, β = 94.26(3), V = 5075.3(18) Å3, Z = 4. Crystal data for 2: C62H36Cd2F2N8O9, monoclinic space group P21/n, a = 12.622(2), b = 14.038(3), c = 14.938(3) Å , β = 100.81(2), V = 2600.0(8) Å3, Z = 2. In compound 1, the 1,4-ndc ligands connect the Pb(II) atoms to yield a chain structure. The L ligands are attached on the same side of the chain. The π-π interactions between L ligands of neighboring chains result in a 2D supramolecular architecture of 1. In compound 2, 1,4-ndc ligands link the Cd(II) atoms to generate a layer structure. The L ligands from adjacent layers are paired to furnish strong π-π interactions. Further, these layers are extended into 3D supramolecular architectures through these π-π interactions. The structural differences of 1 and 2 suggest the importance of the metal centers in the construction of the coordination polymers. The luminescent properties of the compounds were also investigated.

Syntheses, Crystal Structures and Luminescence of Two Coordination Polymers Based on Isophthalic Acid and 2-(3-Pyridyl)benzimidazole Ligands

2011 ◽  
Vol 399-401 ◽  
pp. 896-899
Author(s):  
Ke Fen Yue ◽  
Shuang Zhao ◽  
Rui Li Zhao ◽  
Yao Yu Wang
Keyword(s):  
Coordination Polymers ◽  
Room Temperature ◽  
Luminescent Properties ◽  
Isophthalic Acid ◽  
Stacking Interactions ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
3D Network

Two new coordination polymers, [Zn(PyHBIm)2(IPA)]•3H2O (1), [Cd(PyHBIm)(IPA)(H2O)2]•2H2O (2), were synthesized under hydrothermal conditions based on 2-(3-pyridyl)benzimidazole (3-PyHBIm) and isophthalic acid (IPA). The complexes were characterized by single crystal X-ray diffraction. They contain simple 1D chains and can be assembled into a 3D network through aromatic π–π stacking interactions and hydrogen bonding interactions. Their luminescent properties were studied in the solid state at room temperature.

Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (22) ◽  
pp. 4783-4795 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debraj Saha ◽  
Dilip Kumar Maity ◽  
Rajdip Dey ◽  
Debajyoti Ghoshal
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Luminescent Properties ◽  
Donor Ligand ◽  
X Ray
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