A Series of Metal–Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photoluminescent, and Magnetic Properties

2013 ◽  
Vol 13 (7) ◽  
pp. 2756-2765 ◽  
Author(s):  
Shu-Na Zhao ◽  
Sheng-Qun Su ◽  
Xue-Zhi Song ◽  
Min Zhu ◽  
Zhao-Min Hao ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Organic Frameworks ◽  
Carboxylate Ligand ◽  
Metal Organic

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

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