Coordination Polymers of Copper and Zinc Ions with a Linear Linker Having Imidazole at Each End and an Azo Moiety in the Middle: Pedal Motion, Gas Adsorption, and Emission Studies

2012 ◽  
Vol 12 (10) ◽  
pp. 5025-5034 ◽  
Author(s):  
Ruchi Singh ◽  
Musheer Ahmad ◽  
Parimal K. Bharadwaj
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Zinc Ions ◽  
Copper And Zinc ◽  
Pedal Motion ◽  
Emission Studies

Syntheses, X-ray structures, gas adsorption and luminescent properties of three coordination polymers of Zn(ii) dicarboxylates mixed with a linear, neutral, and rigid N,N′-donor ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (22) ◽  
pp. 4783-4795 ◽  
Author(s):  
Biswajit Bhattacharya ◽  
Debraj Saha ◽  
Dilip Kumar Maity ◽  
Rajdip Dey ◽  
Debajyoti Ghoshal
Keyword(s):  
Coordination Polymers ◽  
Gas Adsorption ◽  
Luminescent Properties ◽  
Donor Ligand ◽  
X Ray

Directed adenine functionalization for creating complex architectures for material and biological applications

2017 ◽  
Vol 53 (35) ◽  
pp. 4748-4758 ◽  
Author(s):  
Balaram Mohapatra ◽  
Pratibha Pratibha ◽  
Sandeep Verma
Keyword(s):  
Metal Complexes ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Bioactive Molecules ◽  
Biological Applications ◽  
Design Strategies ◽  
Feature Article ◽  
Complex Architectures ◽  
Adenine Derivatives

This feature article outlines design strategies for modified adenine derivatives to construct discrete metal complexes, ring-expanded skeletons, coordination polymers, MOFs, and capped nanoparticles, for applications in gas adsorption, as bioimaging agents and as bioactive molecules.

Two Coordination Polymers Constructed from Pentanuclear Zinc Clusters with Triazolate and Benzenecarboxylate Ligands: Selective Gas Adsorption

2018 ◽  
Vol 71 (3) ◽  
pp. 111 ◽  
Author(s):  
Wen-Wen Zhang ◽  
Yu-Ling Wang ◽  
Ying Liu ◽  
Qing-Yan Liu
Keyword(s):  
Porous Structure ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
3D Structure ◽  
Co2 Uptake ◽  
N2 Adsorption ◽  
Carboxylate Oxygen ◽  
Zinc Clusters ◽  
Solvent Molecules ◽  
3D Framework

Reactions of Zn(NO3)2·6H2O with 1,2,4-triazole (Htrz) and 1,3,5-benzenetricarboxylic acid (H3BTC) or 5-sulfoisophthalic acid (5-H3SIP) afforded two coordination polymers, {[Zn5(μ3-OH)2(trz)2(BTC)2(DMF)2]·x(solvent)}n (1) and {[Zn7(trz)8(5-SIP)2(H2O)4]·4(H2O)}n (2). Compound 1 has pentanuclear [Zn5(μ3-OH)2] clusters, which are linked by the triazolate ligands to give a 2D layer. The 2D layer is further bridged by BTC3− ligands to form a 3D framework. The 3D framework of 1 has 1D channels filled by solvent molecules. Desolvated 1 shows a moderate CO2 uptake and high CO2/CH4 and CO2/N2 adsorption selectivities due to its carboxylate oxygen decorated pore environment. Compound 2 contains a rare 3D zinc-triazolate framework constructed from a pentanuclear [Zn5(trz)8] cluster wherein the five zinc atoms are arranged linearly. The 3D zinc-triazolate substructure has 1D open channels filled by 5-SIP3− ligands, which interact with the zinc-triazolate framework through Zn–O bonds, leading to a non-porous 3D structure of 2. Introduction of BTC3− into the zinc-triazolate system gave the porous structure of 1. While a variation of BTC3−, 5-SIP3− was introduced into the zinc-triazolate system yielding a non-porous structure of 2, demonstrating that the secondary ligands play an important role in the formation of the final structures.

scholarly journals The effect of carboxylate and N,N′-ditopic ligand lengths on the structures of copper and zinc coordination polymers

CrystEngComm ◽  
2012 ◽  
Vol 14 (10) ◽  
pp. 3658 ◽  
Author(s):  
Andrew D. Burrows ◽  
Mary F. Mahon ◽  
Paul R. Raithby ◽  
Anna J. Warren ◽  
Simon J. Teat ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Copper And Zinc ◽  
Zinc Coordination ◽  
Ditopic Ligand

Gram-scale synthesis of monodisperse sulfonated polystyrene nanospheres for rapid and efficient sequestration of heavy metal ions

2017 ◽  
Vol 53 (95) ◽  
pp. 12766-12769 ◽  
Author(s):  
Bin Gong ◽  
Yaotian Peng ◽  
Ziyan Pan ◽  
Weiming Chen ◽  
Yi Shen ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Large Scale ◽  
Zinc Ions ◽  
Sulfonated Polystyrene ◽  
Copper And Zinc ◽  
Polystyrene Nanospheres

Large-scale monodisperse sulfonated polystyrene nanospheres are synthesized for the removal of lead, copper and zinc ions from aqueous solutions.

Synthesis and structural characterization of homochiral coordination polymers with imidazole-based monocarboxylate ligands

2019 ◽  
Vol 48 (24) ◽  
pp. 8731-8739 ◽  
Author(s):  
Elena Borrego ◽  
Antonio I. Nicasio ◽  
Eleuterio Álvarez ◽  
Francisco Montilla ◽  
José Manuel Córdoba ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization ◽  
Two Dimensional ◽  
Bridging Ligands ◽  
Silver Copper ◽  
Copper And Zinc

Two-dimensional homochiral coordination polymers of sodium, silver, copper and zinc were obtained with 2alkyl,2-(1H-imidazol-1-yl)acetate anions as bridging ligands.

Structural diversity, gas adsorption and magnetic properties of three coordination polymers based on a rigid multicarboxylate ligand

CrystEngComm ◽  
2020 ◽  
Vol 22 (42) ◽  
pp. 7046-7053
Author(s):  
Lingling Gao ◽  
Yongjun Bian ◽  
Yuan Tian ◽  
Yongqiang Chen ◽  
Tuoping Hu
Keyword(s):  
Magnetic Properties ◽  
Benzoic Acid ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
Structural Diversity ◽  
Acid Ligand

A pictogram: the gas adsorption and magnetic properties of three Co(ii) coordination polymers constructed from 3,5-di(2′,5′-dicarboxylphenyl)benzoic acid ligand have been explored.

A Study on the Coordination of Fully Substituted Cyclopentano Cucurbit[5, 6]uril with Copper and Zinc Ions

2019 ◽  
Vol 4 (40) ◽  
pp. 11674-11677 ◽  
Author(s):  
Wei Wei Zhao ◽  
Lian Tong Wei ◽  
Kai Zhi Zhou ◽  
Ming Hua Chen ◽  
Si Yuan Cheng ◽  
...  
Keyword(s):  
Zinc Ions ◽  
Copper And Zinc
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