Two Unprecedented Transition-Metal–Organic Frameworks Showing One Dimensional-Hexagonal Channel Open Network and Two-Dimensional Sheet Structures

2012 ◽  
Vol 12 (3) ◽  
pp. 1091-1094 ◽  
Author(s):  
Chengjie Wang ◽  
Tao Wang ◽  
Wan Zhang ◽  
Huijie Lu ◽  
Gang Li
Keyword(s):  
Transition Metal ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
One Dimensional ◽  
Open Network ◽  
Metal Organic

Structural variation of transition metal–organic frameworks using deep eutectic solvents with different hydrogen bond donors

2019 ◽  
Vol 48 (27) ◽  
pp. 10199-10209 ◽  
Author(s):  
Ming-Yu Zhao ◽  
Jian-Nan Zhu ◽  
Peng Li ◽  
Wei Li ◽  
Ting Cai ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Structural Variation ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Deep Eutectic Solvents ◽  
One Dimensional ◽  
Metal Organic ◽  
Hydrogen Bond Donors

Seven transition metal–organic frameworks with structures ranging from one-dimensional chains to three-dimensional networks have been synthesized in deep eutectic solvents.

Novel One-Dimensional Tubelike and Two-Dimensional Polycatenated Metal−Organic Frameworks

2003 ◽  
Vol 42 (1) ◽  
pp. 158-162 ◽  
Author(s):  
Jian Fan ◽  
Hui-Fang Zhu ◽  
Taka-aki Okamura ◽  
Wei-Yin Sun ◽  
Wen-Xia Tang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
One Dimensional ◽  
Metal Organic

Two new NiII and ZnII metal–organic frameworks of glutarate and 1,4-bis[(2-methyl-1H-imidazol-1-yl)methyl]benzene ligands: syntheses, structures and luminescence sensing properties

2020 ◽  
Vol 76 (2) ◽  
pp. 148-158
Author(s):  
Fang-Hua Zhao ◽  
Zhong-Lin Li ◽  
Shu-Fang Zhang ◽  
Jian-Hui Han ◽  
Mei Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Vis Spectroscopy ◽  
Metal Organic ◽  
3D Framework ◽  
Methyl Benzene

Two new metal–organic frameworks (MOFs), namely, three-dimensional poly[diaquabis{μ2-1,4-bis[(2-methyl-1H-imidazol-1-yl)methyl]benzene}bis(μ2-glutarato)dinickel(II)] monohydrate], {[Ni2(C5H6O4)2(C16H18N4)2(H2O)2]·H2O} n or {[Ni2(Glu)2(1,4-mbix)2(H2O)2]·H2O} n , (I), and two-dimensional poly[[{μ2-1,4-bis[(2-methyl-1H-imidazol-1-yl)methyl]benzene}(μ2-glutarato)zinc(II)] tetrahydrate], {[Zn(C5H6O4)(C16H18N4)]·4H2O} n or {[Zn(Glu)(1,4-mbix)]·4H2O} n (II), have been synthesized hydrothermally using glutarate (Glu2−) mixed with 1,4-bis[(2-methyl-1H-imidazol-1-yl)methyl]benzene (1,4-mbix), and characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, powder X-ray diffraction, and thermogravimetric and photoluminescence analyses. NiII MOF (I) shows a 4-connected 3D framework with point symbol 66, but is not a typical dia network. ZnII MOF (II) displays a two-dimensional 44-sql network with one-dimensional water chains penetrating the grids along the c direction. The solid-state photoluminescence analysis of (II) was performed at room temperature and the MOF exhibits highly selective sensing toward Fe3+ and Cr2O7 2− ions in aqueous solution.

Two-dimensional transition metal dichalcogenides as metal sources of metal–organic frameworks

2018 ◽  
Vol 54 (29) ◽  
pp. 3664-3667 ◽  
Author(s):  
Yanwei Sun ◽  
Shen Hu ◽  
Chunshan Song ◽  
Shu Miao ◽  
Zhou Jiang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Organic Frameworks ◽  
Transition Metal Dichalcogenides ◽  
Two Dimensional ◽  
Metal Sources ◽  
Metal Precursors ◽  
Metal Dichalcogenides ◽  
Metal Organic

It was found that transition metal dichalcogenides could serve as competent metal precursors of metal–organic frameworks with several obvious advantages.

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