Solvent-Free Polymorphism Control in a Covalent Mechanochemical Reaction

2011 ◽  
Vol 12 (1) ◽  
pp. 44-48 ◽  
Author(s):  
Dominik Cinčić ◽  
Ivana Brekalo ◽  
Branko Kaitner
Keyword(s):  
Solvent Free ◽  
Mechanochemical Reaction

An analytical model for mechanochemical reaction kinetics

2021 ◽  
Author(s):  
Maria Carta ◽  
Francesco Delogu ◽  
Andrea Porcheddu
Keyword(s):  
Reaction Kinetics ◽  
Analytical Model ◽  
Chemical Reactions ◽  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Synthetic Routes ◽  
Chemical Products

With its ability to enable solvent-free chemical reactions, mechanochemistry promises to open new and greener synthetic routes to chemical products of industrial interest. Its practical exploitation requires understanding the relationships...

Solvent-free iodine-promoted synthesis of 3,2′-pyrrolinyl spirooxindoles from alkylidene oxindoles and enamino esters under ball-milling conditions

2017 ◽  
Vol 53 (92) ◽  
pp. 12477-12480 ◽  
Author(s):  
Hui Xu ◽  
Hong-Wei Liu ◽  
Hao-Sheng Lin ◽  
Guan-Wu Wang
Keyword(s):  
Ball Milling ◽  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Free Iodine

A solvent-free mechanochemical reaction of alkylidene oxindoles with enamino esters via an iodine-promoted tandem Michael/cyclization sequence has been developed to provide a variety of spirocyclic oxindoles in moderate to good yields with excellent diastereoselectivities.

scholarly journals Recyclable heterogeneous metal foil-catalyzed cyclopropenation of alkynes and diazoacetates under solvent-free mechanochemical reaction conditions

2018 ◽  
Vol 9 (20) ◽  
pp. 4650-4661 ◽  
Author(s):  
Longrui Chen ◽  
Devonna Leslie ◽  
Michael G. Coleman ◽  
James Mack
Keyword(s):  
Copper Foil ◽  
Heterogeneous Catalysts ◽  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Metal Foil ◽  
Reaction Conditions ◽  
Internal Alkynes

Silver and copper foil were found to be effective, versatile and selective heterogeneous catalysts for the cyclopropenation of terminal and internal alkynes under mechanochemical reaction conditions.

Solvent-Free and Liquid-Phase Iodination of Thiophene Derivatives with Potassium Dichloroiodate Monohydrate

Synthesis ◽  
2020 ◽  
Vol 52 (07) ◽  
pp. 1140-1146
Author(s):  
Grigoriy Sereda ◽  
Akash Mamon Sarkar ◽  
Anwar Hussain ◽  
Nikolai Zefirov
Keyword(s):  
Liquid Phase ◽  
Small Extent ◽  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Benzene Derivatives ◽  
Solvent Free Conditions ◽  
Solid Substrates ◽  
Thiophene Derivatives

Iodination of a series of benzene and thiophene derivatives by potassium dichloroiodate monohydrate was studied with and without a solvent. The liquid substrates tend to be more reactive in water while the solid substrates afford better yields in dichloromethane or under the solvent-free conditions. The 2-substituted thiophenes show good to excellent yields whereas the yield for 3-substituted and 3,4- or 2,4-disubstituted thiophenes and benzene derivatives are significantly lower. The mechanochemical reaction of 5-carbaldehyde-2,2′-bithiophene shows excellent yields, while 2,2′-bithiophene gives practical yields only in dichloromethane. In the case of thiophene and N-acetyl-p-toluidine, electrophilic iodination is accompanied by a small extent of chlorination.

scholarly journals Nitrate Ion-Incorporated Stable Perovskite Nanocrystals by a Solvent-Free Mechanochemical Reaction

ACS Omega ◽  
2019 ◽  
Vol 4 (13) ◽  
pp. 15678-15683 ◽  
Author(s):  
Gaurav Kumar Nim ◽  
Parul Bansal ◽  
Prasenjit Kar
Keyword(s):  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Nitrate Ion ◽  
Perovskite Nanocrystals

Synthesis of Ni-based fluoroperovskites by solvent-free mechanochemical reaction

2021 ◽  
Author(s):  
Jin San Choi ◽  
Muhammad Sheeraz ◽  
Fazli Akram ◽  
Hyoung-Su Han ◽  
Jae-Shin Lee ◽  
...  
Keyword(s):  
Solvent Free ◽  
Mechanochemical Reaction

Comparative studies on conventional and solvent-free synthesis toward hydrazones: application of PXRD and chemometric data analysis in mechanochemical reaction monitoring

CrystEngComm ◽  
2018 ◽  
Vol 20 (13) ◽  
pp. 1804-1817 ◽  
Author(s):  
Jana Pisk ◽  
Tomica Hrenar ◽  
Mirta Rubčić ◽  
Gordana Pavlović ◽  
Vladimir Damjanović ◽  
...  
Keyword(s):  
Data Analysis ◽  
Mechanochemical Synthesis ◽  
Comparative Studies ◽  
Chemometric Analysis ◽  
Solvent Free ◽  
Mechanochemical Reaction ◽  
Reaction Monitoring ◽  
Solvent Free Synthesis

We describe the implementation of chemometric analysis for mechanochemical synthesis monitoring.

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