A New Family of 3d–4f Heterometallic Tetrazole-based Coordination Frameworks: In Situ Tetrazole Ligand Synthesis, Structure, Luminescence, and Magnetic Properties

2012 ◽  
Vol 12 (3) ◽  
pp. 1151-1158 ◽  
Author(s):  
Li Liang ◽  
Guo Peng ◽  
Li Ma ◽  
Lin Sun ◽  
Hong Deng ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
New Family ◽  
Ligand Synthesis ◽  
Coordination Frameworks

In Situ Tetrazole Ligand Synthesis of Two-Fold Interpenetrating Zinc Coordination Frameworks

2011 ◽  
Vol 2011 (23) ◽  
pp. 3446-3453 ◽  
Author(s):  
Li Ma ◽  
Yong-Cai Qiu ◽  
Guo Peng ◽  
Jin-Biao Cai ◽  
Hong Deng
Keyword(s):  
Zinc Coordination ◽  
Ligand Synthesis ◽  
Coordination Frameworks

Zinc and cadmium metal-directed coordination polymers: in situ flexible tetrazole ligand synthesis, structures, and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (30) ◽  
pp. 5814-5831 ◽  
Author(s):  
Ruo Ting Dong ◽  
Zhao Ying Ma ◽  
Li Xin Chen ◽  
Lan Fen Huang ◽  
Qian Hong Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Conditions ◽  
Structures And Properties ◽  
Cadmium Metal ◽  
Ligand Synthesis ◽  
Coordination Frameworks

Seven zinc and cadmium coordination frameworks were obtained through in situ tetrazole synthesis. By varying the hydrothermal conditions the unprecedented generation of tetrazole ligands were achieved.

Construction of two mercury(II) coordination frameworks involving in situ tetrazole ligand synthesis

2010 ◽  
Vol 13 (6) ◽  
pp. 749-752 ◽  
Author(s):  
Yongcai Qiu ◽  
Biao Liu ◽  
Guo Peng ◽  
Jinbiao Cai ◽  
Hong Deng ◽  
...  
Keyword(s):  
Ligand Synthesis ◽  
Coordination Frameworks

scholarly journals Magnetocaloric Ln(HCO2)(C2O4) frameworks: Synthesis, Structure and Magnetic Properties

2021 ◽  
Author(s):  
Mario Falsaperna ◽  
Gavin B G Stenning ◽  
Ivan da Silva ◽  
Paul James Saines
Keyword(s):  
Magnetic Properties ◽  
Orthorhombic Structure ◽  
One Dimensional ◽  
Coordination Frameworks

This study probes the structure and the magnetic properties of members of the Ln(HCO2)(C2O4) (Ln = Sm3+-Er3+) family of coordination frameworks. These frameworks adopt a Pnma orthorhombic structure with one-dimensional...

In situ synthesis of iron-filled nitrogen-doped carbon nanotubes and their magnetic properties

Carbon ◽  
2013 ◽  
Vol 61 ◽  
pp. 647-649 ◽  
Author(s):  
Qingze Jiao ◽  
Liang Hao ◽  
Qingyan Shao ◽  
Yun Zhao
Keyword(s):  
Carbon Nanotubes ◽  
Magnetic Properties ◽  
In Situ Synthesis ◽  
Nitrogen Doped ◽  
Nitrogen Doped Carbon

scholarly journals Thin film bi-epitaxy and transition characteristics of TiO2/TiN buffered VO2 on Si(100) substrates

MRS Advances ◽  
2016 ◽  
Vol 1 (37) ◽  
pp. 2635-2640 ◽  
Author(s):  
Adele Moatti ◽  
Reza Bayati ◽  
Srinivasa Rao Singamaneni ◽  
Jagdish Narayan
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Magnetic Properties ◽  
Frequency Factor ◽  
Misfit Strain ◽  
Buffer Layers ◽  
Intrinsic Defects ◽  
Domain Matching Epitaxy ◽  
Out Of Plane

ABSTRACTBi-epitaxial VO2 thin films with [011] out-of-plane orientation were integrated with Si(100) substrates through TiO2/TiN buffer layers. At the first step, TiN is grown epitaxially on Si(100), where a cube-on-cube epitaxy is achieved. Then, TiN was oxidized in-situ ending up having epitaxial r-TiO2. Finally, VO2 was deposited on top of TiO2. The alignment across the interfaces was stablished as VO2(011)║TiO2(110)║TiN(100)║Si(100) and VO2(110) /VO2(010)║TiO2(011)║TiN(112)║Si(112). The inter-planar spacing of VO2(010) and TiO2(011) equal to 2.26 and 2.50 Å, respectively. This results in a 9.78% tensile misfit strain in VO2(010) lattice which relaxes through 9/10 alteration domains with a frequency factor of 0.5, according to the domain matching epitaxy paradigm. Also, the inter-planar spacing of VO2(011) and TiO2(011) equals to 3.19 and 2.50 Å, respectively. This results in a 27.6% compressive misfit strain in VO2(011) lattice which relaxes through 3/4 alteration domains with a frequency factor of 0.57. We studied semiconductor to metal transition characteristics of VO2/TiO2/TiN/Si heterostructures and established a correlation between intrinsic defects and magnetic properties.

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