Kinetically Controlled Homogenization and Transformation of Crystalline Fiber Networks in Supramolecular Materials

2011 ◽  
Vol 11 (7) ◽  
pp. 3227-3234 ◽  
Author(s):  
Jing-Liang Li ◽  
Bing Yuan ◽  
Xiang-Yang Liu ◽  
Xun-Gai Wang ◽  
Rong-Yao Wang
2002 ◽  
Vol 124 (50) ◽  
pp. 15055-15063 ◽  
Author(s):  
Xiang Yang Liu ◽  
Prashant D. Sawant ◽  
Wee Beng Tan ◽  
I. B. M. Noor ◽  
C. Pramesti ◽  
...  

2019 ◽  
Author(s):  
Terry Gani ◽  
Michael Orella ◽  
Eric Anderson ◽  
Michael Stone ◽  
Fikile Brushett ◽  
...  

Lignin is an abundant biopolymer important for plant function while holding promise as a renewable source of valuable chemicals. Although the lignification process in plant cell walls has been long-studied, a comprehensive, mechanistic understanding on the molecular scale remains elusive. A better understanding of lignification will lead to improved atomistic models of the plant cell wall that could, in turn, inform effective strategies for biomass valorization. Here, using first-principles quantum chemical calculations, we show that a simple model of kinetically-controlled radical coupling broadly rationalizes qualitative experimental observations of lignin structure across a wide variety of biomass types, thus paving the way for predictive, first-principles models of lignification while highlighting the ability of computational chemistry to help illuminate complex biological processes.


2009 ◽  
Vol 25 (1) ◽  
pp. 63-67
Author(s):  
Hao-Yang XIONG ◽  
Bin-Bin HU ◽  
Zhong-Hui XUE ◽  
Li CAI ◽  
Shu-Xi DAI ◽  
...  

2014 ◽  
Vol 18 (15) ◽  
pp. 1937-1947 ◽  
Author(s):  
Li Ma ◽  
Changjiang Zhou ◽  
Quanzhu Yang ◽  
Xiaogang Yang ◽  
Chao Zhang ◽  
...  

2011 ◽  
Vol 1 (3) ◽  
pp. 169-180 ◽  
Author(s):  
Debdas Ray ◽  
Chih-Kai Liang ◽  
Nathan D. McClenaghan ◽  
Dario M. Bassani

1981 ◽  
Vol 46 (11) ◽  
pp. 2669-2675 ◽  
Author(s):  
Ivo Paseka

Hydrogenation of nitrogen oxide in acid solutions on Pt-C catalysts proceeds in dependence on experimental conditions either in purely diffusion region or in the diffusion and kinetically controlled region. The boundary between these two processes shifts to the higher ratio of NO to H2 partial pressures with increasing platinum content and decreasing intensity of agitation.


2021 ◽  
Vol 10 (8) ◽  
pp. 2170039
Author(s):  
Yuanbo Jia ◽  
Yanzhong Wang ◽  
Lele Niu ◽  
Hang Zhang ◽  
Jin Tian ◽  
...  

Soft Matter ◽  
2021 ◽  
Author(s):  
Brian Tighe ◽  
Karsten Baumgarten

We determine how low frequency vibrational modes control the elastic shear modulus of Mikado networks, a minimal mechanical model for semi-flexible fiber networks. From prior work it is known that...


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