Dependence of Si-Faceted Dendrite Growth Orientation on Twin Spacing and Undercooling

2011 ◽  
Vol 11 (4) ◽  
pp. 1402-1410 ◽  
Author(s):  
Xinbo Yang ◽  
K. Fujiwara ◽  
K. Maeda ◽  
J. Nozawa ◽  
H. Koizumi ◽  
...  
2018 ◽  
Vol 28 (2) ◽  
pp. 290-297 ◽  
Author(s):  
Zhi CHEN ◽  
Pei CHEN ◽  
He-he GONG ◽  
Pei-pei DUAN ◽  
Li-mei HAO ◽  
...  

2012 ◽  
Vol 60 (8) ◽  
pp. 3259-3267 ◽  
Author(s):  
Xinbo Yang ◽  
K. Fujiwara ◽  
R. Gotoh ◽  
K. Maeda ◽  
J. Nozawa ◽  
...  

2008 ◽  
Vol 56 (11) ◽  
pp. 2663-2668 ◽  
Author(s):  
Kozo Fujiwara ◽  
Kensaku Maeda ◽  
Noritaka Usami ◽  
Gen Sazaki ◽  
Yoshitaro Nose ◽  
...  

2019 ◽  
Vol 168 ◽  
pp. 56-60 ◽  
Author(s):  
Keiji Shiga ◽  
Masato Kawano ◽  
Kensaku Maeda ◽  
Haruhiko Morito ◽  
Kozo Fujiwara

2011 ◽  
Vol 98 (1) ◽  
pp. 012113 ◽  
Author(s):  
Xinbo Yang ◽  
K. Fujiwara ◽  
K. Maeda ◽  
J. Nozawa ◽  
H. Koizumi ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Dan Luo ◽  
Lei Zheng ◽  
Zhen Zhang ◽  
Matthew Li ◽  
Zhongwei Chen ◽  
...  

AbstractStable solid electrolyte interface (SEI) is highly sought after for lithium metal batteries (LMB) owing to its efficient electrolyte consumption suppression and Li dendrite growth inhibition. However, current design strategies can hardly endow a multifunctional SEI formation due to the non-uniform, low flexible film formation and limited capability to alter Li nucleation/growth orientation, which results in unconstrained dendrite growth and short cycling stability. Herein, we present a novel strategy to employ electrolyte additives containing catechol and acrylic groups to construct a stable multifunctional SEI by in-situ anionic polymerization. This self-smoothing and robust SEI offers multiple sites for Li adsorption and steric repulsion to constrain nucleation/growth process, leading to homogenized Li nanosphere formation. This isotropic nanosphere offers non-preferred Li growth orientation, rendering uniform Li deposition to achieve a dendrite-free anode. Attributed to these superiorities, a remarkable cycling performance can be obtained, i.e., high current density up to 10 mA cm−2, ultra-long cycle life over 8500 hrs operation, high cumulative capacity over 4.25 Ah cm−2 and stable cycling under 60 °C. A prolonged lifespan can also be achieved in Li-S and Li-LiFePO4 cells under lean electrolyte content, low N/P ratio or high temperature conditions. This facile strategy also promotes the practical application of LMB and enlightens the SEI design in related fields.


2012 ◽  
Vol 268-270 ◽  
pp. 352-355 ◽  
Author(s):  
Xun Feng Yuan ◽  
Bao Ying Liu

The phase-field model coupling with the concentration field and flow field was used to simulate the dendrite growth during isothermal solidification of Fe-C alloy in a forced flow. The effects of anisotropy modulus and anisotropy strength on the dendrite growth are studied. The results indicate that the dendrites have four preferential growth orientation and the side-branches growth is not perpendicular to the primary branch while the dendrite along with crystallographic directions. When the dendrite along with crystallographic directions, the dendrites have six preferential growth orientation and the side-branches are parallel to the neighborly primary branch. At a anisotropy strength of 0.01, the crystal have no apparent principal branch and grows into coral shapes.With an increase in anisotropy strength, the tip solute concentration decreases, makes the dendrite growth become fast, the tip velocity increased continuously.


2011 ◽  
Vol 109 (8) ◽  
pp. 083527 ◽  
Author(s):  
Noritaka Usami ◽  
Isao Takahashi ◽  
Kentaro Kutsukake ◽  
Kozo Fujiwara ◽  
Kazuo Nakajima

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