Ligand-Directed and pH-Controlled Assembly of Chiral 3d−3d Heterometallic Metal−Organic Frameworks

2010 ◽  
Vol 10 (8) ◽  
pp. 3515-3521 ◽  
Author(s):  
Zhi Su ◽  
Jian Fan ◽  
Taka-aki Okamura ◽  
Wei-Yin Sun ◽  
Norikazu Ueyama
Keyword(s):  
Metal Organic Frameworks ◽  
Controlled Assembly ◽  
Metal Organic ◽  
Ph Controlled

scholarly journals pH-Controlled Assembly of 3D and 2D Zinc-Based Metal-Organic Frameworks with Tetrazole Ligands

ACS Omega ◽  
2018 ◽  
Vol 3 (1) ◽  
pp. 801-807 ◽  
Author(s):  
Ignacio Chi-Durán ◽  
Javier Enríquez ◽  
Carolina Manquian ◽  
Kerry Wrighton-Araneda ◽  
Walter Cañon-Mancisidor ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Controlled Assembly ◽  
Metal Organic ◽  
Ph Controlled

scholarly journals Solvent-Controlled Assembly of Ionic Metal–Organic Frameworks Based on Indium and Tetracarboxylate Ligand: Topology Variety and Gas Sorption Properties

2016 ◽  
Vol 16 (9) ◽  
pp. 5554-5562 ◽  
Author(s):  
Bing Zheng ◽  
Xiaodong Sun ◽  
Guanghua Li ◽  
Amy J. Cairns ◽  
Victor Ch. Kravtsov ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Controlled Assembly ◽  
Metal Organic

Ligand-directed and solvent-controlled assembly of six novel functional supramolecular metal–organic frameworks

2012 ◽  
Vol 25 ◽  
pp. 96-102 ◽  
Author(s):  
Xia Zhao ◽  
Xiao-Ping Ye ◽  
Li-Mei Chang ◽  
Chu-Jun Chen ◽  
Jin-Ying Gao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Controlled Assembly ◽  
Metal Organic

Discovery of precise pH-controlled biomimetic catalysts: defective zirconium metal–organic frameworks as alkaline phosphatase mimics

Nanoscale ◽  
2019 ◽  
Vol 11 (23) ◽  
pp. 11270-11278 ◽  
Author(s):  
Ming Xu ◽  
Liang Feng ◽  
Li-Na Yan ◽  
Sha-Sha Meng ◽  
Shuai Yuan ◽  
...  
Keyword(s):  
Alkaline Phosphatase ◽  
Metal Organic Frameworks ◽  
Biomimetic Catalysts ◽  
Biomimetic Catalysis ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Ph Controlled

Defective zirconium metal–organic frameworks as artificial alkaline phosphatase mimics in precise pH-controlled biomimetic catalysis.

Controlled assembly of zero-, one- and two-dimensional metal-organic frameworks involving in situ ligand synthesis under different reaction pH

Polyhedron ◽  
2008 ◽  
Vol 27 (11) ◽  
pp. 2327-2336 ◽  
Author(s):  
Guang-Xiang Liu ◽  
Rong-Yi Huang ◽  
Heng Xu ◽  
Xue-Jun Kong ◽  
Liang-Fang Huang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Controlled Assembly ◽  
Metal Organic ◽  
Ligand Synthesis

scholarly journals Controlled Assembly of Luminescent Lanthanide-Organic Frameworks via Post-Treatment of 3D-Printed Objects

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Jiahui Huang ◽  
Peiyi Wu
Keyword(s):  
Large Scale ◽  
Metal Organic Frameworks ◽  
Organic Ligand ◽  
Functional Materials ◽  
Lanthanide Ions ◽  
Controlled Assembly ◽  
Sensing Platform ◽  
3D Assembly ◽  
Metal Organic ◽  
3D Printed

Abstract Complex multiscale assemblies of metal–organic frameworks are essential in the construction of large-scale optical platforms but often restricted by their bulk nature and conventional techniques. The integration of nanomaterials and 3D printing technologies allows the fabrication of multiscale functional architectures. Our study reports a unique method of controlled 3D assembly purely relying on the post-printing treatment of printed constructs. By immersing a 3D-printed patterned construct consisting of organic ligand in a solution of lanthanide ions, in situ growth of lanthanide metal–organic frameworks (LnMOFs) can rapidly occur, resulting in macroscopic assemblies and tunable fluorescence properties. This phenomenon, caused by coordination and chelation of lanthanide ions, also renders a sub-millimeter resolution and high shape fidelity. As a proof of concept, a type of 3D assembled LnMOFs-based optical sensing platform has demonstrated the feasibility in response to small molecules such as acetone. It is anticipated that the facile printing and design approach developed in this work can be applied to fabricate bespoke multiscale architectures of functional materials with controlled assembly, bringing a realistic and economic prospect.

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