Three-Dimensional Metal−Organic Network Architecture with Large π-Conjugated Indolocarbazole Derivative: Synthesis, Supramolecular Structure, and Highly Enhanced Fluorescence

2008 ◽  
Vol 8 (1) ◽  
pp. 259-264 ◽  
Author(s):  
Hui-Jun Liu ◽  
Xu-Tang Tao ◽  
Jia-Xiang Yang ◽  
Yun-Xing Yan ◽  
Yan Ren ◽  
...  
Keyword(s):  
Supramolecular Structure ◽  
Network Architecture ◽  
Three Dimensional ◽  
Enhanced Fluorescence ◽  
Metal Organic

Enhanced fluorescence by increasing dimensionality: a novel three-dimensional luminescent metal–organic framework with rigidified ligands

CrystEngComm ◽  
2020 ◽  
Vol 22 (36) ◽  
pp. 5946-5948
Author(s):  
Yuhan Lin ◽  
Liang Yu ◽  
Hao Wang ◽  
Jing Li
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Enhanced Fluorescence ◽  
Structural Dimensionality ◽  
Metal Organic ◽  
Organic Chromophore ◽  
Organic Framework

A novel 3D luminescent MOF has been developed by the incorporation of an organic chromophore, demonstrating the photoluminescence of MOFs can be greatly enhanced by increasing their structural dimensionality.

Synthesis and crystal structures of two coordination polymers and a binuclear cadmium(II) complex containing 3- and 4-aminobenzoate ligands

2015 ◽  
Vol 71 (8) ◽  
pp. 673-678 ◽  
Author(s):  
Dong-Mei Zhou ◽  
Xiao-Lan Zhao ◽  
Feng-Yi Liu ◽  
Jun-Feng Kou
Keyword(s):  
Hydrogen Bonds ◽  
Supramolecular Structure ◽  
Three Dimensional ◽  
Chain Structure ◽  
Complex Iii ◽  
One Dimensional ◽  
Binuclear Molecule ◽  
Wide Range ◽  
Anionic Ligands ◽  
Metal Organic

Due to their wide range of coordination modes and versatile conformations when binding to metal atoms, multicarboxylate ligands are of interest in the design of metal–organic frameworks (MOFs). Three CdIIcomplexes, namelycatena-poly[diammonium [[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-bis(μ-3-aminobenzoato)-κ3N:O,O′;κ3O,O′:N]], {(NH4)[CdCl2(C7H6NO2)]}n, (I),catena-poly[[[aquacadmium(II)]-bis(μ-4-aminobenzoato)-κ3N:O,O′;κ3O,O′:N] monohydrate], {[Cd(C7H6NO2)2(H2O)]·H2O}n, (II), and di-μ-acetato-κ4O:O′-bis[(4-aminobenzoato-κ2O,O′)(2,2′-bipyridine-κ2N,N′)cadmium(II)], [Cd2(CH3COO)2(C7H6NO2)2(C10H8N2)2], (III), with different stuctural forms are reported. Complex (I) has a one-dimensional ladder structure, with strong N—H...O and weak N—H...Cl hydrogen bonds linking the cations and anions in the three-dimensional supramolecular structure. Complex (II) has a one-dimensional chain structure. Extensive O—H...O and N—H...O hydrogen bonds between the anionic ligands and the solvent water molecules and π–π stacking interactions between the centroids of the benzene rings lead to the three-dimensional supramolecular structure. Complex (III) is a binuclear molecule which is extended into a three-dimensional supramolecular structureviastrong N—H...O and weak C—H...O hydrogen bonds.

Molecular Engineering in a Family of Pillared-Layered Metal Organic Frameworks for Tuning Gas Adsorption Behavior

2021 ◽  
Author(s):  
Shuai Liang ◽  
Fa-Yuan Ge ◽  
Shuang-Shuang Ren ◽  
Ming-Yuan Lei ◽  
Xiang-Jing Gao ◽  
...  
Keyword(s):  
Supramolecular Structure ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Mixed Ligand ◽  
Molecular Engineering ◽  
Adsorption Behavior ◽  
Metal Organic ◽  
Layered Matrix

In this work, inspired by a water-assisted three-dimensional supramolecular structure 1, we use a mixed-ligand strategy to form a 3D pillared-layered matrix by introduction of linear ligands to compete against...

Efficient chemosensors for toxic pollutants based on photoluminescent Zn(II) and Cd(II) metal-organic networks

2021 ◽  
Author(s):  
Luis David Rosales-Vazquez ◽  
Alejandro Dorazco-González ◽  
Victor Sanchez-Mendieta
Keyword(s):  
Optical Sensors ◽  
Three Dimensional ◽  
High Sensitivity ◽  
Environmental Research ◽  
Toxic Pollutants ◽  
Sensitivity And Selectivity ◽  
Metal Organic ◽  
Analytical Tools ◽  
Organic Networks

Optical sensors with high sensitivity and selectivity, as important analytical tools for chemical and environmental research, can be accomplished by straightforward synthesis of luminescent one-, two- and three-dimensional Zn(II) and...

Ingan Quantum Dots Fabricated On Aigan Surfaces -Growth Mechanism And Optical Propertiesh-

1997 ◽  
Vol 482 ◽  
Author(s):  
H. Hirayama ◽  
S. Tanaka ◽  
P. Ramvall ◽  
Y. Aoyagi
Keyword(s):  
Quantum Dots ◽  
Three Dimensional ◽  
Chemical Vapor ◽  
Energy Shift ◽  
Organic Chemical ◽  
Self Assembling ◽  
Atomic Force ◽  
Peak Energy ◽  
Metal Organic ◽  
Organic Chemical Vapor Deposition

AbstractWe demonstrate photoluminescence from self- assembling InGaN quantum dots (QDs), which are artificially fabricated on AlGaN surfaces via metal- organic chemical vapor deposition. InGaN QDs are successfully fabricated by the growth mode transition from step- flow to three dimensional island formation by using anti-surfactant silicon on AlGaN surface. The diameter and height of the fabricated InGaN QDs are estimated to be ˜10nm and ˜5nm, respectively, by an atomic- force- microscope (AFM). Indium mole fraction of InxGal−x N QDs is controlled from x=˜0.22 to ˜0.52 by varying the growth temperature of QDs. Intense photoluminescence is observed even at room temperature from InGaN QDs embedded with the GaN capping layers. In addition, the temperature- dependent energy shift of the photoluminescence peak- energy shows a localization behavior.

Three-dimensional hierarchical C-Co-N/Se derived from metal-organic framework as superior cathode for Li-Se batteries

2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Metal Organic ◽  
Organic Framework

A New POM-Based Supramolecular Compound: Synthesis, Structure and Adsorptive Property of [Cu(phen)2]3[W6O19]

2014 ◽  
Vol 919-921 ◽  
pp. 2013-2016 ◽  
Author(s):  
Ya Bing Liu ◽  
Hong Jie Wang ◽  
Hong Kai Zhao
Keyword(s):  
Three Dimensional ◽  
Building Blocks ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Adsorptive Property ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Compound Synthesis ◽  
Metal Organic

A POM - based organice - inorganic hybrid compound with the chemical formula of[Cu (phen)2]3[W6O19] (phen = 1,10-phenanthroline) (1) has been hydrothermally synthesized andstructurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space groupC2/c witha=18.319(4) Å,b= 17.311(4) Å,c= 22.248(4) Å,β= 112.40(3) o,V= 6523(2) Å3,Z= 4, R1= 0.0448, andwR2=0.1218. Compound 1 consists of the [W6O19]3-building blocks and [Cu (phen)2]+metal organic cationic moieties, which are packed together via the extensive hydrogen-bonding interactions to form a three-dimensional supramolecular framework. The adsorption of methylene blue (MB) under UV irradiation with 1 as the heterogeneous adsorbent has been investigated, showing a good adsorptive property of 1 for MB degradation.

Sign in / Sign up

Export Citation Format

Share Document