Supramolecular Isomerism in Self-Assembled Complexes from 4,4‘-Dipyridyl Disulfide and M(hfac)2:  Coordination Polymers (M = Mn) and Metallamacrocycles (M = Co, Ni)

2005 ◽  
Vol 5 (1) ◽  
pp. 243-249 ◽  
Author(s):  
Ryo Horikoshi ◽  
Tomoyuki Mochida ◽  
Makoto Kurihara ◽  
Masahiro Mikuriya
Keyword(s):  
Coordination Polymers ◽  
Supramolecular Isomerism ◽  
Assembled Complexes ◽  
Self Assembled ◽  
Dipyridyl Disulfide

scholarly journals Back Cover: Ferroelectric Coordination Polymers Self-Assembled from Mesogenic Zinc(II) Porphyrin and Dipolar Bridging Ligands (Chem. Eur. J. 40/2016)

2016 ◽  
Vol 22 (40) ◽  
pp. 14408-14408
Author(s):  
Joseph K.-H. Hui ◽  
Hiroyuki Kishida ◽  
Keita Ishiba ◽  
Kenta Takemasu ◽  
Masa-aki Morikawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Bridging Ligands ◽  
Back Cover ◽  
Self Assembled

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Square-grid coordination networks of (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) in its clathrate with two guest molecules of 1,2-dichlorobenzene: supramolecular isomerism of the porphyrin self-assembly

2009 ◽  
Vol 65 (3) ◽  
pp. m139-m142 ◽  
Author(s):  
Rajesh Koner ◽  
Israel Goldberg
Keyword(s):  
Self Assembly ◽  
Metal Ion ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Coordination Networks ◽  
Guest Molecules ◽  
Square Grid ◽  
Supramolecular Isomerism ◽  
Self Assembled ◽  
Solvent Molecules

The title compound, (5,10,15,20-tetra-4-pyridylporphyrinato)zinc(II) 1,2-dichlorobenzene disolvate, [Zn(C40H24N8)]·2C6H4Cl2, contains a clathrate-type structure. It is composed of two-dimensional square-grid coordination networks of the self-assembled porphyrin moiety, which are stacked one on top of the other in a parallel manner. The interporphyrin cavities of the overlapping networks combine into channel voids accommodated by the dichlorobenzene solvent. Molecules of the porphyrin complex are located on crystallographic inversion centres. The observed two-dimensional assembly mode of the porphyrin units represents a supramolecular isomer of the unique three-dimensional coordination frameworks of the same porphyrin building block observed earlier. The significance of this study lies in the discovery of an additional supramolecular isomer of the rarely observed structures of metalloporphyrins self-assembled directly into extended coordination polymers without the use of external ligand or metal ion auxiliaries.

Redox-Triggered Folding of Self-Assembled Coordination Polymers incorporating Viologen Units

2018 ◽  
Vol 24 (49) ◽  
pp. 12961-12969 ◽  
Author(s):  
Wathiq Sattar Abdul-Hassan ◽  
Denis Roux ◽  
Christophe Bucher ◽  
Saioa Cobo ◽  
Florian Molton ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembled

Synthesis and mesomorphism of ionic self-assembled complexes of anthraquinones

2017 ◽  
Vol 44 (14-15) ◽  
pp. 2311-2320 ◽  
Author(s):  
K. Swamynathan ◽  
V. A. Raghunathan ◽  
Sandeep Kumar
Keyword(s):  
Assembled Complexes ◽  
Self Assembled
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