Photoinitiated Cross-Linking of the Biodegradable Polyester Poly(propylene fumarate). Part I. Determination of Network Structure

2003 ◽  
Vol 4 (5) ◽  
pp. 1327-1334 ◽  
Author(s):  
John P. Fisher ◽  
Mark D. Timmer ◽  
Theresa A. Holland ◽  
David Dean ◽  
Paul S. Engel ◽  
...  
2003 ◽  
Vol 4 (5) ◽  
pp. 1335-1342 ◽  
Author(s):  
John P. Fisher ◽  
Theresa A. Holland ◽  
David Dean ◽  
Antonios G. Mikos

1986 ◽  
Vol 19 (5) ◽  
pp. 1337-1343 ◽  
Author(s):  
Frederic C. Schilling ◽  
Alan E. Tonelli

2016 ◽  
Vol 291 (11) ◽  
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Author(s):  
Zeliang Zheng ◽  
Amy Blum ◽  
Tithi Banerjee ◽  
Qianyu Wang ◽  
Virginia Dantis ◽  
...  

2006 ◽  
Vol 283 (1-2) ◽  
pp. 253-265 ◽  
Author(s):  
Roy D. Raharjo ◽  
Haiqing Lin ◽  
David F. Sanders ◽  
Benny D. Freeman ◽  
Sumod Kalakkunnath ◽  
...  

2009 ◽  
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George Z. Papageorgiou ◽  
Sofia A. Papadimitriou ◽  
Evangelos Karavas ◽  
Konstantinos Avgoustakis

2018 ◽  
Vol 7 (1) ◽  
pp. 21-30 ◽  
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Christoph Kugler ◽  
Eduard Kraus ◽  
Benjamin Baudrit ◽  
Thomas Hochrein ◽  
...  

Abstract. The degree of cross-linking and curing is one of the most important values concerning the quality of cross-linked polyethylene (PE-X) and the functionality of adhesives and resin-based components. Up to now, the measurement of this property has mostly been time-consuming and usually destructive. Within the shown work the feasibility of single-sided nuclear magnetic resonance (NMR) for the non-destructive determination of the degree of cross-linking and curing as process monitoring was investigated. First results indicate the possibility of distinguishing between PE-X samples with different degrees of cross-linking. The homogeneity of the samples and the curing kinetics of adhesives can also be monitored. The measurements show good agreement with reference tests (wet chemical analysis, differential scanning calorimetry, dielectric analysis). Furthermore, the influence of sample temperature on the characteristic relaxation times can be observed.


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