Enzymatic Synthesis and Curing of Biodegradable Epoxide-Containing Polyesters from Renewable Resources

2003 ◽  
Vol 4 (2) ◽  
pp. 211-215 ◽  
Author(s):  
Hiroshi Uyama ◽  
Mai Kuwabara ◽  
Takashi Tsujimoto ◽  
Shiro Kobayashi
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis

scholarly journals Enzymatic Synthesis of Muconic Acid-Based Polymers: Trans, Trans-Dimethyl Muconate and Trans, β-Dimethyl Hydromuconate

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2498
Author(s):  
Dina Maniar ◽  
Csaba Fodor ◽  
Indra Karno Adi ◽  
Albert J. J. Woortman ◽  
Jur van Dijken ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Renewable Resources ◽  
Enzymatic Synthesis ◽  
Enzyme Catalysis ◽  
Unsaturated Polyester ◽  
Chain Extension ◽  
Side Reactions ◽  
Muconic Acid ◽  
Thermal Stabilities ◽  
Polyester Resins

The vast majority of commodity polymers are acquired from petrochemical feedstock, and these resources will plausibly be depleted within the next 100 years. Therefore, the utilization of carbon-neutral renewable resources for the production of polymers is crucial in modern green chemistry. Herein, we report an eco-friendly strategy that uses enzyme catalysis to design biobased unsaturated (co)polyesters from muconic acid derivatives. This method is an attractive pathway for the production of well-defined unsaturated polyesters with minimum side reactions. A suite of characterization techniques was performed to probe the reaction mechanism and properties of the obtained polyesters. It is rationalized that the alkene functionality of the muconate monomers plays an important role in the enzyme catalysis mechanism. The rendered polyesters possessed excellent thermal stabilities and unreacted alkene functionality that can consecutively undergo chain extension, copolymerization, or act as an anchor for other functional groups. These properties open new avenues in the fields of unsaturated polyester resins and photosensitive coatings.

scholarly journals Cover Feature: Furan‐Based Copolyesters from Renewable Resources: Enzymatic Synthesis and Properties (ChemSusChem 5/2019)

ChemSusChem ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 957-957 ◽  
Author(s):  
Dina Maniar ◽  
Yi Jiang ◽  
Albert J. J. Woortman ◽  
Jur van Dijken ◽  
Katja Loos
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis

scholarly journals Furan‐Based Copolyesters from Renewable Resources: Enzymatic Synthesis and Properties

ChemSusChem ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 990-999 ◽  
Author(s):  
Dina Maniar ◽  
Yi Jiang ◽  
Albert J. J. Woortman ◽  
Jur van Dijken ◽  
Katja Loos
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis

ChemInform Abstract: Enzymatic Synthesis of Sugar Esters and Oligosaccharides from Renewable Resources

ChemInform ◽  
2008 ◽  
Vol 39 (22) ◽  
Author(s):  
A. Ballesteros ◽  
F. J. Plou ◽  
M. Alcalde ◽  
M. Ferrer ◽  
H. Garcia-Arellano ◽  
...  
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis ◽  
Sugar Esters

Fully Biobased Unsaturated Aliphatic Polyesters from Renewable Resources: Enzymatic Synthesis, Characterization, and Properties

2014 ◽  
Vol 215 (22) ◽  
pp. 2185-2197 ◽  
Author(s):  
Yi Jiang ◽  
Gert O. R. Alberda van Ekenstein ◽  
Albert J. J. Woortman ◽  
Katja Loos
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis ◽  
Aliphatic Polyesters

Enzymatic Synthesis of Cross-Linkable Polyesters from Renewable Resources

2001 ◽  
Vol 2 (1) ◽  
pp. 29-31 ◽  
Author(s):  
Takashi Tsujimoto ◽  
Hiroshi Uyama ◽  
Shiro Kobayashi
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis

Enzymatic synthesis and curing of polycardol from renewable resources

2009 ◽  
Vol 57 (1-4) ◽  
pp. 312-316 ◽  
Author(s):  
Seung Young Park ◽  
Yong Hwan Kim ◽  
Keehoon Won ◽  
Bong Keun Song
Keyword(s):  
Renewable Resources ◽  
Enzymatic Synthesis

Enzymatic Synthesis of Enantiomerically Pure Chiral Synthons: Lipase-Catalyzed Resolution of (R/S, 4E)-2-Methyl-4-hexen-l-ol

Synlett ◽  
1991 ◽  
Vol 1991 (04) ◽  
pp. 310-312
Author(s):  
Patrizia Ferraboschi ◽  
Daria Brembilla ◽  
Paride Grisenti ◽  
Enzo Santaniello
Keyword(s):  
Enzymatic Synthesis ◽  
Enantiomerically Pure
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