High-Temperature Flammability and Mechanical Properties of Thermoplastic Polyurethane Nanocomposites

2012 ◽  
pp. 343-360 ◽  
Author(s):  
Preejith Ambuken ◽  
Holly Stretz ◽  
Joseph H. Koo ◽  
Jason Lee ◽  
Rosa Trejo
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Thermoplastic Polyurethane ◽  
Polyurethane Nanocomposites

A molecular dynamics-based investigation on tribological properties of functionalized graphene reinforced thermoplastic polyurethane nanocomposites

2020 ◽  
Vol 235 (1) ◽  
pp. 61-78 ◽  
Author(s):  
Animesh Talapatra ◽  
Debasis Datta
Keyword(s):  
Mechanical Properties ◽  
Molecular Dynamics ◽  
Coefficient Of Friction ◽  
Normal Load ◽  
Thermoplastic Polyurethane ◽  
Load Condition ◽  
Monolayer Graphene ◽  
Sliding Velocity ◽  
Abrasion Rate ◽  
Polyurethane Nanocomposites

Tribo-mechanical properties of pure thermoplastic polyurethane and functionalized monolayer graphene-reinforced thermoplastic polyurethane polymer nanocomposites are investigated by molecular dynamics simulations. Initially, the mechanical properties of the thermoplastic polyurethane and functionalized monolayer graphene-reinforced thermoplastic polyurethane nanocomposites are measured by applying constant stain method. Subsequently, interfacial layer models are developed to apply confined shear on the iron layers to find out the coefficient of friction and the abrasion rate of pure thermoplastic polyurethane and functionalized monolayer graphene-reinforced thermoplastic polyurethane nanocomposites. The results imply that by the incorporation of 0.5 wt.% functionalized monolayer, graphene shows the increase of 20% in Young’s modulus, 15% in shear modulus and 6.66% in bulk modulus of pure thermoplastic polyurethane, respectively, which are in good agreement with the previous experimental studies. Maximum enhancement of mechanical properties can be obtained up to 3 wt.% addition of functionalized monolayer graphene addition in thermoplastic polyurethane matrix. Further, it is observed that 3 wt.% of functionalized monolayer graphene-reinforced thermoplastic polyurethane nanocomposite results in minimum coefficient of friction (0.42) and abrasion rate (19%) under constant normal load (5 kcal/mol/Å) and maximum sliding velocity (11 m/s). However, further reduction in minimum values of coefficient of friction and abrasion rate at 3 wt.% of functionalized monolayer graphene-reinforced thermoplastic polyurethane nanocomposites is seen under the minimum sliding velocity (1 m/s) considered with the same normal load condition. Finally, the inherent mechanisms for enhancement of tribo-mechanical properties in functionalized monolayer graphene-reinforced thermoplastic polyurethane nanocomposites are analysed by the atomic density profile, free volume and Connolly surface at the atomic level.

Organophilic graphene nanosheets as a promising nanofiller for bio-based polyurethane nanocomposites: investigation of the thermal, barrier and mechanical properties

2019 ◽  
Vol 43 (39) ◽  
pp. 15659-15672 ◽  
Author(s):  
Mohammed Majdoub ◽  
Younes Essamlali ◽  
Othmane Amadine ◽  
Ikram Ganetri ◽  
Mohamed Zahouily
Keyword(s):  
Mechanical Properties ◽  
Graphene Oxide ◽  
Graphene Nanosheets ◽  
Thermoplastic Polyurethane ◽  
Nanocomposite Films ◽  
Thermal Barrier ◽  
Amine Functionalized ◽  
Reduced Graphene ◽  
Polyurethane Nanocomposites ◽  
Long Chain

The present study focuses on the design of new nanocomposite films using bio-based thermoplastic polyurethane (TPU) as a polymer matrix and long chain amine functionalized reduced graphene oxide (G-ODA) as a nanofiller.

Lattice Imaging of Grain Boundaries in Ceramics

1977 ◽  
Vol 35 ◽  
pp. 114-115
Author(s):  
D. R. Clarke ◽  
G. Thomas
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Silicon Nitride ◽  
Grain Boundaries ◽  
High Temperature Strength ◽  
Current Interest ◽  
Lattice Imaging ◽  
Special Significance ◽  
Structural Applications ◽  
Refractory Ceramics

Grain boundaries have long held a special significance to ceramicists. In part, this has been because it has been impossible until now to actually observe the boundaries themselves. Just as important, however, is the fact that the grain boundaries and their environs have a determing influence on both the mechanisms by which powder compaction occurs during fabrication, and on the overall mechanical properties of the material. One area where the grain boundary plays a particularly important role is in the high temperature strength of hot-pressed ceramics. This is a subject of current interest as extensive efforts are being made to develop ceramics, such as silicon nitride alloys, for high temperature structural applications. In this presentation we describe how the techniques of lattice fringe imaging have made it possible to study the grain boundaries in a number of refractory ceramics, and illustrate some of the findings.

TEM Studies of Grain Boundary Films in Si3N4 Ceramics

1991 ◽  
Vol 49 ◽  
pp. 930-931
Author(s):  
H.-J. Kleebe ◽  
J.S. Vetrano ◽  
J. Bruley ◽  
M. Rühle
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Silicon Nitride ◽  
Hot Isostatic Pressing ◽  
Amorphous Film ◽  
Liquid Phase Sintering ◽  
Second Phase ◽  
High Temperature Mechanical Properties ◽  
Triple Points ◽  
Boundary Films

It is expected that silicon nitride based ceramics will be used as high-temperature structural components. Though much progress has been made in both processing techniques and microstructural control, the mechanical properties required have not yet been achieved. It is thought that the high-temperature mechanical properties of Si3N4 are limited largely by the secondary glassy phases present at triple points. These are due to various oxide additives used to promote liquid-phase sintering. Therefore, many attempts have been performed to crystallize these second phase glassy pockets in order to improve high temperature properties. In addition to the glassy or crystallized second phases at triple points a thin amorphous film exists at two-grain junctions. This thin film is found even in silicon nitride formed by hot isostatic pressing (HIPing) without additives. It has been proposed by Clarke that an amorphous film can exist at two-grain junctions with an equilibrium thickness.

AEM of reaction-bonded SiC

1992 ◽  
Vol 50 (1) ◽  
pp. 344-345
Author(s):  
K Das Chowdhury ◽  
R. W. Carpenter ◽  
W. Braue
Keyword(s):  
Mechanical Properties ◽  
Phase Transformation ◽  
High Temperature ◽  
Epitaxial Growth ◽  
Liquid Silicon ◽  
Structural Ceramic ◽  
Few Data

Research on reaction-bonded SiC (RBSiC) is aimed at developing a reliable structural ceramic with improved mechanical properties. The starting materials for RBSiC were Si,C and α-SiC powder. The formation of the complex microstructure of RBSiC involves (i) solution of carbon in liquid silicon, (ii) nucleation and epitaxial growth of secondary β-SiC on the original α-SiC grains followed by (iii) β>α-SiC phase transformation of newly formed SiC. Due to their coherent nature, epitaxial SiC/SiC interfaces are considered to be segregation-free and “strong” with respect to their effect on the mechanical properties of RBSiC. But the “weak” Si/SiC interface limits its use in high temperature situations. However, few data exist on the structure and chemistry of these interfaces. Microanalytical results obtained by parallel EELS and HREM imaging are reported here.

ALUMINUM 220

Alloy Digest ◽  
1962 ◽  
Vol 11 (3) ◽  
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Shear Strength ◽  
High Temperature ◽  
Heat Treating ◽  
Casting Alloy ◽  
Aluminum Casting ◽  
Aluminum Casting Alloy ◽  
Temperature Performance ◽  
Aluminum Company

Abstract ALUMINUM 220 is a 10% magnesium-aluminum casting alloy having the highest combination of mechanical properties, corrosion resistance and machinability. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive and shear strength as well as fatigue. It also includes information on high temperature performance and corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: Al-112. Producer or source: Aluminum Company of America.

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