Molecular Composition of Shale Oil

Author(s):  
James W. Bunger ◽  
Christopher P. Russell ◽  
Donald E. Cogswell
2022 ◽  
Author(s):  
Bowei Zhang ◽  
Juhe Zhang

Abstract The important research content and basis of exploration and development is to evaluate the reservoir property, oil bearing property, fluidity and compressibility of shale reservoir.The key of exploration and development is to evaluate the oil-bearing and fluidity of shale reservoir.In this paper, the "shale oil content and fine components synchronous experimental analysis device" is used. Five temperature ranges of 30 ℃-90 ℃, 90 ℃-150 ℃, 100 ℃- 200 ℃, 150 ℃-250 ℃ and 250 ℃-300 ℃ were adopted. The heating rate of each temperature segment was 25 ℃ / min, and the final temperature was kept constant for 5 min. The oil content of shale (pyrolysis S1) was cut into five fractions.Simultaneous determination of oil content and molecular composition of shale fractions,and the external standard method was used to evaluate the oil content and fluidity.The results show that the five fractions of shale are mainly composed of nC1-nC9 gas, nC10-nC15 gasoline, nC12-nC20 kerosene, nC15-nC22 diesel oil and nC18-nC26 heavy oil of the first member of Qingshangkou formation in Songliao basin.There are differences in the fractionation and oil content characteristics of samples with different maturity in different wells.The parent material, properties and quality of crude oil are reflected in shale. The higher the maturity of shale oil is, the more light components are, the larger the light / heavy ratio parameter value of (gasoline + kerosene + diesel) and heavy oil is, the better the fluidity is, and the easier to exploit effectively.


2018 ◽  
Vol 40 (3) ◽  
pp. 54-80 ◽  
Author(s):  
V. I. Isaev ◽  
G. A. Lobova ◽  
V. V. Stotskiy ◽  
A. N. Fomin

Oil Shale ◽  
2011 ◽  
Vol 28 (1S) ◽  
pp. 101 ◽  
Author(s):  
A OTS ◽  
A POOBUS ◽  
T LAUSMAA
Keyword(s):  

Author(s):  
Svetlana Punanova

This research considered the content of trace elements (TE), including potentially toxic elements (PTE) in shale plays and deposits in various regions of the world. Their comparative analysis was carried out and the highest concentrations of PTE in the shales of some regions were revealed. The author notes that the destruction of organometallic compounds occurs during the development of shale hydrocarbon (HC) using horizontal drilling with hydraulic fracturing – injecting large volumes of chemicals while increasing the temperature. During such destruction processes, PTE can escape into the environment: into groundwater, soil layers, and other objects of economic use, and also deteriorate well equipment. In connection with the noted environmental hazards present during the development of shale HC, this paper proposes to monitor the content of TE in both shale rocks as well as in extracted shale oil in order to mitigate the risks of their release into the environment. In addition, developers and scientists should consider the losses of industrially significant volumes of valuable metals that occur due to the lack of cost-effective technologies for their capture and extraction from naphthides.


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