Gas Separation and Pervaporation through Microporous Carbon Membranes Derived from Phenolic Resin

Author(s):  
Hidetoshi Kita ◽  
Koji Nanbu ◽  
Hiroshi Maeda ◽  
Ken-ichi Okamoto
2011 ◽  
Vol 675-677 ◽  
pp. 1185-1188
Author(s):  
Bing Zhang ◽  
Yong Hong Wu ◽  
Tong Hua Wang ◽  
Jie Shan Qiu ◽  
Tie Jun Xu ◽  
...  

A novel cheap blended precursor phenolic resin/poly(vinyl alcohol) (PR/PVA) was developed to prepare carbon membranes. The effect of two curing methods (i.e., crosslinker and preoxidation) on the gas separation performance of their derived carbon membranes was investigated. Thermogravimetric analysis (TGA), Differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy were used to analyze the thermal stability of precursor and the changes in functional groups on membrane surface. The gas permeation of carbon membranes was tested for H2 and N2. The results show that PR, PR/PVA, and two PR/PVA cured samples have three thermal degradation stages. The thermal stability for original PR/PVA membrane is significantly improved via the method of preoxidation or crosslinker. Similar crosslinking structure is formed by the two curing methods. However, carbon membranes from crosslinker method present two-fold higher in hydrogen permeability and four-fold higher in selectivity than that from preoxidation method.


2010 ◽  
Vol 25 (5) ◽  
pp. 449-456 ◽  
Author(s):  
Lin LI ◽  
Tong-Hua WANG ◽  
Yi-Ming CAO ◽  
Jie-Shan QIU

2017 ◽  
Vol 42 (39) ◽  
pp. 24830-24845 ◽  
Author(s):  
Janice B.S. Hamm ◽  
Alan Ambrosi ◽  
Julia G. Griebeler ◽  
Nilson R. Marcilio ◽  
Isabel Cristina Tessaro ◽  
...  

2009 ◽  
Vol 48 (6) ◽  
pp. 2886-2890 ◽  
Author(s):  
Bing Zhang ◽  
Guoliang Shen ◽  
Yonghong Wu ◽  
Tonghua Wang ◽  
Jieshan Qiu ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 14149-14163 ◽  
Author(s):  
Shokofeh Heydari ◽  
Vahid Pirouzfar

One of the common polyimides, P84 HT (BTDA-TDI/MDI), was used to synthesize gas separation carbon molecular sieve (CMS) membranes and study their gas transport properties.


2007 ◽  
Vol 99 (1-2) ◽  
pp. 181-189 ◽  
Author(s):  
F.K. Katsaros ◽  
Th.A. Steriotis ◽  
G.E. Romanos ◽  
M. Konstantakou ◽  
A.K. Stubos ◽  
...  

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