Gas Permeation Properties of Silane-Cross-Linked Poly(propylene oxide)

2004 ◽  
pp. 139-153 ◽  
Author(s):  
Kazukiyo Nagai ◽  
Tsutomu Nakagawa
Keyword(s):  
Propylene Oxide ◽  
Gas Permeation ◽  
Poly Propylene ◽  
Permeation Properties

scholarly journals Gas Permeation Properties of High-Silica CHA-Type Zeolite Membrane

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda
Keyword(s):  
Molecular Size ◽  
Gas Permeation ◽  
Zeolite Membrane ◽  
Type Zeolite ◽  
High Silica ◽  
Separation Of Co2 ◽  
Α Al2o3 ◽  
Separation Performances ◽  
Molecular Sieving ◽  
Permeation Properties

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.

scholarly journals Heterotelechelic poly(propylene oxide) as migration-inhibited toughening agent in hot lithography based additive manufacturing

2021 ◽  
Vol 12 (9) ◽  
pp. 1260-1272
Author(s):  
Daniel Grunenberg ◽  
Katharina Ehrmann ◽  
Christian Gorsche ◽  
Bernhard Steyrer ◽  
Thomas Koch ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Propylene Oxide ◽  
Chain Transfer ◽  
Poly Propylene ◽  
Toughening Agent

Linking an addition–fragmentation-chain-transfer (AFCT) functionality and methacrylate moiety via poly(propylene oxide)-oligomer within one molecule creates a non-migrating AFCT-reagent aiding network-homogeneity.

Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Succinic Anhydride ◽  
Poly Propylene ◽  
Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

scholarly journals Fabrication and characterization of the ternary composite catalyst system of ZnGA/RET/DMC for the terpolymerization of CO2, propylene oxide and trimellitic anhydride

RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8782-8792
Author(s):  
Ningzhang Liu ◽  
Chuanhai Gu ◽  
Qinghe Wang ◽  
Linhua Zhu ◽  
Huiqiong Yan ◽  
...  
Keyword(s):  
Propylene Oxide ◽  
Ternary Complex ◽  
Catalyst System ◽  
Composite Catalyst ◽  
Trimellitic Anhydride ◽  
Ternary Composite ◽  
Metal Cyanide ◽  
Fabrication And Characterization ◽  
Poly Propylene

For poly(propylene carbonate trimellitic anhydride) with good yield, thermal stability and high molecular weight, a catalyst of zinc glutarate/rare earth ternary complex/double metal cyanide was used for terpolymerization of CO2, propylene oxide and trimellitic anhydride.

Carbon-13 NMR determination of poly(propylene oxide) microstructure

1986 ◽  
Vol 19 (5) ◽  
pp. 1337-1343 ◽  
Author(s):  
Frederic C. Schilling ◽  
Alan E. Tonelli
Keyword(s):  
Propylene Oxide ◽  
Poly Propylene

NMR study of a poly(propylene oxide)-NaCF3SO3 polymer electrolyte

1990 ◽  
Vol 40-41 ◽  
pp. 645-647 ◽  
Author(s):  
S SCHANTZ ◽  
M KAKIHANA ◽  
M SANDBERG
Keyword(s):  
Polymer Electrolyte ◽  
Propylene Oxide ◽  
Nmr Study ◽  
Poly Propylene
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