Catalytic Behavior of Calcium Oxide for Synthesis of Dimethyl Carbonate from Propylene Carbonate and Methanol Near Room Temperature

Author(s):  
Tong Wei ◽  
M. Wang ◽  
Wei Wei ◽  
Yuhan Sun ◽  
Bin Zhong
Molbank ◽  
10.3390/m1217 ◽  
2021 ◽  
Vol 2021 (2) ◽  
pp. M1217
Author(s):  
Rebeca González-Fernández ◽  
Pascale Crochet ◽  
Victorio Cadierno

The title compound, i.e., [RuCl2(η6-p-cymene)(PPh2NHnPr)] (2), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl2(η6-p-cymene)(PPh2Cl)] (1) with two equivalents of n-propylamine at room temperature. The aminophosphine complex 2 was characterized by elemental analysis, multinuclear NMR (31P{1H}, 1H and 13C{1H}) and IR spectroscopy. In addition, its catalytic behavior in the hydration of benzonitrile was briefly explored.


2021 ◽  
Vol 2103 (1) ◽  
pp. 012075
Author(s):  
AA Dmitrievskiy ◽  
DG Zhigacheva ◽  
VM Vasyukov ◽  
PN Ovchinnikov

Abstract In this work, the phase composition (relative fractions of monoclinic m-ZrO2, tetragonal t-ZrO2, and cubic c-ZrO2 phases) and mechanical properties (hardness, fracture toughness, compressive strength) of alumina toughened zirconia (ATZ) ceramics, with an addition of silica were investigated. Calcium oxide was used as a stabilizer for the zirconia tetragonal phase. It was shown that CaO-ATZ+SiO2 ceramics demonstrate increased resistance to low-temperature degradation. The plasticity signs at room temperature were found due to the SiO2 addition to CaO-ATZ ceramics. A yield plateau appears in the uniaxial compression diagram at 5 mol. % SiO2 concentration. It is hypothesized that discovered plasticity is due to the increased t→m transformability.


2019 ◽  
Vol 6 (13) ◽  
pp. 3429-3436 ◽  
Author(s):  
Erik Björklund ◽  
Mara Göttlinger ◽  
Kristina Edström ◽  
Daniel Brandell ◽  
Reza Younesi

2007 ◽  
Vol 24 (5) ◽  
pp. 917-919 ◽  
Author(s):  
Hye-Young Ju ◽  
Mamparambath Dharman Manju ◽  
Kyung-Hoon Kim ◽  
Sang-Wook Park ◽  
Dae-Won Park

2017 ◽  
Vol 309 ◽  
pp. 13-21 ◽  
Author(s):  
Praveen Kumar ◽  
Vimal Chandra Srivastava ◽  
Roger Gläser ◽  
Patrick With ◽  
Indra Mani Mishra

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