Toward a Green Chemistry and Engineering Solution for the U.S. Energy Industry: Reducing Emissions and Converting Waste Streams into Value-Added Products

Author(s):  
M. M. Mercedes Maroto-Valer ◽  
John M. Andrésen ◽  
Yinzhi Zhang
2020 ◽  
Vol 21 (22) ◽  
pp. 8777
Author(s):  
Regina Kutscha ◽  
Stefan Pflügl

Ecological concerns have recently led to the increasing trend to upgrade carbon contained in waste streams into valuable chemicals. One of these components is acetate. Its microbial upgrading is possible in various species, with Escherichia coli being the best-studied. Several chemicals derived from acetate have already been successfully produced in E. coli on a laboratory scale, including acetone, itaconic acid, mevalonate, and tyrosine. As acetate is a carbon source with a low energy content compared to glucose or glycerol, energy- and redox-balancing plays an important role in acetate-based growth and production. In addition to the energetic challenges, acetate has an inhibitory effect on microorganisms, reducing growth rates, and limiting product concentrations. Moreover, extensive metabolic engineering is necessary to obtain a broad range of acetate-based products. In this review, we illustrate some of the necessary energetic considerations to establish robust production processes by presenting calculations of maximum theoretical product and carbon yields. Moreover, different strategies to deal with energetic and metabolic challenges are presented. Finally, we summarize ways to alleviate acetate toxicity and give an overview of process engineering measures that enable sustainable acetate-based production of value-added chemicals.


2021 ◽  
Author(s):  
Matthew Donald Hinnecke

Due to the exponential growth of the human population and declining environmental quality in the world, waste derived volatile fatty acids (VFAs) have been identified as a source for the production of value-added products. Throughout this paper, different technologies for the production of value-added products from VFAs, various high content VFA waste streams and value-added products from each process will be discussed. Additionally, an in-depth literature review will be conducted on 5 value added products from VFAs. Highlights of various experiments will be identified as well as common trends in experiments to date. Some considerations will also be given to particular strategies and methods which may enhance the production of a value-added product in the future. Even through the uncertainty it has been proven that waste derived VFAs are a major candidate in contributing to a more environmentally and sustainable society in the immediate future.


2021 ◽  
Author(s):  
Matthew Donald Hinnecke

Due to the exponential growth of the human population and declining environmental quality in the world, waste derived volatile fatty acids (VFAs) have been identified as a source for the production of value-added products. Throughout this paper, different technologies for the production of value-added products from VFAs, various high content VFA waste streams and value-added products from each process will be discussed. Additionally, an in-depth literature review will be conducted on 5 value added products from VFAs. Highlights of various experiments will be identified as well as common trends in experiments to date. Some considerations will also be given to particular strategies and methods which may enhance the production of a value-added product in the future. Even through the uncertainty it has been proven that waste derived VFAs are a major candidate in contributing to a more environmentally and sustainable society in the immediate future.


2021 ◽  

Abstract Selenium contamination of air, aquatic environments, soils and sediments is a serious environmental concern of increasing importance. Selenium has a paradoxical feature in bringing about health benefits under the prescribed level, but only a few fold increase in its concentration causes deleterious effects to flora and fauna, humans and the environment. This book Environmental Technologies to Treat Selenium Pollution: Principles and Engineering: presents the fundamentals of the biogeochemical selenium cycle and which imbalances in this cycle result in pollution.overviews chemical and biological technologies for successful treatment of selenium contaminated water, air, soils and sediments.explores the recovery of value-added products from selenium laden waste streams, including biofortication and selenium-based nanoparticles and quantum dots. This book may serve both as an advanced textbook for undergraduate and graduate students majoring in environmental sciences, technology or engineering as well as as a handbook for tertiary educators, researchers, professionals and policy makers who conduct research and practices in selenium related fields. It is essential reading for consulting companies when dealing with selenium related environmental (bio)technologies. ISBN: 9781789061048 (Paperback) ISBN: 9781789061055 (eBook)


MRS Advances ◽  
2018 ◽  
Vol 3 (36) ◽  
pp. 2137-2142
Author(s):  
Kofi W. Adu ◽  
Paul Armstrong ◽  
Lucas Servera ◽  
David K. Essumang ◽  
Samuel Y. Mensah

ABSTRACTMuch of the global agricultural by products go waste, especially in developing nations where much of their revenues depend on the exports of raw agricultural products. Such waste streams, if converted to “value added” products could serve as additional source of revenue while simultaneously having a positive impact on the socio-economic well being of the people. We present a preliminary investigation on utilizing chemical activation technique and ball milling to convert agricultural waste streams such as cocoa pod, coconut husk, palm midrib and calabash commonly found in Ghana into ultra-high surface area activated carbon. Such activated carbons are suitable for myriads of applications in environmental remediation, climate management, energy storage and conversion systems (batteries and supercapacitors), and improving crop productivity. We achieved BET surface area as high as ∼ 3000 m2/g.


2020 ◽  
Author(s):  
Caoxing Huang ◽  
Wenqian Lin ◽  
Yuxuan Shi ◽  
Yayue Zheng ◽  
Qiang Yong

Abstract Background The existences of soluble lignin, furfural and HMF in industrial pre-hydrolysis liquor (PHL) can inhibit its bioconversion into bioethanol and other bio-chemicals. Although various technologies have been carried out to remove these inhibitors, a undesirable sugars removal is also happened during the process. Hence, polystyrene divinylbenzene (PS-DVB) resin was used as adsorptive material to simultaneously remove fermentation inhibitors while retain sugars with higher yield for improving the fermentability of PHL after acid-hydrolysis (A-PHL) treatment. The fermentability of treated PHL was evaluated by the bioconversion into ethanol and xylosic acid (XA). Results Results showed that an highest xylose concentration (101.1 g/L) in PHL could be obtained by acid-hydrolysis at 100 oC for 80 min with 4% acid, while concentration of fermentation inhibitors (furfural, HMF and lignin) could also be significantly improved. After treating, not only 97% of lignin, 92% of furfural, and 97% of HMF were removed from solution, but also 96% of xylose was retained for subsequent fermentation. With resin treatment, the fermentability of A-PHL could be improved by 162–282% for ethanol production from A-PHL with 30–50 g/L xylose and by 18–828% for XA production from A-PHL with 90–150 g/L xylose. Conclusions These results confirmed that PS-DVB resin can remove inhibitors from PHL before producing value-added products by bioconversion. In addition, the work will ideally provide a concept by which pulping facilities could go about producing value-added chemicals from existing waste streams.


2017 ◽  
Vol 19 (18) ◽  
pp. 4200-4233 ◽  
Author(s):  
S. Gillet ◽  
M. Aguedo ◽  
L. Petitjean ◽  
A. R. C. Morais ◽  
A. M. da Costa Lopes ◽  
...  

We provide a critical review of green processes enabling the fractionation and/or depolymerization of lignin towards value-added products.


2019 ◽  
Vol 20 (10) ◽  
pp. 776-786 ◽  
Author(s):  
Charalampia Dimou ◽  
Haralabos C. Karantonis ◽  
Dimitrios Skalkos ◽  
Antonios E. Koutelidakis

Owning to the increase in the world population as well as the consumer’s awareness on the health benefits of consumption of fruits, the demand for both fresh and processed fruits has been increased. The by-product and waste streams generated from fruit processing industries are extremely diverse, owning mainly to different fruits varieties and the wide range of the processes employed towards the production of the end fruit-based products. Due to the increasing production and processing of fruits, disposal of waste and by-product streams has become a serious issue, since these materials are prone to microbial spoilage. Also, the inappropriate waste management practices pose severe environmental issues. Furthermore, the costs of drying and storage of fruit processing residues are economically limiting factors hindering their further exploitation. Therefore, fruit processing by-products such as peels, seeds and unused flesh are often utilized as fertilizers. On the other hand, plant residues contain biomolecules such as vitamins, proteins, minerals, antioxidants and aromatic oil. Recovery of bioactive compounds holds a great potential for their usage in food industry as functional ingredients and nutraceuticals or in pharmaceutical and in cosmetic applications. So, valorization of plant fruit processing by-products to high-value added compounds, constitute a promising alternative not only for addressing fruit residues management issues but also leading to the production of functional food products of high nutritional value, with several potential beneficial health effects. The aim of this paper is to highlight current trends in addressing environmental issues caused by the production of high volumes of specific categories of fruit processing waste streams by investigating their potential usage as natural raw materials for the recovery of valuable bioactive compounds (such as polyphenols, dietary fibers or aromatic oil). The extracted nutrients may be used in the industrial food sector for the production of functional foods, nutraceuticals or even as health promoting natural pharmaceutical ingredients or additives for the production of innovative enriched foods. </p><p> Highlights: • Fruit processing by product streams are rich in bioactive compounds. </p><p> • Integration of fruit by-products and waste streams to value added products such as additives, unconventional oil, bioactive compounds and novel functional products is a very interesting approach regarding fruit processing residues exploitation. </p><p> • Recovering of biomolecules from fruit residues by non-thermal processes could lead to the efficient production of highly purified functional ingredients. </p><p> • Negative-valued fruit processing residues could be recycled for the production of health promoting value added products.


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