Surface-Iniatiated Anionic Polymerization: Tethered Polymer Brushes on Silicate Flat Surfaces

2001 ◽  
pp. 39-55 ◽  
Author(s):  
Qingye Zhou ◽  
Yo Nakamura ◽  
Seiji Inaoka ◽  
Mi-kyoung Park ◽  
Yingfan Wang ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Polymer Brushes ◽  
Flat Surfaces

scholarly journals Thermo-Responsive Polymer Brushes with Side Graft Chains: Relationship Between Molecular Architecture and Underwater Adherence

2019 ◽  
Vol 20 (24) ◽  
pp. 6295
Author(s):  
Ugo Sidoli ◽  
Hisaschi T. Tee ◽  
Ivan Raguzin ◽  
Jakob Mühldorfer ◽  
Frederik R. Wurm ◽  
...  
Keyword(s):  
Polymer Brushes ◽  
Bulk Solution ◽  
Molecular Architecture ◽  
Adhesive Properties ◽  
Adhesion Properties ◽  
Grafted Polymer ◽  
Flat Surfaces ◽  
Underwater Adhesion ◽  
Lcst Behavior ◽  
Responsive Polymer

During the last few decades, wet adhesives have been developed for applications in various fields. Nonetheless, key questions such as the most suitable polymer architecture as well as the most suitable chemical composition remain open. In this article, we investigate the underwater adhesion properties of novel responsive polymer brushes with side graft chain architecture prepared using “grafting through” approach on flat surfaces. The incorporation in the backbone of thermo-responsive poly(N-isopropylacrylamide) (PNIPAm) allowed us to obtain LCST behavior in the final layers. PNIPAm is co-polymerized with poly(methyl ethylene phosphate) (PMEP), a poloyphosphoester. The final materials are characterized studying the surface-grafted polymer as well as the polymer from the bulk solution, and pure PNIPAm brush is used as reference. PNIPAm-g-PMEP copolymers retain the responsive behavior of PNIPAm: when T > LCST, a clear switching of properties is observed. More specifically, all layers above the critical temperature show collapse of the chains, increased hydrophobicity and variation of the surface charge even if no ionizable groups are present. Secondly, effect of adhesion parameters such as debonding rate and contact time is studied. Thirdly, the reversibility of the adhesive properties is confirmed by performing adhesion cycles. Finally, the adhesive properties of the layers are studied below and above the LCST against hydrophilic and hydrophobic substrates.

Molecular-Weight Determination of Polymer Brushes Generated by SI-ATRP on Flat Surfaces

2013 ◽  
Vol 47 (1) ◽  
pp. 269-275 ◽  
Author(s):  
Chengjun Kang ◽  
Rowena M. Crockett ◽  
Nicholas D. Spencer
Keyword(s):  
Molecular Weight ◽  
Polymer Brushes ◽  
Molecular Weight Determination ◽  
Flat Surfaces

Neutral and Charged Polymer Brushes:  A Model Unifying Curvature Effects from Micelles to Flat Surfaces

1997 ◽  
Vol 30 (6) ◽  
pp. 1787-1792 ◽  
Author(s):  
C. Biver ◽  
R. Hariharan ◽  
J. Mays ◽  
W. B. Russel
Keyword(s):  
Polymer Brushes ◽  
Flat Surfaces ◽  
Curvature Effects ◽  
Charged Polymer

Understanding the Morphologies and Polymerization Mechanism of Homopolymer and Block Copolymer Brushes by Living Anionic Surface Initiated Polymerization

2002 ◽  
Vol 734 ◽  
Author(s):  
Mi-Kyoung Park ◽  
George Sakellariou ◽  
Stergios Pispas ◽  
Nikos Hadjichristides ◽  
Jimmy Mays ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Anionic Polymerization ◽  
Polymer Brushes ◽  
High Vacuum ◽  
Living Anionic Polymerization ◽  
Self Assembled Monolayer ◽  
Surface Initiated Polymerization ◽  
Copolymer Brushes ◽  
Polymerization Conditions ◽  
Anionic Surface

ABSTRACTHomopolymer and block copolymer brushes grafted from Au and Si (SiOx) surfaces via living anionic surface initiated polymerization (LASIP) has been reported. 1,1-diphenylethylene (DPE) derivative, an initiator for anionic polymerization, was grafted onto planar Si-wafer and Au surfaces by self-assembled monolayer (SAM) techniques. n-BuLi was used to activate the DPE for anionic polymerization of monomers at the interface under high vacuum. By a careful sequence of monomer introduction, reaction, and termination, homopolymer and block copolymer tethered polymer brushes were obtained. The importance of initiator activation, control of polymerization conditions, and removal of excess BuLi is emphasized. Interesting differences in morphology, thickness, grafting density, and polymerization conditions contrasts LASIP from solution and other surface initiated polymerization (SIP) mechanisms. The formation of block copolymer sequences highlights the unique utility of a living anionic polymerization technique on surfaces.

HREM observation of dislocations near room temperature fractures in silicon

1988 ◽  
Vol 46 ◽  
pp. 892-893
Author(s):  
M. H. Rhee ◽  
W. A. Coghlan
Keyword(s):  
Cross Section ◽  
Room Temperature ◽  
Single Crystal Silicon ◽  
Dislocation Nucleation ◽  
Back Side ◽  
Ion Milling ◽  
Crystal Silicon ◽  
Flat Surfaces ◽  
Induced Fractures ◽  
Vicker’S Microhardness

Silicon is believed to be an almost perfectly brittle material with cleavage occurring on {111} planes. In such a material at room temperature cleavage is expected to occur prior to any dislocation nucleation. This behavior suggests that cleavage fracture may be used to produce usable flat surfaces. Attempts to show this have failed. Such fractures produced in semiconductor silicon tend to occur on planes of variable orientation resulting in surfaces with a poor surface finish. In order to learn more about the mechanisms involved in fracture of silicon we began a HREM study of hardness indent induced fractures in thin samples of oxidized silicon.Samples of single crystal silicon were oxidized in air for 100 hours at 1000°C. Two pieces of this material were glued together and 500 μm thick cross-section samples were cut from the combined piece. The cross-section samples were indented using a Vicker's microhardness tester to produce cracks. The cracks in the samples were preserved by thinning from the back side using a combination of mechanical grinding and ion milling.

A TEM study of electron tunneling in biological macromolecules

1987 ◽  
Vol 45 ◽  
pp. 140-141
Author(s):  
J. A. Panitz
Keyword(s):  
Stark Effect ◽  
Electron Tunneling ◽  
Imaging Modality ◽  
Tunneling Current ◽  
Biological Species ◽  
Scanning Tunneling ◽  
Biological Macromolecules ◽  
Flat Surfaces ◽  
Virus Particles ◽  
Stm Images

Tunneling is a ubiquitous phenomenon. Alpha particle disintegration, the Stark effect, superconductivity in thin films, field-emission, and field-ionization are examples of electron tunneling phenomena. In the scanning tunneling microscope (STM) electron tunneling is used as an imaging modality. STM images of flat surfaces show structure at the atomic level. However, STM images of large biological species deposited onto flat surfaces are disappointing. For example, unstained virus particles imaged in the STM do not resemble their TEM counterparts.It is not clear how an STM image of a biological species is formed. Most biological species are large compared to the nominal electrode separation of ∼ 1nm that is required for electron tunneling. To form an image of a biological species, the tunneling electrodes must be separated by a distance that would normally be too large for a tunneling current to be observed.

On the Faceting of Polar Ceramic Surfaces: Microscopy and Holography Studies of MGO(111) Surfaces

1996 ◽  
Vol 54 ◽  
pp. 366-367
Author(s):  
M. Gajdardziska-Josifovska ◽  
B. G. Frost ◽  
E. Völkl ◽  
L. F. Allard
Keyword(s):  
Electron Microscopy ◽  
High Vacuum ◽  
Ultra High Vacuum ◽  
Electron Holography ◽  
Flat Surfaces ◽  
Transmission Electron ◽  
Excess Surface ◽  
Polar Surfaces ◽  
Salt Structure ◽  
Crystallographic Planes

Polar surfaces are those crystallographic faces of ionically bonded solids which, when bulk terminated, have excess surface charge and a non-zero dipole moment perpendicular to the surface. In the case of crystals with a rock salt structure, {111} faces are the exemplary polar surfaces. It is commonly believed that such polar surfaces facet into neutral crystallographic planes to minimize their surface energy. This assumption is based on the seminal work of Henrich which has shown faceting of the MgO(111) surface into {100} planes giving rise to three sided pyramids that have been observed by scanning electron microscopy. These surfaces had been prepared by mechanical polishing and phosphoric acid etching, followed by Ar+ sputtering and 1400 K annealing in ultra-high vacuum (UHV). More recent reflection electron microscopy studies of MgO(111) surfaces, annealed in the presence of oxygen at higher temperatures, have revealed relatively flat surfaces stabilized by an oxygen rich reconstruction. In this work we employ a combination of optical microscopy, transmission electron microscopy, and electron holography to further study the issue of surface faceting.

Design of a Spectroscopic Low-Energy Emission Microscope

1990 ◽  
Vol 48 (1) ◽  
pp. 358-359
Author(s):  
Lee H. Veneklasen
Keyword(s):  
Parallel Imaging ◽  
Objective Lens ◽  
Energy Window ◽  
Flat Surfaces ◽  
Beam Voltage ◽  
New Instrument ◽  
Real Time Image ◽  
Image Planes ◽  
Backscatter Diffraction ◽  
Time Image

This paper discusses some of the unique aspects of a spectroscopic emission microscope now being tested in Clausthal. The instrument is designed for the direct parallel imaging of both elastic and inelastic electrons from flat surfaces. Elastic contrast modes of the familiar LEEM include large and small angle LEED, mirror microscopy, backscatter diffraction contrast (for imaging of surface structure), and phase contrast (for imaging of step dynamics)(1). Inelastic modes include topology sensitive secondary, and work function sensitive photoemission. Most important, the new instrument will also allow analytical imaging using characteristic Auger or soft X-ray emissions. The basic instrument has been described by Bauer and Telieps (2). This configuration has been redesigned to include an airlock, and a LaB6 gun, triple condensor lens, magnetic objective lens, a double focussing separator field, an imaging energy analyzer, and a real time image processor.Fig. 1 shows the new configuration. The basic beam voltage supply Vo = 20 KV, upon which separate supplies for the gun Vg, specimen Vs, lens electrode Vf, and analyzer bias Vb float. The incident energy at the sample can be varied from Vs = 0-1 KV for elastic imaging, or from Vg + Vs = (3 + Vs) KV for inelastic imaging. The image energy window Vs±V/2 may be varied without readjusting either the illumation, or imaging/analyzer optics. The diagram shows conjugate diffraction and image planes. The apertures defining incoming Humiliation and outgoing image angles are placed below the separator magnet to allow for their independent optimization. The instrument can illuminate and image 0.5-100 μm fields at 0-1 keV emission energies with an energy window down to 0.2 eV.

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