Eu3+and UO22+Surface Complexes on SiO2and TiO2: Models for Testing Mediated Electrochemical Methods for the Treatment of Actinide Processing Residues

2000 ◽  
pp. 83-97
Author(s):  
Tammy A. Diaz ◽  
Deborah S. Ehler ◽  
Carol J. Burns ◽  
Davis E. Morris
Keyword(s):  
Electrochemical Methods ◽  
Surface Complexes

Imaging molecules adsorbed onto electrodes under potential control by scanning probe microscopy

1991 ◽  
Vol 49 ◽  
pp. 376-377 ◽  
Author(s):  
N.J. Tao ◽  
J.A. DeRose ◽  
P.I. Oden ◽  
S.M. Lindsay
Keyword(s):  
Surface Charge ◽  
Environmental Effects ◽  
Scanning Probe Microscopy ◽  
Statistical Significance ◽  
Electrochemical Methods ◽  
Surface Structures ◽  
Scanning Probe ◽  
Potential Control ◽  
Afm Imaging ◽  
Special Circumstances

Clemmer and Beebe have pointed out that surface structures on graphite substrates can be misinterpreted as biopolymer images in STM experiments. We have been using electrochemical methods to react DNA fragments onto gold electrodes for STM and AFM imaging. The adsorbates produced in this way are only homogeneous in special circumstances. Searching an inhomogeneous substrate for ‘desired’ images limits the value of the data. Here, we report on a reversible method for imaging adsorbates. The molecules can be lifted onto and off the substrate during imaging. This leaves no doubt about the validity or statistical significance of the images. Furthermore, environmental effects (such as changes in electrolyte or surface charge) can be investigated easily.

Immunogold and immunoblot studies on a cell surface protein found in primary mesenchyme cells and in the cortical secretory vesicles of the sea urchin egg

1987 ◽  
Vol 45 ◽  
pp. 832-833
Author(s):  
G.L. Decker ◽  
M.C. Valdizan
Keyword(s):  
Cell Surface ◽  
Sea Urchin ◽  
Surface Protein ◽  
Egg Cell ◽  
Secretory Vesicles ◽  
Cell Surface Protein ◽  
Surface Complexes ◽  
Mesenchyme Cells ◽  
Lowicryl K4m ◽  
Primary Mesenchyme Cells

A monoclonal antibody designated MAb 1223 has been used to show that primary mesenchyme cells of the sea urchin embryo express a 130-kDa cell surface protein that may be directly involved in Ca2+ uptake required for growth of skeletal spicules. Other studies from this laboratory have shown that the 1223 antigen, although in relatively low abundance, is also expressed on the cell surfaces of unfertilized eggs and on the majority of blastomeres formed prior to differentiation of the primary mesenchyme cells.We have studied the distribution of 1223 antigen in S. purpuratus eggs and embryos and in isolated egg cell surface complexes that contain the cortical secretory vesicles. Specimens were fixed in 1.0% paraformaldehyde and 1.0% glutaraldehyde and embedded in Lowicryl K4M as previously reported. Colloidal gold (8nm diameter) was prepared by the method of Mulpfordt.

SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS

2011 ◽  
Vol 10 (5) ◽  
pp. 697-701 ◽  
Author(s):  
Firuta Fitigau ◽  
Claudia Popescu ◽  
Adina-Elena Segneanu ◽  
Ionel Balcu ◽  
Raluca Martagiu ◽  
...  
Keyword(s):  
Electrochemical Methods

Studies and Research on the Corrosion Behavior of Ni-Al2O3 Compound Coatings Obtained by Electrochemical Methods

2020 ◽  
Vol 43 (3) ◽  
pp. 21-25
Author(s):  
Simona BOICIUC ◽  
◽  
◽  
Keyword(s):  
Corrosion Resistance ◽  
Corrosion Behavior ◽  
Corrosion Behaviour ◽  
Composite Coatings ◽  
Point Of View ◽  
Electrochemical Methods ◽  
Dispersed Phase ◽  
Nickel Matrix ◽  
Technical Alumina ◽  
Compound Coatings

The undertaken research which is described in this paper aims at the corrosion behaviour of composite coatings in nickel matrix using as dispersed phase technical alumina with dimensions of 5 μm and their characterization from a microstructural point of view. The corrosion resistance in the saline fog of the coatings is influenced by the microstructure, the stresses developed in the layer and the roughness.

Uranyl Surface Complexes Formed on Subsurface Media from DOE Facilities

2002 ◽  
Vol 66 (1) ◽  
pp. 99 ◽  
Author(s):  
Benjamin C. Bostick ◽  
Scott Fendorf ◽  
Mark O. Barnett ◽  
Phillip M. Jardine ◽  
Scott C. Brooks
Keyword(s):  
Surface Complexes

Recent Progress in the Analysis of Captopril Using Electrochemical Methods: A Review

2019 ◽  
Vol 15 (3) ◽  
pp. 198-206 ◽  
Author(s):  
Sarfaraz Ahmed Mahesar ◽  
Saeed Ahmed Lakho ◽  
Syed Tufail Hussain Sherazi ◽  
Hamid Ali Kazi ◽  
Kamran Ahmed Abro ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Modified Electrodes ◽  
High Sensitivity ◽  
Pharmaceutical Formulations ◽  
Inorganic Materials ◽  
Electrochemical Methods ◽  
Nano Particles ◽  
Moderate Heart Failure ◽  
Analytical Instrumentation

Background: Captopril is the synthetic dipeptide used as an angiotensin converting enzyme inhibitor. Captopril is used to treat hypertension as well as for the treatment of moderate heart failure. Analytical instrumentation and methodology plays an important role in pharmaceutical analysis. Methods: This review presents some important applications of electrochemical modes used for the analysis of captopril. So far captopril has been analyzed by using different bare and modified working electrodes with a variety of modifiers from organic and inorganic materials to various types of nano particles/materials. Results: This paper presents some of the methods which have been published in the last few years i.e. from 2003 to 2016. This review highlights the role of the analytical instrumentation, particularly electrochemical methods in assessing captopril using various working electrodes. Conclusion: A large number of studies on voltammetry noted by means of various bare and modified electrodes. Among all of the published voltammetric methods, DPV, SWV, CV and miscellaneous modes were trendy techniques used to analyze captopril in pharmaceutical formulations as well as biological samples. Electrodes modified with nanomaterials are promising sensing tools as this showed high sensitivity, good accuracy with precision as well as selectivity. In comparison to chromatographic methods, the main advantages of electrochemical methods are its cheaper instrumentation, lower detection limit and minimal or no sample preparation.

Electroanalysis of Catecholamine Drugs using Graphene Modified Electrodes

2019 ◽  
Vol 15 (4) ◽  
pp. 443-466 ◽  
Author(s):  
Mahya Karami Mosammam ◽  
Mohammad Reza Ganjali ◽  
Mona Habibi-Kool-Gheshlaghi ◽  
Farnoush Faridbod
Keyword(s):  
Electrochemical Sensors ◽  
Modified Electrodes ◽  
Electrochemical Methods ◽  
High Signal ◽  
Signal To Noise ◽  
Low Level ◽  
Biological Studies

Background: Catecholamine drugs are a family of electroactive pharmaceutics, which are widely analyzed through electrochemical methods. However, for low level online determination and monitoring of these compounds, which is very important for clinical and biological studies, modified electrodes having high signal to noise ratios are needed. Numerous materials including nanomaterials have been widely used as electrode modifies for these families during the years. Among them, graphene and its family, due to their remarkable properties in electrochemistry, were extensively used in modification of electrochemical sensors. Objective: In this review, working electrodes which have been modified with graphene and its derivatives and applied for electroanalyses of some important catecholamine drugs are considered.

Electrochemical Methods for Corrosion Monitoring: A Survey of Recent Patents~!2009-10-01~!2009-11-25~!2010-02-18~!

2010 ◽  
Vol 2 (1) ◽  
pp. 34-39 ◽  
Author(s):  
Fei Kuang ◽  
Jinna Jinna ◽  
Changjun Zou ◽  
Taihe Shi ◽  
Yang Wang ◽  
...  
Keyword(s):  
Electrochemical Methods ◽  
Corrosion Monitoring

O-O bond activation with cobalt(II)-ethylenediamine complexes in ion-exchange resins

1980 ◽  
Vol 45 (6) ◽  
pp. 1780-1784 ◽  
Author(s):  
Atanas Andreev ◽  
Lachezar Prahov ◽  
Dimitar Shopov
Keyword(s):  
Ion Exchange ◽  
Bond Activation ◽  
Catalytic Properties ◽  
Decomposition Reaction ◽  
Ion Exchange Resins ◽  
Hydrogen Peroxide Decomposition ◽  
Surface Complexes ◽  
Peroxide Decomposition ◽  
Epr Parameters ◽  
Exchange Resins

The formation of Oxygen paramagnetic adducts of Co(II) containing ion-exchange resins in the presence of adsorbed ethylenediamine has been found. The EPR parameters of a complex of the type Co(III) (en)2O-2 and of O-2 species formed in the presence of Co(en)2+3 have been described. The catalytic properties of Co-ethylenediamine surface complexes with respect to the hydrogen peroxide decomposition reaction have been investigated and a probable mechanism has been suggested.

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