Bis(diphenylphosphino)methane in Organometallic Synthesis

1992 ◽  
pp. 173-185 ◽  
Author(s):  
Alan N. Hughes
Keyword(s):  
Organometallic Synthesis

scholarly journals Facile Organometallic Synthesis of Fe-Based Nanomaterials by Hot Injection Reaction

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1141
Author(s):  
Georgia Basina ◽  
Hafsa Khurshid ◽  
Nikolaos Tzitzios ◽  
George Hadjipanayis ◽  
Vasileios Tzitzios
Keyword(s):  
Room Temperature ◽  
Colloidal Particles ◽  
Iron Pentacarbonyl ◽  
Vibrating Sample Magnetometer ◽  
X Ray Diffraction ◽  
Organometallic Synthesis ◽  
X Ray ◽  
Transmission Electron ◽  
Hot Injection ◽  
The Stability

Fe-based colloids with a core/shell structure consisting of metallic iron and iron oxide were synthesized by a facile hot injection reaction of iron pentacarbonyl in a multi-surfactant mixture. The size of the colloidal particles was affected by the reaction temperature and the results demonstrated that their stability against complete oxidation related to their size. The crystal structure and the morphology were identified by powder X-ray diffraction and transmission electron microscopy, while the magnetic properties were studied at room temperature with a vibrating sample magnetometer. The injection temperature plays a very crucial role and higher temperatures enhance the stability and the resistance against oxidation. For the case of injection at 315 °C, the nanoparticles had around a 10 nm mean diameter and revealed 132 emu/g. Remarkably, a stable dispersion was created due to the colloids’ surface functionalization in a nonpolar solvent.

scholarly journals Study of Nucleation and Growth in the Organometallic Synthesis of Magnetic Alloy Nanocrystals: The Role of Nucleation Rate in Size Control of CoPt3 Nanocrystals.

ChemInform ◽  
2003 ◽  
Vol 34 (42) ◽  
Author(s):  
Elena V. Shevchenko ◽  
Dmitri V. Talapin ◽  
Heimo Schnablegger ◽  
Andreas Kornowski ◽  
Oerjan Festin ◽  
...  
Keyword(s):  
Nucleation Rate ◽  
Size Control ◽  
Nucleation And Growth ◽  
Magnetic Alloy ◽  
Organometallic Synthesis ◽  
Alloy Nanocrystals

Organometallic Synthesis in the Furazan Series. Part 2. Furazanylethanes.

ChemInform ◽  
2003 ◽  
Vol 34 (41) ◽  
Author(s):  
A. B. Sheremetev ◽  
E. A. Ivanova ◽  
A. Yu. Sizov ◽  
V. O. Kulagina ◽  
D. E. Dmitriev ◽  
...  
Keyword(s):  
Organometallic Synthesis

scholarly journals Acyclic 1,2-dimagnesioethanes/-ethene derived from magnesium(i) compounds: multipurpose reagents for organometallic synthesis

2019 ◽  
Vol 10 (11) ◽  
pp. 3208-3216 ◽  
Author(s):  
Deepak Dange ◽  
Andrew R. Gair ◽  
Dafydd D. L. Jones ◽  
Martin Juckel ◽  
Simon Aldridge ◽  
...  
Keyword(s):  
Metal Halide ◽  
Organometallic Synthesis ◽  
Novel Products

The sometimes redox reversible 1,2-additions of magnesium(i) dimers across several alkenes and one alkyne yield 1,2-dimagnesioethanes and a 1,2-dimagnesioethene. Treatment of these with bulky amido metal halide precursors affords novel products via three reactivity modes.

ChemInform Abstract: CHROMIUM ATOMS IN ORGANOMETALLIC SYNTHESIS

1973 ◽  
Vol 4 (30) ◽  
pp. no-no
Author(s):  
P. S. SKELL ◽  
D. L. WILLIAMS-SMITH ◽  
M. J. MCGLINCHEY
Keyword(s):  
Organometallic Synthesis
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