Transfer of Solution Reactivity Properties to Electrode Surfaces

1982 ◽  
pp. 133-158 ◽  
Author(s):  
HECTOR D. ABRUNA ◽  
JEFFREY M. CALVERT ◽  
PETER DENISEVICH ◽  
CHARLES D. ELLIS ◽  
THOMAS J. MEYER ◽  
...  
Keyword(s):  
Electrode Surfaces

The Plasma Technology for Shaping the Electric Pacemaker Electrode Surfaces Coated with Ruthenium

Vestnik MEI ◽  
2019 ◽  
Vol 6 ◽  
pp. 64-70
Author(s):  
Yuriy V. Martynenko ◽  
◽  
Vyacheslav P. Budaev ◽  
Keyword(s):  
Plasma Technology ◽  
Electrode Surfaces

Host-Guest Interactions on Electrode Surfaces for Immobilization of Molecular Catalysts

2020 ◽  
Author(s):  
Laurent Sévery ◽  
Jacek Szczerbiński ◽  
Mert Taskin ◽  
Isik Tuncay ◽  
Fernanda Brandalise Nunes ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Heterogeneous Systems ◽  
Catalytic Systems ◽  
New Approach ◽  
Molecular Systems ◽  
Electrode Surfaces ◽  
Catalytic Surfaces ◽  
Oxide Electrodes ◽  
The Stability ◽  
Molecular Catalysts

The strategy of anchoring molecular catalysts on electrode surfaces combines the high selectivity and activity of molecular systems with the practicality of heterogeneous systems. The stability of molecular catalysts is, however, far less than that of traditional heterogeneous electrocatalysts, and therefore a method to easily replace anchored molecular catalysts that have degraded could make such electrosynthetic systems more attractive. Here, we apply a non-covalent “click” chemistry approach to reversibly bind molecular electrocatalysts to electrode surfaces via host-guest complexation with surface-anchored cyclodextrins. The host-guest interaction is remarkably strong and allows the flow of electrons between the electrode and the guest catalyst. Electrosynthesis in both organic and aqueous media was demonstrated on metal oxide electrodes, with stability on the order of hours. The catalytic surfaces can be recycled by controlled release of the guest from the host cavities and readsorption of fresh guest. This strategy represents a new approach to practical molecular-based catalytic systems.

A simple strategy based on photobiotin irradiation for the photoelectrochemical immobilization of proteins on electrode surfaces

2006 ◽  
Vol 26 (2-3) ◽  
pp. 436-441 ◽  
Author(s):  
Serge Cosnier ◽  
Carmen Molins ◽  
Christine Mousty ◽  
Bruno Galland ◽  
Arielle Lepellec
Keyword(s):  
Electrode Surfaces ◽  
Simple Strategy

scholarly journals The Role of Peptides in the Design of Electrochemical Biosensors for Clinical Diagnostics

Biosensors ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 246
Author(s):  
Patrick Severin Sfragano ◽  
Giulia Moro ◽  
Federico Polo ◽  
Ilaria Palchetti
Keyword(s):  
Functional Groups ◽  
Synthetic Peptides ◽  
Clinical Diagnostics ◽  
Electrochemical Biosensors ◽  
Practical Application ◽  
Design And Development ◽  
Electrode Surfaces ◽  
Electrochemical Transducers ◽  
Target Analyte

Peptides represent a promising class of biorecognition elements that can be coupled to electrochemical transducers. The benefits lie mainly in their stability and selectivity toward a target analyte. Furthermore, they can be synthesized rather easily and modified with specific functional groups, thus making them suitable for the development of novel architectures for biosensing platforms, as well as alternative labelling tools. Peptides have also been proposed as antibiofouling agents. Indeed, biofouling caused by the accumulation of biomolecules on electrode surfaces is one of the major issues and challenges to be addressed in the practical application of electrochemical biosensors. In this review, we summarise trends from the last three years in the design and development of electrochemical biosensors using synthetic peptides. The different roles of peptides in the design of electrochemical biosensors are described. The main procedures of selection and synthesis are discussed. Selected applications in clinical diagnostics are also described.

Enabling directional ion transport over graphene electrode surfaces for kilohertz electrochemical capacitors

2021 ◽  
Vol 368 ◽  
pp. 137561
Author(s):  
Lixia Wang ◽  
Zhou Li ◽  
Meirong Song ◽  
Cuilian Xu ◽  
Zhonghu Liu ◽  
...  
Keyword(s):  
Ion Transport ◽  
Electrochemical Capacitors ◽  
Electrode Surfaces ◽  
Graphene Electrode

Electrochemical Eu(III)/Eu(II) behaviors and recovery over terpyridyl-derivatized modified indium tin oxide electrode surfaces

2021 ◽  
Vol 412 ◽  
pp. 128717
Author(s):  
So Jeong Park ◽  
Min Hee Joo ◽  
Sung-Min Hong ◽  
Choong Kyun Rhee ◽  
Jun-Gill Kang ◽  
...  
Keyword(s):  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Oxide Electrode ◽  
Indium Tin Oxide Electrode ◽  
Electrode Surfaces

The Lead Dioxide Anode. II. The Kinetics and Participation of the Lead Dioxide Electrode in Electrochemical Oxidation Reactions in Sulfuric Acid

1989 ◽  
Vol 42 (9) ◽  
pp. 1527 ◽  
Author(s):  
TH Randle ◽  
AT Kuhn
Keyword(s):  
Sulfuric Acid ◽  
Electrochemical Oxidation ◽  
Maximum Rate ◽  
Lead Dioxide ◽  
Chemical Oxidation ◽  
Oxidation Reactions ◽  
Electrochemical Regeneration ◽  
Electrode Surfaces ◽  
Lead Dioxide Electrode ◽  
Lead Dioxide Anode

Lead dioxide is a strong oxidizer in sulfuric acid, consequently electrochemical oxidation of solution species at a lead dioxide anode may occur by a two-step, C-E process (chemical oxidation of solution species by PbO2 followed by electrochemical regeneration of the reduced lead dioxide surface). The maximum rate of each step has been determined in sulfuric acid for specified lead dioxide surfaces and compared with the rates observed for the electrochemical oxidation of cerium(III) and manganese(II) on the same electrode surfaces. While the rate of electrochemical oxidation of a partially reduced PbO2 surface may be sufficient to support the observed rates of CeIII and MnII oxidation at the lead dioxide anode, the rate of chemical reaction between PbO2 and the reducing species is not. Hence it is concluded that the lead dioxide electrode functions as a simple, 'inert' electron-transfer agent during the electrochemical oxidation of CellI and MnII in sulfuric acid. In general, it will most probably be the rate of the chemical step which determines the feasibility or otherwise of the C-E mechanism.

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