Internal Water Molecules ofpharaonisPhoborhodopsin Studied by Low-Temperature Infrared Spectroscopy†

Biochemistry ◽  
2001 ◽  
Vol 40 (51) ◽  
pp. 15693-15698 ◽  
Author(s):  
Hideki Kandori ◽  
Yuji Furutani ◽  
Kazumi Shimono ◽  
Yoshinori Shichida ◽  
Naoki Kamo
1999 ◽  
Vol 39 (supplement) ◽  
pp. S74
Author(s):  
A. Maeda ◽  
F. L. Tomson ◽  
R. B. Gennis ◽  
T. G. Ebrey ◽  
S. P. Balashov

2010 ◽  
Vol 98 (3) ◽  
pp. 287a
Author(s):  
Mikkel Jensen ◽  
Erica C. Saint Clair ◽  
Alan Gabel ◽  
Vladislav B. Bergo ◽  
Elena N. Spudich ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3089
Author(s):  
Peilei Zhou ◽  
Wensheng Wang ◽  
Lili Zhu ◽  
Haoyun Wang ◽  
Yongming Ai

This study aims to investigate the performance evolution and mechanism of asphalt under action of chloride salt erosion. Asphalt samples soaked with five different snow melting chloride salt concentrations were taken as the research object. Then, the high-temperature performance, low-temperature performance, temperature sensitivity and asphalt–aggregate adhesion property of asphalt samples were carried out. Additionally, Fourier transform infrared spectroscopy (FTIR) was used to explore the mechanism of chloride salt erosion on asphalt. Test results showed the linear variation relationships of high-temperature performance, low-temperature performance and temperature sensitivity with chloride salt concentrations. The high-temperature performance of asphalt would be improved by chloride snowmelt salt. With the increase in the chloride salt solution concentration, the low-temperature performance of asphalt became worse, and the temperature sensitivity increased. Moreover, after the effect of the chloride salt solution, the asphalt–aggregate adhesion property decreased with the increase in the chloride salt solution concentration. It is necessary to control the amount of chloride snowmelt salt in the actual snow removal projects. Finally, based on Fourier transform infrared spectroscopy, the mechanism of chloride salt erosion on asphalt was preliminarily explored. With the increase in the chloride salt solution concentration, the proportion of light components (saturated fraction, aromatic fraction) in asphalt decreased, and the proportion of heavy components (resin and asphaltene) with good thermal stability increased.


2009 ◽  
Vol 96 (3) ◽  
pp. 680a
Author(s):  
Eduardo Jardón-Valadez ◽  
Ana-Nicoleta Bondar ◽  
Douglas J. Tobias

2007 ◽  
Vol 5 (1) ◽  
pp. 169-176 ◽  
Author(s):  
Abdülhadi Baykal ◽  
Yüksel Köseoğlu ◽  
Mehmet Şenel

AbstractHeating hydrous manganese (II) hydroxide gel at 85 °C for 12 hours produces Mn3O4 nanoparticles. They were characterized by X-ray powder diffraction (XRD) and infrared spectroscopy (FTIR). The particle size estimated from the SEM and X-ray peak broadening is approximately 32 nm, showing them to be nanocrystalline. EPR measurements confirm a typical Mn2+signal with a highly resolved hyperfine structure.


2021 ◽  
Author(s):  
Rahma Rahzelli Zrelli ◽  
Fathia Chehimi-Moumen ◽  
Dalila Ben Hassen-Chehimi ◽  
Malika Trabelsi-Ayadi

Abstract The synthesis of the diphosphate HYP2O7·3H2O was made via soft chemistry route from evaporation of aqueous solution at room temperature. The obtained compound, was characterized by means of X-ray diffraction (XRD) and infrared spectroscopy (IR). The results showed a high purity phase. IR spectrum of this diphosphate revealed usual signals related to P2O7 diphosphate group and water molecules. The thermal decomposition of the synthesized product by DTA / TG proceeded through four stages leading to the formation of the Y2P4O13 as a final product. On the other hand, its decomposition by CRTA took place in three stages leading to the formation of the anhydrous diphosphate HYP2O7 as a final product. X-ray powder diffraction and infrared spectroscopy were used to identify these materials. Furthermore the electrical properties of the HYP2O7 were investigated through impedance complex analysis. Modest conductivity has been observed in this material at relatively medium temperature range. Activation energy of 0.67 and 1.44 eV, was deduced from the corresponding Arrhenius plot.The optical band gap of the title compound is calculated and found to be 2.71 eV.


2002 ◽  
Vol 19 (4) ◽  
pp. 257-265 ◽  
Author(s):  
Yuji Furutani ◽  
Hideki Kandori

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