Studies on the Mechanism of Enzyme-Catalyzed Oxidation Reduction Reactions. II. Methods for Characterization of the Mechanism for Two-Substrate Systems*

Biochemistry ◽  
1962 ◽  
Vol 1 (1) ◽  
pp. 35-40 ◽  
Author(s):  
R. H. Baker ◽  
H. R. Mahler
1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.


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