Kinetic mapping of the antibody combining site by chemical relaxation spectrometry

Biochemistry ◽  
1974 ◽  
Vol 13 (10) ◽  
pp. 2210-2222 ◽  
Author(s):  
David Haselkorn ◽  
Suzan Friedman ◽  
David Givol ◽  
Israel Pecht
Keyword(s):  
Chemical Relaxation

Chemical Stress Relaxation of NR Networks Prepared in the Swollen State

1986 ◽  
Vol 59 (4) ◽  
pp. 541-550 ◽  
Author(s):  
Kyung-Do Suh ◽  
Hidetoshi Oikawa ◽  
Kenkichi Murakami
Keyword(s):  
Stress Relaxation ◽  
Network Structure ◽  
Three Dimensional ◽  
Polymer Chains ◽  
Chemical Stress ◽  
Network Chain ◽  
Crosslinking Process ◽  
Dimensional Network ◽  
Chemical Relaxation ◽  
The Difference

Abstract From the experimental results of the present investigation, it is apparent that two kinds of networks which have a different three-dimensional network structure give quite different behavior of chemical stress relaxation, even if both networks have the same network chain density. The difference in three-dimensional network structure for the two kinds of rubber arises from the degree of entanglement, which changes with the concentration of the polymer chains prior to the crosslinking process. The direct cause of chemical relaxation is due to the scission of network chains by degradation, whereas the total relaxation is caused by the change of geometrical conformation of network chains. This then casts doubt on the basic concept of chemorheology which is represented by Equation 2.

Rubber elasticity on chemical relaxation

1972 ◽  
Vol 16 (9) ◽  
pp. 2249-2255 ◽  
Author(s):  
Kenkichi Murakami ◽  
Gin-ho Hisue
Keyword(s):  
Rubber Elasticity ◽  
Chemical Relaxation

Effect of temperature on the chemical relaxation process in rubbers

1971 ◽  
Vol 3 (3) ◽  
pp. 298-303 ◽  
Author(s):  
G. M. Bartenev ◽  
N. G. Kolyadina ◽  
D. Z. Novikova ◽  
B. Kh. Avrushchenko
Keyword(s):  
Relaxation Process ◽  
Effect Of Temperature ◽  
Chemical Relaxation

scholarly journals Perturbed and Unperturbed: Analyzing the Conservatively Perturbed Equilibrium (Linear Case)

Entropy ◽  
2020 ◽  
Vol 22 (10) ◽  
pp. 1160
Author(s):  
Yiming Xi ◽  
Xinquan Liu ◽  
Denis Constales ◽  
Gregory S. Yablonsky
Keyword(s):  
Inflection Point ◽  
Extreme Values ◽  
Chemical Elements ◽  
Batch Reactor ◽  
Chemical System ◽  
Essential Information ◽  
Detailed Mechanism ◽  
Chemical Relaxation ◽  
One Step ◽  
Equilibrium Concentrations

The “conservatively perturbed equilibrium” (CPE) technique for a complex chemical system is computationally analyzed in a batch reactor considering different linear mechanisms with three and four species. Contrary to traditional chemical relaxation procedures, in CPE experiments only some initial concentrations are modified; other conditions, including the total amount of chemical elements and temperature are kept unchanged. Generally, for “unperturbed” species with initial concentrations equal to their corresponding equilibrium concentrations, unavoidable extreme values are observed during relaxation to the equilibrium. If the unperturbed species is involved in one step only, this extremum is a momentary equilibrium of the step; if the unperturbed species is involved in more reactions, the extremum is not a momentary equilibrium. The acyclic mechanism with four species may exhibit two extrema and an inflection point, which corresponds to an extremum of the rate of the species change. These facts provide essential information about the detailed mechanism of the complex reaction.

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