Role of internal thermodynamics in determining hydrogen tunneling in enzyme-catalyzed hydrogen transfer reactions

Biochemistry ◽  
1992 ◽  
Vol 31 (46) ◽  
pp. 11489-11499 ◽  
Author(s):  
J. Rucker ◽  
Y. Cha ◽  
T. Jonsson ◽  
K. L. Grant ◽  
J. P. Klinman
Keyword(s):  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Hydrogen Tunneling ◽  
Hydrogen Transfer Reactions

Role of .sigma.-Donation in the Stereocontrol of Hydrogen-Transfer Reactions Involving Acyclic Radicals

1995 ◽  
Vol 60 (2) ◽  
pp. 288-289 ◽  
Author(s):  
Y. Guindon ◽  
A. Slassi ◽  
J. Rancourt ◽  
G. Bantle ◽  
M. Bencheqroun ◽  
...  
Keyword(s):  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Hydrogen Transfer Reactions

The role of acid–base equilibria in formal hydrogen transfer reactions: tryptophan radical repair by uric acid as a paradigmatic case

2017 ◽  
Vol 19 (23) ◽  
pp. 15296-15309 ◽  
Author(s):  
Leonardo Muñoz-Rugeles ◽  
Annia Galano ◽  
Juan Raúl Alvarez-Idaboy
Keyword(s):  
Electron Transfer ◽  
Uric Acid ◽  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Acid Base ◽  
Transfer Mechanisms ◽  
Hydrogen Transfer Reactions

The sequential proton gain electron transfer and proton electron sequential transfer mechanisms play the most important roles in tryptophan repair by uric acid.

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