Rotational dynamics of hexaamminecobalt(III) bound to oligomeric DNA: Correlation with cation-induced structural transitions

Biochemistry ◽  
1993 ◽  
Vol 32 (44) ◽  
pp. 11754-11760 ◽  
Author(s):  
Qiuwei Xu ◽  
Srinivas Rao B. Jampani ◽  
William H. Braunlin
Keyword(s):  
Rotational Dynamics ◽  
Structural Transitions ◽  
Oligomeric Dna

Introductory Rotational Dynamics

2018 ◽  
Author(s):  
Peter Mann
Keyword(s):  
Angular Momentum ◽  
Angular Displacement ◽  
Rigid Bodies ◽  
Rotational Dynamics ◽  
Circular Motion ◽  
Uniform Rotation ◽  
Chemical Systems ◽  
Inertial Frames ◽  
Rotating Frames ◽  
Special Case

This chapter discusses the importance of circular motion and rotations, whose applications to chemical systems are plentiful. Circular motion is the book’s first example of a special case of motion using the laws developed in previous chapters. The chapter begins with the basic definitions of circular motion; as uniform rotation around a principle axis is much easier to consider, it is the focus of this chapter and is used to develop some key ideas. The chapter discusses angular displacement, angular velocity, angular momentum, torque, rigid bodies, orbital and spin momenta, inertia tensors and non-inertial frames and explores fictitious forces as well as transformations in rotating frames.

scholarly journals Temperature and Pressure Variation of the Cl-NQR in A2PbCl6-Crystals

1986 ◽  
Vol 41 (1-2) ◽  
pp. 311-314 ◽  
Author(s):  
Y. M. Seo ◽  
J. Pelzl ◽  
C. Dimitropoulos
Keyword(s):  
Relaxation Rate ◽  
Room Temperature ◽  
Lattice Relaxation ◽  
Pressure Variation ◽  
Mixed Crystals ◽  
Spin Lattice Relaxation ◽  
Structural Transitions ◽  
Spin Lattice Relaxation Rate ◽  
Spin Lattice ◽  
Temperature And Pressure

The 35Cl NQR frequency and spin-lattice relaxation rate in the compounds A2PbCl6 (A = Cs, Rb, NH4, K) have been investigated in the range 4.2 K to 500 K, and as a function of pressure at room temperature. NQR experiments conducted on (K: NH4)2PbCl6 mixed crystals have been used to complete the NQR-frequency versus temperature diagram of K2PbCl6, revealing two structural transitions at Tc1 ≅ 358 K and at TC2 ≅ 333 K.

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