Intramolecular electron transfer in cytochrome o of Escherichia coli: events following the photolysis of fully and partially reduced carbon monoxide-bound forms of the bo3 and oo3 enzymes

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A cyanide-bridged trigonal bipyramidal [Co3Fe2] cluster shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition behaviour.


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