Aqueous RAFT Polymerization:  Recent Developments in Synthesis of Functional Water-Soluble (Co)polymers with Controlled Structures†

2004 ◽  
Vol 37 (5) ◽  
pp. 312-325 ◽  
Author(s):  
Charles L. McCormick ◽  
Andrew B. Lowe
Keyword(s):  
Raft Polymerization ◽  
Water Soluble ◽  
Recent Developments ◽  
Controlled Structures

Modification of Gold Surfaces with Water-Soluble (Co)polymers Prepared via Aqueous Reversible Addition−Fragmentation Chain Transfer (RAFT) Polymerization†

Langmuir ◽  
2003 ◽  
Vol 19 (14) ◽  
pp. 5559-5562 ◽  
Author(s):  
Brent S. Sumerlin ◽  
Andrew B. Lowe ◽  
Paul A. Stroud ◽  
Ping Zhang ◽  
Marek W. Urban ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Water Soluble ◽  
Gold Surfaces ◽  
Reversible Addition

Study of the RAFT Polymerization of a Water-Soluble Bisubstituted Acrylamide Derivative. 1. Influence of the Dithioester Structure

2002 ◽  
Vol 35 (22) ◽  
pp. 8271-8280 ◽  
Author(s):  
Arnaud Favier ◽  
Marie-Thérèse Charreyre ◽  
Philippe Chaumont ◽  
Christian Pichot
Keyword(s):  
Raft Polymerization ◽  
Water Soluble

Synthesis of water-soluble homo- and block-copolymers by RAFT polymerization under γ-irradiation in aqueous media

Polymer ◽  
2010 ◽  
Vol 51 (19) ◽  
pp. 4319-4328 ◽  
Author(s):  
Pierre-Eric Millard ◽  
Leonie Barner ◽  
Jürgen Reinhardt ◽  
Michael R. Buchmeiser ◽  
Christopher Barner-Kowollik ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Raft Polymerization ◽  
Aqueous Media ◽  
Water Soluble ◽  
Γ Irradiation

scholarly journals Surface functionalization of aluminosilicate nanotubes with organic molecules

2012 ◽  
Vol 3 ◽  
pp. 82-100 ◽  
Author(s):  
Wei Ma ◽  
Weng On Yah ◽  
Hideyuki Otsuka ◽  
Atsushi Takahara
Keyword(s):  
Surface Functionalization ◽  
Organic Molecules ◽  
Photophysical Properties ◽  
Acid Group ◽  
Water Soluble ◽  
Dimensional Structure ◽  
Inorganic Nanotubes ◽  
Surface Initiated Polymerization ◽  
Recent Developments ◽  
Potential Applications

The surface functionalization of inorganic nanostructures is an effective approach for enriching the potential applications of existing nanomaterials. Inorganic nanotubes attract great research interest due to their one-dimensional structure and reactive surfaces. In this review paper, recent developments in surface functionalization of an aluminosilicate nanotube, “imogolite”, are introduced. The functionalization processes are based on the robust affinity between phosphate groups of organic molecules and the aluminol (AlOH) surface of imogolite nanotubes. An aqueous modification process employing a water soluble ammonium salt of alkyl phosphate led to chemisorption of molecules on imogolite at the nanotube level. Polymer-chain-grafted imogolite nanotubes were prepared through surface-initiated polymerization. In addition, the assembly of conjugated molecules, 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-yl)ethylphosphonic acid (HT3P) and 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-yl)ethylphosphonic acid 1,1-dioxide (HT3OP), on the imogolite nanotube surface was achieved by introducing a phosphonic acid group to the corresponding molecules. The optical and photophysical properties of these conjugated-molecule-decorated imogolite nanotubes were characterized. Moreover, poly(3-hexylthiophene) (P3HT) chains were further hybridized with HT3P modified imogolite to form a nanofiber hybrid.

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