Chemical reactions and energy transfer processes of electronically excited Group IIB metal atoms: full collisions and half-collisions

1989 ◽  
Vol 22 (1) ◽  
pp. 21-27 ◽  
Author(s):  
William H. Breckenridge
Keyword(s):  
Energy Transfer ◽  
Chemical Reactions ◽  
Transfer Processes ◽  
Metal Atoms ◽  
Electronically Excited

The Quantum Classical Theory

2003 ◽  
Keyword(s):  
Energy Transfer ◽  
Chemical Reactions ◽  
Cross Sections ◽  
Plasma Chemistry ◽  
Theoretical Background ◽  
Theoretical Description ◽  
Surface Dynamics ◽  
Gas Lasers ◽  
Transfer Processes ◽  
Kinetics Of

Over a period of fifty years, the quantum-classical or semi-classical theories have been among the most popular for calculations of rates and cross sections for many dynamical processes: energy transfer, chemical reactions, photodissociation, surface dynamics, reactions in clusters and solutions, etc. These processes are important in the simulation of kinetics of processes in plasma chemistry, chemical reactors, chemical or gas lasers, atmospheric and interstellar chemistry, as well as various industrial processes. This book gives an overview of quantum-classical methods that are currently used for a theoretical description of these molecular processes. It gives the theoretical background for the derivation of the theories from first principles. Enough details are provided to allow numerical implementation of the methods. The book gives the necessary background for understanding the approximations behind the methods and the working schemes for treating energy transfer processes from diatomic to polyatomic molecules, reactions at surfaces, non-adiabatic processes, and chemical reactions.

Energy transfer processes of working gas in pulse tube

2000 ◽  
Author(s):  
Vincenzo Naso ◽  
Marco Lucentini ◽  
Wei Dong
Keyword(s):  
Energy Transfer ◽  
Pulse Tube ◽  
Transfer Processes

Carbon-Heteroatom Cross-Coupling via an Electronically Excited Nickel (II) Complex

2019 ◽  
Author(s):  
Randolph Escobar ◽  
Jeffrey Johannes
Keyword(s):  
Energy Transfer ◽  
Functional Groups ◽  
Cross Coupling ◽  
Reductive Elimination ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
General Methodology ◽  
Cross Coupling Reactions ◽  
Electronically Excited ◽  
Energy Transfer Pathway

<div>While carbon-heteroatom cross coupling reactions have been extensively studied, many methods are specific and</div><div>limited to a set of substrates or functional groups. Reported here is a method that allows for C-O, C-N and C-S cross coupling reactions under one general methodology. We propose that an energy transfer pathway, in which an iridium photosensitizer produces an excited nickel (II) complex, is responsible for the key reductive elimination step that couples aryl halides to 1° and 2° alcohols, anilines, thiophenols, carbamates and sulfonamides.</div>

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