Polyethylenimine Aqueous Solution: A Low-Cost and Environmentally Friendly Formulation to Produce Low-Work-Function Electrodes for Efficient Easy-to-Fabricate Organic Solar Cells

2014 ◽  
Vol 6 (24) ◽  
pp. 22628-22633 ◽  
Author(s):  
Xue Min ◽  
Fangyuan Jiang ◽  
Fei Qin ◽  
Zaifang Li ◽  
Jinhui Tong ◽  
...  
2020 ◽  
Vol 56 (92) ◽  
pp. 14337-14352
Author(s):  
Lijiao Ma ◽  
Shaoqing Zhang ◽  
Jingwen Wang ◽  
Ye Xu ◽  
Jianhui Hou

The key factors for OSC materials toward application mainly include high performance, thickness tolerance, low cost, simple fabrication processing, high stability, and an environmentally-friendly nature.


2014 ◽  
Vol 2 (19) ◽  
pp. 6734-6739 ◽  
Author(s):  
Riming Nie ◽  
Aiyuan Li ◽  
Xianyu Deng

Peptides present a low cost and environmentally friendly route to facilitate the fabrication of organic solar cells.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Juanyong Wan ◽  
Yonggao Xia ◽  
Junfeng Fang ◽  
Zhiguo Zhang ◽  
Bingang Xu ◽  
...  

AbstractNonfullerene organic solar cells (OSCs) have achieved breakthrough with pushing the efficiency exceeding 17%. While this shed light on OSC commercialization, high-performance flexible OSCs should be pursued through solution manufacturing. Herein, we report a solution-processed flexible OSC based on a transparent conducting PEDOT:PSS anode doped with trifluoromethanesulfonic acid (CF3SO3H). Through a low-concentration and low-temperature CF3SO3H doping, the conducting polymer anodes exhibited a main sheet resistance of 35 Ω sq−1 (minimum value: 32 Ω sq−1), a raised work function (≈ 5.0 eV), a superior wettability, and a high electrical stability. The high work function minimized the energy level mismatch among the anodes, hole-transporting layers and electron-donors of the active layers, thereby leading to an enhanced carrier extraction. The solution-processed flexible OSCs yielded a record-high efficiency of 16.41% (maximum value: 16.61%). Besides, the flexible OSCs afforded the 1000 cyclic bending tests at the radius of 1.5 mm and the long-time thermal treatments at 85 °C, demonstrating a high flexibility and a good thermal stability.


2021 ◽  
Author(s):  
Junzhen Ren ◽  
Pengqing Bi ◽  
Jianqi Zhang ◽  
Jiao Liu ◽  
Jingwen Wang ◽  
...  

Abstract Developing photovoltaic materials with simple chemical structures and easy synthesis still remains a major challenge in the industrialization process of organic solar cells (OSCs). Herein, an ester substituted poly(thiophene vinylene) derivative, PTVT-T, was designed and synthesized in very few steps by adopting commercially available raw materials. The ester groups on the thiophene units enable PTVT-T to have a planar and stable conformation. Moreover, PTVT-T presents a wide absorption band and strong aggregation effect in solution, which are the key characteristics needed to realize high performance in non-fullerene-acceptor (NFA)-based OSCs. We then prepared OSCs by blending PTVT-T with three representative fullerene- and NF-based acceptors, PC71BM, IT-4F and BTP-eC9. It was found that PTVT-T can work well with all the acceptors, showing great potential to match new emerging NFAs. Particularly, a remarkable power conversion efficiency of 16.20% is achieved in a PTVT-T:BTP-eC9-based device, which is the highest value among the counterparts based on PTV derivatives. This work demonstrates that PTVT-T shows great potential for the future commercialization of OSCs.


Author(s):  
Dorota Zając ◽  
Dariusz Przybylski ◽  
Jadwiga Sołoducho

AbstractDeveloping effective and low‐cost organic semiconductors is an opportunity for the development of organic solar cells (OPV). Herein, we report the molecular design, synthesis and characterization of two molecules with D–A–D–A configuration: 2-cyano-3-(5-(8-(3,4-ethylenodioxythiophen-5-yl)-2,3-diphenylquinoxalin-5-yl)thiophen-2-yl)acrylic acid (6) and 2-cyano-3-(5-(2,3-diphenyl-8-(thiophen-2-yl)quinoxalin-5-yl)thiophen-2-yl)acrylic acid (7). Moreover, we investigated the structural, theoretical and optical properties. The distribution of HOMO/LUMO orbitals and the values of the ionization potential indicate good semiconducting properties of the compounds and that they can be a bipolar material. Also, the optical study show good absorption in visible light (λabs 380–550 nm). We investigate the theoretical optoelectronic properties of obtained compounds as potential materials for solar cells.


Solar RRL ◽  
2021 ◽  
Author(s):  
Jiage Song ◽  
Fangfang Cai ◽  
Can Zhu ◽  
Honggang Chen ◽  
Qingya Wei ◽  
...  

2012 ◽  
Vol 576 ◽  
pp. 773-776 ◽  
Author(s):  
Puteri Sarah Mohamad Saad ◽  
F.S.S. Zahid ◽  
M. Rusop

This paper investigates the performance of organic solar cells by using different types of metal contact. The metal contacts that have been chosen are Ag, Au and Pt. The different work function of the metals will influence the efficiency of the organic solar cells. From the results it can be seen that the absorbance value is quite high around 0.5 which absorb more photon when it is illuminated. The efficiency of the device using Pt shows the highest efficiency which is 10.62x10-3% followed by Au with 8.01x10-4% and Ag 1.25x10-4%.


2021 ◽  
pp. 2110159
Author(s):  
Jing Guo ◽  
Beibei Qiu ◽  
Dengchen Yang ◽  
Can Zhu ◽  
Liuyang Zhou ◽  
...  

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