A Highly Sensitive Hydrogen Sensor with Gas Selectivity Using a PMMA Membrane-Coated Pd Nanoparticle/Single-Layer Graphene Hybrid

2015 ◽  
Vol 7 (6) ◽  
pp. 3554-3561 ◽  
Author(s):  
Juree Hong ◽  
Sanggeun Lee ◽  
Jungmok Seo ◽  
Soonjae Pyo ◽  
Jongbaeg Kim ◽  
...  
2012 ◽  
Vol 717-720 ◽  
pp. 687-690
Author(s):  
Ruth Pearce ◽  
R. Yakimova ◽  
L. Hultman ◽  
Jens Eriksson ◽  
Mike Andersson ◽  
...  

Epitaxially grown single layer graphene on silicon carbide (SiC) resistive sensors were characterised for NO2 response at room and elevated temperatures, with an n-p type transition observed with increasing NO2 concentrations for all sensors. The concentration of NO2 required to cause this transition varied with different graphene samples and is attributed to varying degrees of substrate induced Fermi-level pinning above the Dirac point. The work function of a single layer device demonstrated a steady increase in work function with increasing NO2 concentration indicating no change in reaction mechanism in the concentration range measured despite a change in sensor response direction. Epitaxially grown graphene device preparation is challenging due to poor adhesion of the graphene layer to the substrate. A field effect transistor (FET) device is presented which does not require wire bonding to contacts on graphene.


2016 ◽  
Vol 24 (23) ◽  
pp. 25922 ◽  
Author(s):  
Feng-Xia Liang ◽  
Deng-Yue Zhang ◽  
Jiu-Zhen Wang ◽  
Wei-Yu Kong ◽  
Zhi-Xiang Zhang ◽  
...  

2017 ◽  
Vol 46 (6) ◽  
pp. 3353-3358 ◽  
Author(s):  
Nguyen Hai Ha ◽  
Cung Thanh Long ◽  
Nguyen Hoang Nam ◽  
Nguyen Thi Hue ◽  
Nguyen Huy Phuong ◽  
...  

2019 ◽  
Vol 33 (31) ◽  
pp. 1950384
Author(s):  
Di Lu ◽  
Yu-E Yang ◽  
Weichun Zhang ◽  
Caixia Wang ◽  
Jining Fang ◽  
...  

We have investigated Raman spectra of the G and 2D lines of a single-layer graphene (SLG) with metallic contacts. The shift of the G and 2D lines is correlated to two different factors. Before performing annealing treatment or annealing under low temperature, the electron transfer on graphene surface is dominated by nonuniform strain effect. As the annealing treatment is enhanced, however, a suitable annealing treatment can eliminate the nonuniform strain effect where the relative work function (WF) between graphene and metal becomes a main factor to determine electronic transfer. Moreover, it is confirmed that the optimized annealing treatment can also decrease effectively the structural defect and induced disorder in graphene due to metallic contacts.


2021 ◽  
Vol 7 (9) ◽  
pp. eabf0116
Author(s):  
Shiqi Huang ◽  
Shaoxian Li ◽  
Luis Francisco Villalobos ◽  
Mostapha Dakhchoune ◽  
Marina Micari ◽  
...  

Etching single-layer graphene to incorporate a high pore density with sub-angstrom precision in molecular differentiation is critical to realize the promising high-flux separation of similar-sized gas molecules, e.g., CO2 from N2. However, rapid etching kinetics needed to achieve the high pore density is challenging to control for such precision. Here, we report a millisecond carbon gasification chemistry incorporating high density (>1012 cm−2) of functional oxygen clusters that then evolve in CO2-sieving vacancy defects under controlled and predictable gasification conditions. A statistical distribution of nanopore lattice isomers is observed, in good agreement with the theoretical solution to the isomer cataloging problem. The gasification technique is scalable, and a centimeter-scale membrane is demonstrated. Last, molecular cutoff could be adjusted by 0.1 Å by in situ expansion of the vacancy defects in an O2 atmosphere. Large CO2 and O2 permeances (>10,000 and 1000 GPU, respectively) are demonstrated accompanying attractive CO2/N2 and O2/N2 selectivities.


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