Green Synthesis of Large-Scale Highly Ordered Core@Shell Nanoporous Au@Ag Nanorod Arrays as Sensitive and Reproducible 3D SERS Substrates

2014 ◽  
Vol 6 (18) ◽  
pp. 15667-15675 ◽  
Author(s):  
Bin Chen ◽  
Guowen Meng ◽  
Qing Huang ◽  
Zhulin Huang ◽  
Qiaoling Xu ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (71) ◽  
pp. 67204-67211 ◽  
Author(s):  
Chih-Wei Chiu ◽  
Po-Hsien Lin

A novel flexible, freestanding, large-scale, and disposable SERS substrate of core/shell Ag@silicate and poly(vinyl alcohol) spherical nanohybrids, fabricated by coaxial electrospray, allows for the high-efficiency detection of adenine from DNA.


Author(s):  
Azam Ali ◽  
Mehrukh Zehravi ◽  
Muhammad Humble Khalid Treen ◽  
Jiri Militky ◽  
Fiaz Hussain ◽  
...  

The versatile one-pot green synthesis of a highly concentrated and stable colloidal dispersion of AgNPs was carried out using the self-assembled tannic acid without using any other hazardous chemicals. Tannic acid (Plant-based polyphenol) was used as a reducing and stabilizing agent for silver nitrate in a mild alkaline condition. The synthesized AgNPs were characterized for their concentration, capping, size distribution, and shape. The experimental results confirmed the successful synthesis of nearly spherical and highly concentrated (2281 ppm) AgNPs, capped with poly-tannic acid (AgNPs-PTA). The average particle size of AgNPs-PTA was found 9.90 ± 1.60 nm. The colloidal dispersion of synthesized nanoparticles was observed stable for more than 15 months in the ambient environment (25 oC, 65 % relative humidity). The synthesized AgNPs-PTA showed an effective antimicrobial activity against Staphylococcus Aureus Escherichia coli. Ag-PTA also exhibited enhanced catalytic properties. It reduces 4-nitrophenol into 4-aminophenol in the presence of NaBH4 with a normalized rate constant (Knor = K/m) of 615.04 mL·s-1·mg-1. Furthermore, AgNPs-PTA were stable for more than 15 months under ambient conditions. The unique core-shell structure and ease of synthesis render the synthesized nanoparticles superior to others, with potential for large-scale applications, especially in the field of catalysis and biomedical.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1007
Author(s):  
Azam Ali ◽  
Mariyam Sattar ◽  
Fiaz Hussain ◽  
Muhammad Humble Khalid Tareen ◽  
Jiri Militky ◽  
...  

The versatile one-pot green synthesis of a highly concentrated and stable colloidal dispersion of silver nanoparticles (Ag NPs) was carried out using the self-assembled tannic acid without using any other hazardous chemicals. Tannic acid (Plant-based polyphenol) was used as a reducing and stabilizing agent for silver nitrate in a mild alkaline condition. The synthesized Ag NPs were characterized for their concentration, capping, size distribution, and shape. The experimental results confirmed the successful synthesis of nearly spherical and highly concentrated (2281 ppm) Ag NPs, capped with poly-tannic acid (Ag NPs-PTA). The average particle size of Ag NPs-PTA was found to be 9.90 ± 1.60 nm. The colloidal dispersion of synthesized nanoparticles was observed to be stable for more than 15 months in the ambient environment (25 °C, 65% relative humidity). The synthesized AgNPs-PTA showed an effective antimicrobial activity against Staphylococcus Aureus (ZOI 3.0 mM) and Escherichia coli (ZOI 3.5 mM). Ag NPs-PTA also exhibited enhanced catalytic properties. It reduces 4-nitrophenol into 4-aminophenol in the presence of NaBH4 with a normalized rate constant (Knor = K/m) of 615.04 mL·s−1·mg−1. For comparison, bare Ag NPs show catalytic activity with a normalized rate constant of 139.78 mL·s−1·mg−1. Furthermore, AgNPs-PTA were stable for more than 15 months under ambient conditions. The ultra-high catalytic and good antimicrobial properties can be attributed to the fine size and good aqueous stability of Ag NPs-PTA. The unique core-shell structure and ease of synthesis render the synthesized nanoparticles superior to others, with potential for large-scale applications, especially in the field of catalysis and medical.


2021 ◽  
Vol 35 ◽  
pp. 102319
Author(s):  
Tao Wang ◽  
Weibing Ma ◽  
Yuxin Zhang ◽  
Jingdong Guo ◽  
Tingting Li ◽  
...  

2012 ◽  
Vol 4 (8) ◽  
pp. 3910-3915 ◽  
Author(s):  
Seong Been Kim ◽  
Won Woo Lee ◽  
Jaeseok Yi ◽  
Won Il Park ◽  
Jin-Sang Kim ◽  
...  

Langmuir ◽  
2013 ◽  
Vol 29 (37) ◽  
pp. 11770-11778 ◽  
Author(s):  
Yiya Li ◽  
Dongying Yuan ◽  
Mingjie Dong ◽  
Zhihua Chai ◽  
Guoqi Fu

Author(s):  
Zeyuan Hu ◽  
Yidong Miao ◽  
Xiaolan Xue ◽  
Bin Xiao ◽  
Jiqiu Qi ◽  
...  

2014 ◽  
Vol 26 (3) ◽  
pp. 1602-1607 ◽  
Author(s):  
Fang Li ◽  
Yu-Ling Zhao ◽  
Wei Dai ◽  
Jing Chen ◽  
Zhengquan Li ◽  
...  

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