Enhanced Permittivity and Energy Density in Neat Poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) Terpolymer Films through Control of Morphology

2014 ◽  
Vol 6 (12) ◽  
pp. 9584-9589 ◽  
Author(s):  
O’Neil L. Smith ◽  
Yunsang Kim ◽  
Mohanalingam Kathaperumal ◽  
Matthew R. Gadinski ◽  
Ming-Jen Pan ◽  
...  
Keyword(s):  
Energy Density ◽  
Vinylidene Fluoride ◽  
Poly Vinylidene Fluoride

scholarly journals Nanocomposite multilayer capacitors comprising BaTiO3@TiO2 and poly(vinylidene fluoride-hexafluoropropylene) for dielectric-based energy storage

2014 ◽  
Vol 04 (02) ◽  
pp. 1450009 ◽  
Author(s):  
Mojtaba Rahimabady ◽  
Li Lu ◽  
Kui Yao
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Vinylidene Fluoride ◽  
Discharge Rate ◽  
Low Cost ◽  
Breakdown Field ◽  
High Discharge ◽  
High Discharge Rate ◽  
Poly Vinylidene Fluoride ◽  
Multilayer Capacitors

Multilayer dielectric capacitors were fabricated from nanocomposite precursor comprised of BaTiO 3@ TiO 2 core–shell nanosized particles and poly(vinylidene fluoride–hexafluoropropylene) (P(VDF–HFP)) polymer matrix (20 vol%). The multilayer capacitors showed very high discharge speed and high discharged energy density of around 2.5 J/cm3 at its breakdown field (~ 166 MV/m). The energy density of the nanocomposite multilayer capacitors was substantially higher than the energy density of commercially used power capacitors. Low cost, flexible structure, high discharge rate and energy density suggest that the nanocomposite multilayer capacitors are promising for energy storage applications in many power devices and systems.

High-performance capacitors based on NaNbO3 nanowires/poly(vinylidene fluoride) nanocomposites

2018 ◽  
Vol 6 (30) ◽  
pp. 14614-14622 ◽  
Author(s):  
Zhongbin Pan ◽  
Lingmin Yao ◽  
Guanglong Ge ◽  
Bo Shen ◽  
Jiwei Zhai
Keyword(s):  
Energy Density ◽  
Power Density ◽  
High Performance ◽  
Vinylidene Fluoride ◽  
Nanocomposite Films ◽  
Discharge Energy ◽  
High Discharge ◽  
Fast Discharge ◽  
Poly Vinylidene Fluoride ◽  
Discharge Energy Density

Nanocomposite films loaded with small NaNbO3 nanowires exhibit a high discharge energy density of 12.26 J cm−3 at 410 MV m−1, superior power density of 2.01 MW cm−3, and ultra-fast discharge speed of 146 ns.

The high energy density and efficiency of PVDF-based composites with double-shell Nd-BaTiO3 particles as fillers

2020 ◽  
Vol 13 (06) ◽  
pp. 2051042
Author(s):  
Zhong Yang ◽  
Jing Wang ◽  
Long He ◽  
Chaoyong Deng ◽  
Kongjun Zhu
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Vinylidene Fluoride ◽  
Composite Films ◽  
High Energy ◽  
Maximum Energy ◽  
Dielectric Constants ◽  
High Energy Density ◽  
Element Simulation ◽  
Poly Vinylidene Fluoride

Flexible dielectric capacitors are becoming shining stars in modern electronic devices. Ceramic particles with large dielectric constants and benign compatibility are attractive candidates to enhance the energy storage density of pristine polymer capacitors while guaranteeing their flexibility. In this work, double-shell structure of Al2O3 (AO) and dopamine (PDA) were successively coated on the Nd-doped BaTiO3 (NBT) particles and then introduced into the Poly(vinylidene fluoride) (PVDF) matrix. Obvious enhancement in dielectric constants was observed while the dielectric loss remained nearly constant. For the composite films with 1–4[Formula: see text]vol.% NBT@AO@PDA NPs, the maximum energy density of 9.1[Formula: see text]J/cm3 and energy efficiency of 65% was achieved at 430[Formula: see text]MV/m in the sample with 1[Formula: see text]vol.% filling ratio, which are 1.4 and 1.3 times larger than those of pristine PVDF at 450[Formula: see text]MV/m. The finite element simulation reveals the effective relief of the electric field concentration in the composite film induced by the AO and PDA layers. The greater improvement in the energy storage performance could be anticipated if the dispersity of NBT@AO@PDA NPs was further improved.

High-field antiferroelectric-like behavior in uniaxially stretched poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene)-grafted-poly(methyl methacrylate) films with high energy density

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1589-1599 ◽  
Author(s):  
Honghong Gong ◽  
Bei Miao ◽  
Xiao Zhang ◽  
Junyong Lu ◽  
Zhicheng Zhang
Keyword(s):  
Energy Density ◽  
Methyl Methacrylate ◽  
High Field ◽  
Vinylidene Fluoride ◽  
Breakdown Strength ◽  
High Energy ◽  
High Energy Density ◽  
Poly Methyl Methacrylate ◽  
Poly Vinylidene Fluoride ◽  
Discharged Energy Density

The antiferroelectric-like behavior could be retained up to 675 MV m−1 with a discharged energy density of 23.3 J cm−3 because of the confinement of rigid PMMA segment onto the ferroelectric relaxation of P(VDF-TrFE-CTFE) and the high breakdown strength.

High electric breakdown strength and energy density in vinylidene fluoride oligomer/poly(vinylidene fluoride) blend thin films

2011 ◽  
Vol 99 (14) ◽  
pp. 142901 ◽  
Author(s):  
Mojtaba Rahimabady ◽  
Shuting Chen ◽  
Kui Yao ◽  
Francis Eng Hock Tay ◽  
Li Lu
Keyword(s):  
Thin Films ◽  
Energy Density ◽  
Vinylidene Fluoride ◽  
Breakdown Strength ◽  
Electric Breakdown ◽  
Poly Vinylidene Fluoride
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