Novel Composite Material Polyoxovanadate@MIL-101(Cr): A Highly Efficient Electrocatalyst for Ascorbic Acid Oxidation

2013 ◽  
Vol 5 (24) ◽  
pp. 13382-13390 ◽  
Author(s):  
Diana M. Fernandes ◽  
André D. S. Barbosa ◽  
João Pires ◽  
Salete S. Balula ◽  
Luís Cunha-Silva ◽  
...  
2018 ◽  
Vol 8 (18) ◽  
pp. 4757-4765 ◽  
Author(s):  
Xinran Zhang ◽  
Hongsheng Fan ◽  
Jinlong Zheng ◽  
Sibin Duan ◽  
Yunxia Huang ◽  
...  

Highly uniform Pd–Zn nanocrystals were facilely fabricated with coexisting noble metals and ascorbic acid, which exhibited superior electrocatalytic activity for formic acid oxidation.


2016 ◽  
Vol 65 (1) ◽  
pp. 203-208 ◽  
Author(s):  
V. V. Emelianov ◽  
A. V. Musalnikova ◽  
E. A. Savateeva ◽  
Yu. S. Shakhmina ◽  
T. A. Kalinina ◽  
...  

2011 ◽  
Vol 236-238 ◽  
pp. 1962-1965 ◽  
Author(s):  
Jun Min Ji

Scorbyl palmitate is a safty and highly efficient lipophilic antioxidant.It is produced by a novel ionic liquid method: L-ascorbic acid was esterified with palmitic acid to synthesize ascorbyl palmitate,using concentrated sulfuric acid as chemical catalyst in 1-Butyl-3-methy limidazolium terafluoroborate ([BMIM]BF4).The yield of ascorbyl palmitate reached 69.6±1%.


2013 ◽  
Vol 67 (8) ◽  
Author(s):  
Vladimir Lyutov ◽  
Svetlozar Ivanov ◽  
Vladimir Mirsky ◽  
Vessela Tsakova

AbstractPoly(2-acrylamido-2-methyl-1-propanesulphonic acid) (PAMPSA)-doped polyaniline (PANI) layers are synthesised in the presence of sulphuric and perchloric acids. The effects of the inorganic acid as well as of the electrochemical synthetic procedure (potentiostatic and potentiodynamic deposition) and thickness of the polymer layers are studied. The focus is directed towards the pH dependence of the electrochemical redox activity and conductivity of the PAMPSA-doped PANI layers obtained under different conditions. Ascorbic acid oxidation is used as a test reaction to study the electrocatalytic behaviour of various PAMPSA-doped PANI layers in neutral solution. It is found that the type of inorganic component present in the polymerisation solution has a marked effect on the extent of doping in acidic solutions as well as on the redox electroactivity in neutral solutions. A comparison between potentiostatically and potentiodynamically synthesised layers at pH 7 shows a markedly lower conductance and lower extent of redox charge preservation in the case of potentiodynamic synthesis. The PANI electrocatalytic activity for ascorbic acid oxidation is also dependent on the polymer electrodeposition procedure, with potentiostatically synthesised layers exhibiting better electrocatalytic performance.


1956 ◽  
Vol 39 (2) ◽  
pp. 267-282
Author(s):  
M A Joslyn ◽  
Enrico Zuegg
Keyword(s):  

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