On–Off–On Fluorescent Carbon Dot Nanosensor for Recognition of Chromium(VI) and Ascorbic Acid Based on the Inner Filter Effect

2013 ◽  
Vol 5 (24) ◽  
pp. 13242-13247 ◽  
Author(s):  
Min Zheng ◽  
Zhigang Xie ◽  
Dan Qu ◽  
Di Li ◽  
Peng Du ◽  
...  
RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 21137-21144
Author(s):  
Mengyuan He ◽  
Ning Shang ◽  
Bo Zheng ◽  
Gege Yue

An ultrasensitive colorimetric and fluorescence dual-readout assay based on carbon dot–MnO2 nanosheets platform was developed for GSH detection in human body fluid samples.


2018 ◽  
Vol 42 (5) ◽  
pp. 3729-3735 ◽  
Author(s):  
Haitao Wang ◽  
Shan Liu ◽  
Yisha Xie ◽  
Jingran Bi ◽  
Yao Li ◽  
...  

Label-free fluorescence assay system is designed for Cr(iv) detection.


NANO ◽  
2020 ◽  
Vol 15 (06) ◽  
pp. 2050074
Author(s):  
Suping Wang ◽  
Yujiao Tu ◽  
Kunhao Qin ◽  
Xiaotian Yuan ◽  
Wei Chen ◽  
...  

Phenolic compounds, especially 4-nitrophenol (4-NP), and chromium (VI) are highly toxic environmental pollutants. Thus, it is significantly important to establish a rapid and sensitive sensor for 4-NP and Cr(VI) monitoring in environment. In this paper, a novel approach has been adopted where E. coli-derived CDs (CDs-WT) prepared by one step hydrothermal method previously and sensitized by ampicillin (turn-on) were used as fluorescence nanoprobe (CDs-WT-Amp) for 4-NP and Cr(VI) determination based on the inner filter effect quenching mechanism (turn-off). Then, the quenching fluorescence was reversed by addition of ampicillin (turn-on). The linear ranges of 4-NP and Cr(VI) detection were 0–50[Formula: see text][Formula: see text]M and 0–25[Formula: see text][Formula: see text]M, with the limits of detection 88.89[Formula: see text]nM and 64.75[Formula: see text]nM, respectively. The “turn-on-on-off-on” fluorescent nanosensor system was successfully used to determine Cr(VI) and 4-NP in water with satisfactory results. It shows that the “turn-on-off-on” nanoprobe has great promising potential for application to environmental pollutant detection.


2018 ◽  
Vol 42 (1) ◽  
pp. 293-300 ◽  
Author(s):  
Ambreen Abbasi ◽  
Mohammad Shakir

An effective and simple fluorescent sensing approach for recognition of Cr(vi) using a Schiff base chemosensor,N′-[(E)-(3,4-dimethoxyphenyl) methylidene] furan-2-carbohydrazide, was developed.


2021 ◽  
Vol 23 (1) ◽  
pp. 190
Author(s):  
Thi-Hoa Le ◽  
Ji-Hyeon Kim ◽  
Sang-Joon Park

Glutathione (GSH) is a thiol that plays a significant role in nutrient metabolism, antioxidant defense and the regulation of cellular events. GSH deficiency is related to variety of diseases, so it is useful to develop novel approaches for GSH evaluation and detection. In this study we used nitrogen and phosphorus co-doped carbon dot-gold nanoparticle (NPCD–AuNP) composites to fabricate a simple and selective fluorescence sensor for GSH detection. We employed the reductant potential of the nitrogen and phosphorus co-doped carbon dots (NPCDs) themselves to form AuNPs, and subsequently NPCD–AuNP composites from Au3+. The composites were characterized by using a range of spectroscopic and electron microscopic techniques, including electrophoretic light scattering and X-ray diffraction. The overlap of the fluorescence emission spectrum of NPCDs and the absorption spectrum of AuNPs resulted in an effective inner filter effect (IFE) in the composite material, leading to a quenching of the fluorescence intensity. In the presence of GSH, the fluorescence intensity of the composite was recovered, which increased proportionally to increasing the GSH concentration. In addition, our GSH sensing method showed good selectivity and sensing potential in human serum with a limit of detection of 0.1 µM and acceptable results.


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