Microporous Organic Polymers with Ketal Linkages: Synthesis, Characterization, and Gas Sorption Properties

2013 ◽  
Vol 5 (10) ◽  
pp. 4166-4172 ◽  
Author(s):  
Ying Han ◽  
Li-Min Zhang ◽  
Yan-Chao Zhao ◽  
Tao Wang ◽  
Bao-Hang Han
Keyword(s):  
Sorption Properties ◽  
Organic Polymers ◽  
Gas Sorption ◽  
Microporous Organic Polymers

Microporous organic polymers with acetal linkages: synthesis, characterization, and gas sorption properties

2014 ◽  
Vol 5 (2) ◽  
pp. 614-621 ◽  
Author(s):  
Yan-Chao Zhao ◽  
Li-Min Zhang ◽  
Tao Wang ◽  
Bao-Hang Han
Keyword(s):  
Sorption Properties ◽  
Organic Polymers ◽  
Gas Sorption ◽  
Microporous Organic Polymers

Tetraphenylethylene-based microporous organic polymers: insight into structure geometry, porosity, and CO2/CH4 selectivity

RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 51411-51418 ◽  
Author(s):  
Hui Li ◽  
Xuesong Ding ◽  
Bao-Hang Han
Keyword(s):  
Organic Polymers ◽  
Gas Sorption ◽  
Microporous Organic Polymers ◽  
Structure Geometry ◽  
Insight Into

Tetraphenylethylene-based microporous organic polymers with tunable porosities were synthesized and their gas sorption capabilities were investigated.

scholarly journals Chemical modification of the polymer of intrinsic microporosity PIM-1 for enhanced hydrogen storage

Adsorption ◽  
2020 ◽  
Vol 26 (7) ◽  
pp. 1083-1091
Author(s):  
Mi Tian ◽  
Sébastien Rochat ◽  
Hamish Fawcett ◽  
Andrew D. Burrows ◽  
Christopher R. Bowen ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Surface Area ◽  
Hydrogen Adsorption ◽  
Sorption Properties ◽  
Bet Surface Area ◽  
Polymer Modification ◽  
Gas Sorption ◽  
Chemically Modified ◽  
Polymer Of Intrinsic Microporosity ◽  
Intrinsic Microporosity

Abstract A detailed investigation has been carried out of the pre-polymerisation modification of the polymer of intrinsic microporosity PIM-1 by the addition of two methyl (Me) groups to its spirobisindane unit to create a new chemically modified PIM-1 analogue, termed MePIM. Our work explores the effects of this modification on the porosity of PIM-1 and hence on its gas sorption properties. MePIM was successfully synthesised using either low (338 K) or high (423 K) temperature syntheses. It was observed that introduction of methyl groups to the spirobisindane part of PIM-1 generates additional microporous spaces, which significantly increases both surface area and hydrogen storage capacity. The BET surface area (N2 at 77 K) was increased by ~ 12.5%, resulting in a ~ 25% increase of hydrogen adsorption after modification. MePIM also maintains the advantages of good processability and thermal stability. This work provides new insights on a facile polymer modification that enables enhanced gas sorption properties.

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Microporous organic polymers involving thiadiazolopyridine for high and selective uptake of greenhouse gases at low pressure

2017 ◽  
Vol 53 (76) ◽  
pp. 10576-10579 ◽  
Author(s):  
MD. Waseem Hussain ◽  
Sujoy Bandyopadhyay ◽  
Abhijit Patra
Keyword(s):  
Greenhouse Gases ◽  
Low Pressure ◽  
High Uptake ◽  
Organic Polymers ◽  
Selective Uptake ◽  
Microporous Organic Polymers

Thiadiazolopyridine-based microporous organic polymers were shown to exhibit a remarkably high uptake of CO2 of 5.8 mmol g−1 at 273 K and 1 bar.

Gas-sorption properties of 6FDA-durene/1,4-phenylenediamine (pPDA) and 6FDA-durene/1,3-phenylenediamine (mPDA) copolyimides

2003 ◽  
Vol 90 (8) ◽  
pp. 2187-2193 ◽  
Author(s):  
Si-Xue Cheng ◽  
Tai-Shung Chung ◽  
Rong Wang ◽  
Rohit H. Vora
Keyword(s):  
Sorption Properties ◽  
Gas Sorption

A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

2013 ◽  
Vol 49 (17) ◽  
pp. 1753 ◽  
Author(s):  
Yong-Liang Huang ◽  
Yun-Nan Gong ◽  
Long Jiang ◽  
Tong-Bu Lu
Keyword(s):  
Sorption Properties ◽  
Gas Sorption ◽  
Temperature Dependent

Branching out with aminals: microporous organic polymers from difunctional monomers

2012 ◽  
Vol 3 (2) ◽  
pp. 533-537 ◽  
Author(s):  
Andrea Laybourn ◽  
Robert Dawson ◽  
Rob Clowes ◽  
Jonathan A. Iggo ◽  
Andrew I. Cooper ◽  
...  
Keyword(s):  
Organic Polymers ◽  
Microporous Organic Polymers
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