Design and Synthesis of Supported Nanoscale Metal–Organic Frameworks: Transformation from Transition Metal Silicates

2018 ◽  
Vol 6 (11) ◽  
pp. 14979-14988 ◽  
Author(s):  
Runze Qin ◽  
Hua Chun Zeng
Keyword(s):  
Transition Metal ◽  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Transition Metal Silicates

Design and Synthesis of Conductive Metal‐Organic Frameworks and Their Composites for Supercapacitors

2021 ◽  
Author(s):  
Ting Yue ◽  
Chenfeng Xia ◽  
Xiaobang Liu ◽  
Zhitong Wang ◽  
Kai Qi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Design And Synthesis ◽  
Metal Organic

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks

2008 ◽  
Vol 130 (6) ◽  
pp. 1833-1835 ◽  
Author(s):  
Farid Nouar ◽  
Jarrod F. Eubank ◽  
Till Bousquet ◽  
Lukasz Wojtas ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Highly Porous

Design and synthesis of nanoporous carbon materials using Cd-based homochiral metal–organic frameworks as precursors for supercapacitor application

CrystEngComm ◽  
2018 ◽  
Vol 20 (31) ◽  
pp. 4364-4369 ◽  
Author(s):  
Guangju Zhang ◽  
Siqi Xiu ◽  
Ying Wei ◽  
Qingguo Zhang ◽  
Kedi Cai
Keyword(s):  
Carbon Materials ◽  
Metal Organic Frameworks ◽  
Nanoporous Carbon ◽  
Supercapacitor Application ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Nanoporous Carbon Materials

Design and synthesis of nanoporous carbon materials using Cd-based homochiral metal–organic frameworks as precursors for supercapacitor application.

scholarly journals X-ray crystallographic insights into post-synthetic metalation products in a metal–organic framework

2017 ◽  
Vol 375 (2084) ◽  
pp. 20160028 ◽  
Author(s):  
Michael T. Huxley ◽  
Campbell J. Coghlan ◽  
Witold M. Bloch ◽  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Sphere ◽  
Metal Organic Frameworks ◽  
Void Space ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Nitrates ◽  
Metal Organic

Post-synthetic modification of metal–organic frameworks (MOFs) facilitates a strategic transformation of potentially inert frameworks into functionalized materials, tailoring them for specific applications. In particular, the post-synthetic incorporation of transition-metal complexes within MOFs, a process known as ‘metalation’, is a particularly promising avenue towards functionalizing MOFs. Herein, we describe the post-synthetic metalation of a microporous MOF with various transition-metal nitrates. The parent framework, 1 , contains free-nitrogen donor chelation sites, which readily coordinate metal complexes in a single-crystal to single-crystal transformation which, remarkably, can be readily monitored by X-ray crystallography. The presence of an open void surrounding the chelation site in 1 prompted us to investigate the effect of the MOF pore environment on included metal complexes, particularly examining whether void space would induce changes in the coordination sphere of chelated complexes reminiscent of those found in the solution state. To test this hypothesis, we systematically metalated 1 with first-row transition-metal nitrates and elucidated the coordination environment of the respective transition-metal complexes using X-ray crystallography. Comparison of the coordination sphere parameters of coordinated transition-metal complexes in 1 against equivalent solid- and solution-state species suggests that the void space in 1 does not markedly influence the coordination sphere of chelated species but we show notably different post-synthetic metalation outcomes when different solvents are used. This article is part of the themed issue ‘Coordination polymers and metal–organic frameworks: materials by design’.

Design and Synthesis of Two Porous Metal–Organic Frameworks withnboandagwTopologies Showing High CO2Adsorption Capacity

2013 ◽  
Vol 52 (19) ◽  
pp. 10720-10722 ◽  
Author(s):  
Zhiqiang Liang ◽  
Jingjing Du ◽  
Libo Sun ◽  
Jin Xu ◽  
Ying Mu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Design And Synthesis ◽  
Metal Organic
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