Synthesis and Characterization of Polyurethane Networks Derived from Soybean-Oil-Based Cyclic Carbonates and Bioderivable Diamines

2016 ◽  
Vol 4 (12) ◽  
pp. 6551-6561 ◽  
Author(s):  
Satyabrata Samanta ◽  
Sermadurai Selvakumar ◽  
James Bahr ◽  
Dona Suranga Wickramaratne ◽  
Mukund Sibi ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Synthesis And Characterization ◽  
Cyclic Carbonates ◽  
Polyurethane Networks

scholarly journals Synthesis and characterization of different soybean oil-based polyols with fatty alcohol and aromatic alcohol

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 491-499
Author(s):  
Fukai Yang ◽  
Hao Yu ◽  
Yuyuan Deng ◽  
Xinyu Xu
Keyword(s):  
Molecular Weight ◽  
Soybean Oil ◽  
Retention Time ◽  
Ring Opening ◽  
Isoamyl Alcohol ◽  
Synthesis And Characterization ◽  
Intermolecular Force ◽  
H Nmr ◽  
Epoxy Groups

Abstract In this article, five kinds of soybean oil-based polyols (polyol-E, polyol-P, polyol-I, polyol-B, and polyol-M) were prepared by ring-opening the epoxy groups in epoxidized soybean oil (ESO) with ethyl alcohol, 1-pentanol, isoamyl alcohol, p-tert-butylphenol, and 4-methoxyphenol in the presence of tetrafluoroboric acid as the catalyst. The SOPs were characterized by FTIR, 1H NMR, GPC, viscosity, and hydroxyl numbers. Compared with ESO, the retention time of SOPs is shortened, indicating that the molecular weight of SOPs is increased. The structure of different monomers can significantly affect the hydroxyl numbers of SOPs. Due to the large steric hindrance of isoamyl alcohol, p-hydroxyanisole, and p-tert-butylphenol, SOPs prepared by these three monomers often undergo further dehydration to ether reactions, which consumes the hydroxyl of polyols, thus forming dimers and multimers; therefore, the hydroxyl numbers are much lower than polyol-E and polyol-P. The viscosity of polyol-E and polyol-P is much lower than that of polyol-I, polyol-B, and polyol-M. A longer distance between the molecules and the smaller intermolecular force makes the SOPs dehydrate to ether again. This generates dimer or polymers and makes the viscosity of these SOPs larger, and the molecular weight greatly increases.

Controllable Synthesis and Characterization of Soybean-Oil-Based Hyperbranched Polymers via One-Pot Method

2018 ◽  
Vol 6 (10) ◽  
pp. 12865-12871 ◽  
Author(s):  
Xuan Qin ◽  
Yong He ◽  
Shafilluah Khan ◽  
Baihui Zhang ◽  
Fanxing Chen ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Hyperbranched Polymers ◽  
Synthesis And Characterization ◽  
Controllable Synthesis ◽  
One Pot

Synthesis and Characterization of Alkyd Resin Based on Soybean Oil Polyols

2011 ◽  
Vol 239-242 ◽  
pp. 1721-1724 ◽  
Author(s):  
Xiao Qing Zheng ◽  
Li Ting Yang ◽  
Kun Peng Wang
Keyword(s):  
Maleic Anhydride ◽  
Soybean Oil ◽  
Phthalic Anhydride ◽  
Alkyd Resin ◽  
Ring Opening ◽  
Molar Ratio ◽  
Synthesis And Characterization ◽  
Hydroxyl Value

Soybean oil-based alkyd resin was prepared using soy-based polyol, maleic anhydride and phthalic anhydride. The soy-based polyol was obtained through the epoxidization of soybean oil, followed by ring-opening with methanol and, the hydroxyl values of soybean oil-based polyols used in this reaction is 169.93 mgKOH/g. In the reactions of soy-based polyol, maleic anhydride and phthalic anhydride, the molar ratio of hydroxyl value is equal to carboxyl value and the molar ratio of maleic anhydride to phthalic anhydride is 2:1, 1:1 and 1:2, respectively. 1% hydroquinone based on total reactants was used as inhibitor of polymerization, 1% dibutyltin oxide was used as catalyst.

Lewis-acid catalyzed synthesis and characterization of novel castor fatty acid-based cyclic carbonates

RSC Advances ◽  
2016 ◽  
Vol 6 (31) ◽  
pp. 25703-25712 ◽  
Author(s):  
Naganna Narra ◽  
Badari Narayana Prasad Rachapudi ◽  
Sahithya Phani Babu Vemulapalli ◽  
Padmaja V. Korlipara
Keyword(s):  
Fatty Acid ◽  
Ricinoleic Acid ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Synthesis And Characterization ◽  
Cyclic Carbonates ◽  
Molecular Rearrangement ◽  
Acid Catalyzed

Novel bio-based cyclic carbonates were synthesised from ricinoleic acid by intra molecular rearrangement of an epoxy carbonate ester with Lewis acids.

scholarly journals INVESTIGATION OF BIOPLASTIC PROPERTIES DEVELOPED FROM ACRYLATE EPOXIDIZED SOYBEAN OIL THROUGH RING OPENING POLYMERIZATION PROCESS

1970 ◽  
Vol 1 (1) ◽  
pp. 29-41 ◽  
Author(s):  
Hiew Ming Yu ◽  
Arun Gupta ◽  
Ritu Gupta ◽  
Saad Bala Husain
Keyword(s):  
Mechanical Properties ◽  
Soybean Oil ◽  
Ring Opening ◽  
Unsaturated Fatty Acids ◽  
Ring Opening Polymerization ◽  
Epoxidized Soybean Oil ◽  
Polymerization Process ◽  
Synthesis And Characterization ◽  
Glycerol Concentration

Soybean oil is one of the major vegetable oils containing more than 99% of triglycerides of saturated and unsaturated fatty acids and has become an interesting source to produce bioplastic. This study investigates the synthesis and characterization of bioplastic developed by the acrylate epoxidized soybean oil through ring opening polymerization process. The mechanical properties of the samples were characterized using Fourier Transform Infrared Spectroscopy, Thermogravimetric analysis and the physio-chemical properties of the bioplastics were studied. In this study, the bioplastic made up from soybean oil with the lowest glycerol concentration showed the best mechanical properties.

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