Fluorescent Chemosensors with Varying Degrees of Intramolecular Charge Transfer for Detection of a Nerve Agent Mimic in Solutions and in Vapor

ACS Sensors ◽  
2017 ◽  
Vol 2 (6) ◽  
pp. 834-841 ◽  
Author(s):  
Yuan-Chao Cai ◽  
Chen Li ◽  
Qin-Hua Song
Keyword(s):  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Nerve Agent ◽  
Fluorescent Chemosensors

Dynamic adjustment of emission from both singlets and triplets: the role of excited state conformation relaxation and charge transfer in phenothiazine derivates

2021 ◽  
Author(s):  
Weidong Qiu ◽  
Xinyi Cai ◽  
Mengke Li ◽  
Liangying Wang ◽  
Yanmei He ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Dynamic Adjustment ◽  
Twisted Intramolecular Charge Transfer

Dynamic adjustment of emission behaviours by controlling the extent of twisted intramolecular charge transfer character in excited state.

Various Sensing Mechanisms for the Design of Naphthalimide based Chemosensors Emerging in Recent Years

2020 ◽  
Vol 13 (4) ◽  
pp. 262-289
Author(s):  
Duraisamy Udhayakumari
Keyword(s):  
Metal Ions ◽  
Intramolecular Charge Transfer ◽  
Resonance Energy Transfer ◽  
Resonance Energy ◽  
Intramolecular Proton Transfer ◽  
Biological Applications ◽  
Fluorescent Chemosensors ◽  
The Past ◽  
Photo Induced Electron Transfer ◽  
Displacement Approach

In the design of novel fluorescent chemosensors, investigation of new sensing mechanisms between recognition and signal reporting units is of increasing interest. In recent years, a smart chemosensor probe containing a 1,8-naphthalimide moiety could be developed as a fluorescent and colorimetric sensor for toxic anions, metal ions, biomolecules, nitroaromatics, and acids and be further applied to monitor the relevant biological applications. In this field, several problems and challenges still exist. This critical review is mainly focused on various sensing mechanisms that have emerged in the past few years, such as Photo-Induced Electron Transfer (PET), Intramolecular Charge Transfer (ICT), Fluorescence Resonance Energy Transfer (FRET), Excited-State Intramolecular Proton Transfer (ESIPT), hydrogen bonding and displacement approach. The review concludes with some current and future perspectives, including the use of the naphthalimides for sensing anions, metal ions, biomolecules, nitroaromatics and acids and their potential uses in various fields.

Steric Effects on Intramolecular Charge Transfer Fluorescence of Benzo[b]thiophene-1,1-dioxide Bridged Macrocages

2021 ◽  
Author(s):  
Keita Nobuhara ◽  
Yusuke Inagaki ◽  
Wataru Setaka
Keyword(s):  
Charge Transfer ◽  
Intramolecular Charge Transfer ◽  
Fluorescence Properties ◽  
Steric Effects ◽  
Sensor Molecules

Intramolecular charge transfer (ICT) fluorescence has been widely investigated and exploited in sensor molecules. However, steric effects on the ICT fluorescence properties have rarely been reported so far, although research...

scholarly journals Counterion Migration Driven by Light-Induced Intramolecular Charge Transfer

JACS Au ◽  
2021 ◽  
Author(s):  
Ta-Chun Lin ◽  
Zong-Ying Liu ◽  
Shih-Hung Liu ◽  
Igor O. Koshevoy ◽  
Pi-Tai Chou
Keyword(s):  
Charge Transfer ◽  
Intramolecular Charge Transfer
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