scholarly journals Magnetic Properties of End-to-End Azide-Bridged Tetranuclear Mixed-Valence Cobalt(III)/Cobalt(II) Complexes with Reduced Schiff Base Blocking Ligands and DFT Study

ACS Omega ◽  
2019 ◽  
Vol 4 (24) ◽  
pp. 20634-20643 ◽  
Author(s):  
Abhisek Banerjee ◽  
Snehasis Banerjee ◽  
Carlos J. Gómez García ◽  
Samia Benmansour ◽  
Shouvik Chattopadhyay
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Mixed Valence ◽  
Dft Study ◽  
Reduced Schiff Base ◽  
End To End

Iso-valence Co(II) and mixed-valence Co(II/III) tetranuclear complexes: Synthesis, structure, magnetic properties and DFT study

Polyhedron ◽  
2013 ◽  
Vol 65 ◽  
pp. 60-66 ◽  
Author(s):  
Pallab Mondal ◽  
Reena Singh ◽  
Amar Hens ◽  
Joan Cano ◽  
Enrique Colacio ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Mixed Valence ◽  
Dft Study ◽  
Tetranuclear Complexes

scholarly journals Heterometallic Complexes Containing the NiII-LnIII-NiII Moiety—Structures and Magnetic Properties

Crystals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1117
Author(s):  
Catherine P. Raptopoulou
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Structural Characteristics ◽  
Structural Similarity ◽  
Heterometallic Complexes ◽  
Schiff Base Ligands ◽  
Lanthanide Ion ◽  
Trinuclear Complexes ◽  
Reduced Schiff Base ◽  
Reduced Schiff Base Ligands

This review summarizes the structural characteristics and magnetic properties of trinuclear complexes containing the NiII-LnIII-NiII moiety and also oligonuclear complexes and coordination polymers containing the same trinuclear moiety. The ligands used are mainly polydentate Schiff base ligands and reduced Schiff base ligands and, in some cases, oximato, β-diketonato, pyridyl ketone ligands and others. The compounds reported are restricted to those containing one, two and three oxygen atoms as bridges between the metal ions; examples of carboxylato and oximato bridging are also included due to structural similarity. The magnetic properties of the complexes range from ferro- to antiferromagnetic depending on the nature of the lanthanide ion.

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