scholarly journals Surfactant-Assisted Selective Oxidation of Aromatic Amines to Nitro Compounds by in Situ-Formed Performic Acid

ACS Omega ◽  
2019 ◽  
Vol 4 (5) ◽  
pp. 9453-9457 ◽  
Author(s):  
Krishnan Ravi ◽  
Balasaheb D. Bankar ◽  
Sana Jindani ◽  
Ankush V. Biradar
Keyword(s):  
Selective Oxidation ◽  
Aromatic Amines ◽  
Nitro Compounds ◽  
Performic Acid ◽  
Surfactant Assisted

scholarly journals Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 2701-2714
Author(s):  
Caitlin M. Crombie ◽  
Richard J. Lewis ◽  
Rebekah L. Taylor ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
H2o2 Production ◽  
Oxidation Of Benzyl Alcohol ◽  
Supported Pd

Hypervalent iodine catalysis for selective oxidation of Baylis–Hillman adducts via in situ generation of o-iodoxybenzoic acid (IBX) from 2-iodosobenzoic acid (IBA) in the presence of oxone

2016 ◽  
Vol 40 (12) ◽  
pp. 10300-10304 ◽  
Author(s):  
Raktani Bikshapathi ◽  
Parvathaneni Sai Prathima ◽  
Vaidya Jayathirtha Rao
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Hypervalent Iodine ◽  
In Situ Generation ◽  
Iodosobenzoic Acid ◽  
High Yields

An efficient, eco-friendly protocol for selective oxidation of primary and secondary Baylis–Hillman alcohols to the corresponding carbonyl compounds in high yields has been developed with 2-iodosobenzoic acid (IBA).

Sustainable Aldehyde Oxidations in Continuous Flow Using in Situ-Generated Performic Acid

2021 ◽  
Vol 9 (16) ◽  
pp. 5519-5525
Author(s):  
Michael Prieschl ◽  
Sándor B. Ötvös ◽  
C. Oliver Kappe
Keyword(s):  
Continuous Flow ◽  
Performic Acid

Application of Epoxy Resin for Improvement of the Banana Stem-Acoustic Panel

2021 ◽  
Vol 15 ◽  
Author(s):  
Mohd Azril Riduan ◽  
Mohd Jumain Jalil ◽  
Intan Suhada Azmi ◽  
Afifudin Habulat ◽  
Danial Nuruddin Azlan Raofuddin ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Kinetic Modelling ◽  
Low Cost ◽  
Cost Effective ◽  
Performic Acid ◽  
High Yield ◽  
Renewable Materials ◽  
Runge Kutta Method ◽  
To Come

Background: Greener epoxidation by using vegetable oil to create an eco-friendly epoxide is being studied because it is a more cost-effective and environmentally friendly commodity that is safer than non-renewable materials. The aim of this research is to come up with low-cost solutions for banana trunk acoustic panels with kinetic modelling of epoxy-based palm oil. Method: In this study, the epoxidation of palm oleic acid was carried out by in situ performic acid to produce epoxidized palm oleic acid. Results: Banana trunk acoustic panel was successfully innovated based on the performance when the epoxy was applied. Lastly, a mathematical model was developed by using the numerical integration of the 4th order Runge-Kutta method, and the results showed that there is a good agreement between the simulation and experimental data, which validates the kinetic model. Conclusion: Overall, the peracid mechanism was effective in producing a high yield of epoxy from palm oleic acid that is useful for the improvement of acoustic panels based on the banana trunk.

scholarly journals Preparation and Characterization of Epoxidised and Acrylated Styrene/Isoprene/Styrene (SIS) Triblock Block Copolymer Based Nanocomposites

2013 ◽  
Vol 28 ◽  
pp. 84-88 ◽  
Author(s):  
Santosh Khanal ◽  
Alina Shakya ◽  
Goerg H. Michler ◽  
Boulos Youssef ◽  
Jean M. Saiter ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Chemical Society ◽  
Performic Acid ◽  
Casting Method ◽  
Immiscible Polymers ◽  
Transmission Electron ◽  
Boehmite Nanoparticles ◽  
Solution Casting Method

In this work, a commercially available Styrene-Isoprene-Styrene (SIS)triblock copolymer was modified into epoxidised version (ESIS)using performic acid generated in situ from hydrogen peroxide and formic acid. The epoxidised sample was further acrylated to prepare acrylated version (ASIS). The nanocomposites of each sample (SIS, ESIS and ASIS) were prepared using boehmite nanoparticles as filler by solution casting method. The polymers were characterized by Fourier Transform Infrared (FTIR) spectroscopy and transmission electron microscopy (TEM). TEM investigations revealed that that the epoxidation of the diene block enhanced the dispersion of the nanofiller in the polymer matrix while the segregation of the nanoparticles towards the interface of the immiscible polymers was observed in the acrylated block copolymer based nanocomposite. DOI: http://dx.doi.org/10.3126/jncs.v28i0.8112 Journal of Nepal Chemical Society Vol. 28, 2011 Page: 84-88 Uploaded Date: May 24, 2013

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