scholarly journals Selective Adsorption of Water, Methanol, and Ethanol by Naphthalene Diimide-Based Coordination Polymers with Constructed Open Cu2+ Metal Sites and Separation of Ethanol/Acetonitrile

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 1995-2000 ◽  
Author(s):  
Guo-Bi Li ◽  
Bai-Qiao Song ◽  
Shi-Qiang Wang ◽  
Ling-Min Pei ◽  
Sheng-Gui Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Selective Adsorption ◽  
Naphthalene Diimide ◽  
Adsorption Of Water

scholarly journals Optimization of Mordenite Membranes Using Sucrose Precursor for Pervaporation of Water-Ethanol Mixtures

Membranes ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 160
Author(s):  
Abdulaziz A. Alomair ◽  
Yousef Alqaheem
Keyword(s):  
Pyrolysis Temperature ◽  
Operating Temperature ◽  
Selective Adsorption ◽  
Sucrose Concentration ◽  
Low Cost ◽  
Water Flux ◽  
Separation Performance ◽  
Carbon Membranes ◽  
Adsorption Of Water ◽  
High Separation

Post-treated mordenite membranes were prepared using sucrose (C12H22O11) as a carbon precursor to block any pinholes and defects in the zeolite layer. The pervaporation (PV) process was used to separate ethanol from the water. The effects of the sucrose concentration and the pyrolysis temperature (650–850 °C) were investigated, and the resulting high separation performance compared to those post/pre-treated membranes was reported in the literature. In this study, mordenite carbon membranes yielded a water/ethanol separation factor of 990.37 at a water flux of 9.10 g/m2h. The influence of the operating temperature on the performance of the membrane also was considered. It was concluded that the selective adsorption of water through zeolite pores was achieved. The entire preparation procedure was achieved using a rapid, low-cost preparation process.

scholarly journals Synthesis of a magnetic C@Co material via the design of a MOF precursor for efficient and selective adsorption of water pollutants

2021 ◽  
Author(s):  
Yu Liu ◽  
Yan Wang ◽  
Xiao-Sa Zhang ◽  
Wen-Ze Li ◽  
Ai-Ai Yang ◽  
...  
Keyword(s):  
Active Sites ◽  
Organic Dyes ◽  
Selective Adsorption ◽  
Catalytic Performance ◽  
Adsorption Processes ◽  
Carbon Coated ◽  
Adsorption Of Water ◽  
Metal Organic ◽  
Cobalt Nanoparticle ◽  
Fast Acting

Abstract 3D metal-organic frameworks (MOFs) can be appropriate templates for the fabrication of nanomaterials due to they have active sites exposed on the channel or surface, which thus provide them with improved catalytic performance. In this study, a 3D cobalt-based MOF [Co(H2bpta)]n (Co-MOF), where H4bpta denotes 2,2′,4,4′-biphenyltetracarboxylic acid, has been constructed with the use of a ligand with a high carbon content. On this basis, a 2D magnetic carbon-coated cobalt nanoparticle composite (C@Co) was prepared by using the title MOF. Magnetic C@Co can readily absorb dye from the solution and can thus act as an inexpensive and fast-acting adsorbent. Moreover, we have explored the adsorption isotherms, kinetics and thermodynamics of the anion dyes in detail. The adsorption capacity of the C@Co for investigated methyl orange (MO) and congo red (CR) dyes were 773.48 and 495.66 mg g− 1, respectively. It is noteworthy that MO adsorption is higher in existing materials. Thermodynamic studies suggest that the adsorption processes are spontaneous and exothermic. This study opens a new insight into the synthesis and application of carbon-based materials that enable the selective removal of organic dyes.

MOFs containing a linear bis-pyridyl-tris-amide and angular carboxylates: exploration of proton conductivity, water vapor and dye sorptions

2019 ◽  
Vol 6 (1) ◽  
pp. 184-191 ◽  
Author(s):  
Satyanarayana K. Konavarapu ◽  
Anindita Goswami ◽  
Anaparthi Ganesh Kumar ◽  
Susanta Banerjee ◽  
Kumar Biradha
Keyword(s):  
Methylene Blue ◽  
Water Vapor ◽  
Proton Conductivity ◽  
Crystal Violet ◽  
Selective Adsorption ◽  
Cationic Dyes ◽  
Adsorption Of Water ◽  
Conductivity Water ◽  
Adsorption Of Water Vapor

Four new MOFs were shown to have appreciable proton conductivities, selective adsorption of water vapor over nitrogen and a tendency to selectively adsorb cationic dyes such as methylene blue and crystal violet.

Ethanol separation by selective adsorption of water

1993 ◽  
Vol 8 (5-6) ◽  
pp. 279-282 ◽  
Author(s):  
S. K. Rakshit ◽  
P. Ghosh ◽  
V. S. Bisaria
Keyword(s):  
Selective Adsorption ◽  
Adsorption Of Water ◽  
Ethanol Separation

Supramolecular structural transformation of N,N′-bis(4-pyridylmethyl)-naphthalene diimide and fluorescence water sensing

2017 ◽  
Vol 41 (14) ◽  
pp. 6160-6166 ◽  
Author(s):  
Guo-Bi Li ◽  
Qing-Yuan Yang ◽  
Rong-Kai Pan ◽  
Shenggui Liu ◽  
Yao-Wei Xu
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Selective Adsorption ◽  
Fluorescence Sensing ◽  
Organic Structure ◽  
Naphthalene Diimide ◽  
Adsorption Of Co ◽  
Water Sensing

The supramolecular organic structure exhibits reversible dehydration/rehydration in a single-crystal-to-single-crystal process, selective adsorption of CO2 over N2 as well as H2 and sorption selectivity for water and fluorescence sensing of water.

Selective gas adsorption in microporous metal–organic frameworks incorporating urotropine basic sites: an experimental and theoretical study

2015 ◽  
Vol 51 (73) ◽  
pp. 13918-13921 ◽  
Author(s):  
S. A. Sapchenko ◽  
D. N. Dybtsev ◽  
D. G. Samsonenko ◽  
R. V. Belosludov ◽  
V. R. Belosludov ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Ab Initio ◽  
Coordination Polymers ◽  
Theoretical Study ◽  
Gas Adsorption ◽  
Selective Adsorption ◽  
Metal Organic Frameworks ◽  
Porous Coordination Polymers ◽  
Basic Sites ◽  
Metal Organic

Urotropine-based porous coordination polymers with free N-donors demonstrate selective adsorption towards acidic gas substrates (C2H2 or CO2) as confirmed by isotherm measurements and ab initio DFT calculations.

Sign in / Sign up

Export Citation Format

Share Document